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Materials Today Physics · 2021 · IF 9.298

Magnetoresistance-enhanced electro-thermal conversion performance

C. Li,S. Ma,W. Cui,X. Sang,P. Wei,W. Zhu,X. Nie,W. Zhao,Q. Zhang

Seeking novel and effective approaches to synergistically improve the electrical and thermal transport properties and electro-thermal conversion efficiency of Bi 2 Te 3 -based alloys is essential for commercial applications. Here, GdCo 2 /Bi 0.37 Sb 1.63 Te 3 thermoelectric nanocomposites were designed and synthesized to achieve synergistic improvement of electrical and thermal properties . As confirmed by magnetoresistance measurement, the built-in magnetic field and magnetic scattering generated by magnetic nanoparticles decrease the carrier concentration and mobility, and increase the Seebeck coefficient . Meanwhile, GdCo 2 nanoparticles lead to broad-frequency phonon scattering, which effectively reduces the lattice thermal conductivity of nanocomposites. Eventually, the average ZT of the nanocomposite is increased by 18% in the range of 300–500 K, and the cooling temperature difference is increased by 68% near room temperature. This work proves that the thermoelectromagnetic coupling effects generated by magnetic particles can effectively improve the electro-thermal conversion performance.

研究领域: 材料科学 · 凝聚态物理 · 热电材料 · 纳米科技 · 功能材料
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