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JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS · 2025 ·Vol. 36 ·期 27 ·1-13 · IF 2.8

Water pollution remediation: synthesis of gray-Tio2/Zno/α-Fe2o3 ternary composite for the photocatalytic degradation of Direct Red 28 dye under solar light

Anjum Muhammad Naveed,Qayyum Muhammad Abdul,Zulfiqar Zunaira,Ahmad Mirza Nadeem,Saif Muhammad Jawwad,Bahadur Ali,Iqbal Shahid,Mahmood Sajid,Alotaibi Khalid M.,Farouk Abd-ElAziem

Based on an appropriate procedure and little toxicity to living things, photocatalytic degradation is noted as one of the best ways to address environmental problems, especially for the effective breakdown of organic pollutants. The present work was aimed at investigating the photocatalytic performance of oxides as ternary nanocomposites in the degradation of Direct Red 28 dye in aqueous solution under solar light. The solvothermal process was employed for the synthesis of Gray-TiO 2 /ZnO/α-Fe 2 O 3 composites. The constructed composite was characterized by means of FTIR, PL, XRD, and SEM, among other methods. The photocatalytic activity of the composite enhances up to 98.82% at pH 3, while it reduces up to 72.21% with an increasing concentration of initial dye at 30 mgL −1 . The synthesized composite had a degradation efficiency of around 99% for Direct Red 28 dye since its recombination rate was high. After the four cyclic runs of the used composite, 85% degradation of Direct Red 28 was observed, which substantiates that the Gray-TiO 2 /ZnO/α-Fe 2 O 3 composite is a stable and efficient catalyst.

研究领域: 环境科学 · 材料科学 · 化学工程 · 纳米技术 · 光催化 · 水处理 · 应用化学
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JOURNAL OF APPLIED TOXICOLOGY · 2015 ·Vol. 35 ·期 12 ·1473-1480 · IF 2.982

Toxicity induced by Basic Violet 14, Direct Red 28 and Acid Red 26 in zebrafish larvae

Bing Shen,Hong-Cui Liu,Wen-Bin Ou,Grant Eilers,Sheng-Mei Zhou,Fan-Guo Meng,Chun-Qi Li,Yong-Quan Li

Basic Violet 14, Direct Red 28 and Acid Red 26 are classified as carcinogenic dyes in the European textile ecology standard, despite insufficient toxicity data. In this study, the toxicity of these dyes was assessed in a zebrafish model, and the underlying toxic mechanisms were investigated. Basic Violet 14 and Direct Red 28 showed acute toxicity with a LC 50 value at 60.63 and 476.84 µg ml –1 , respectively, whereas the LC 50 of Acid Red 26 was between 2500 and 2800 µg ml –1 . Treatment with Basic Violet 14, Direct Red 28 and Acid Red 26 resulted in common developmental abnormalities including delayed yolk sac absorption and swimming bladder deflation. Hepatotoxicity was observed in zebrafish treated with Basic Violet 14, and cardiovascular toxicity was found in zebrafish treated with Acid Red 26 at concentrations higher than 2500 µg ml –1 . Basic Violet 14 also caused significant up-regulation of GCLC gene expression in a dose-dependent manner whereas Acid Red 26 induced significant up-regulation of NKX2.5 and down-regulation of GATA4 at a high concentration in a dose-dependent manner. These results suggest that Basic Violet 14, Direct Red 28 and Acid Red 26 induce developmental and organ-specific toxicity, and oxidative stress may play a role in the hepatotoxicity of Basic Violet 14, the suppressed GATA4 expression may have a relation to the cardiovascular toxicity of Acid Red 26. Copyright © 2015 John Wiley & Sons, Ltd.

CAS / MDL: 95-76-1
研究领域: 毒理学 · 分子生物学 · 发育生物学 · 环境科学
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