Regulation of selenium composition by supercritical carbon dioxide for CZTSSe solar cells efficiency improvement
Se-rich selenization offers remarkable benefits for grain growth of Cu 2 ZnSn(S,Se) 4 (CZTSSe) absorber layers , which is critical for solar cells fabrication. However, low-activity selenium often forms Se-clusters and trapped in CZTSSe absorber layers. These trapped Se-clusters increase carrier recombination in CZTSSe absorber layers, thus decreasing efficiency of CZTSSe solar cells. Herein, supercritical carbon dioxide (SCCO 2 ) treatment was demonstrated to regulate selenium composition of CZTSSe absorber layers for solar cells efficiency improvement. Compared with untreated CZTSSe absorber layers, selenium composition of CZTSSe absorber layers were significantly reduced by SCCO 2 treatment. The open circuit voltage ( V OC ) and fill factor (FF) of CZTSSe solar cells improved pronouncedly due to carrier recombination reduction and carrier transport enhancement. As a consequence, the power conversion efficiency (PCE) was increased from 9.26 % (ref device) to 11.43 % (SCCO 2 device). This unique SCCO 2 treatment may offer new ideas for other selenization-based optoelectronic devices performance improvement.
危险品化学品经营许可证（带存储）