The mechanical properties and ablation resistance of the Cf/ZrB2-SiC-C composites fabricated using a cost-effective strategy
Carbon fiber reinforced ultra-high temperature ceramic matrix composites (C f /UHTCMCs) are considered ideal materials for thermal protection components in hypersonic vehicles due to their outstanding overall performance. However, the existing fabrication techniques for C f /UHTCMCs face significant engineering challenges, including high raw material costs and complex processing methods. Here we propose a cost-effective fabrication strategy. This approach ensures the oxidation and ablation resistance of the material by incorporating sufficient ZrB 2 and SiC, followed by filling the remaining pores in the composite with in-situ derived pyrolytic carbon from furfuryl ketone resin, which significantly reduces fabrication costs and enables rapid densification. The C f /ZrB 2 -SiC-C composites produced by this strategy exhibit a flexural strength of 468 ± 18 MPa and a fracture toughness of 18.23 ± 1.14 MPa m 1/2 . Furthermore, the composites remain non-ablative when exposed to temperatures of 2300 °C for extended periods, with a mass ablation rate of only 4.14 × 10 −6 g/(mm 2 ·s) after 400 s of testing. This strategy offers significant design versatility and can be applied to various ultra-high temperature ceramic systems, offering a novel and cost-effective approach to the development of thermal protection materials for hypersonic vehicles.
危险品化学品经营许可证（带存储）