MODERN PHYSICS LETTERS B
·
2024
·
IF 1.8
Li Liu,Qifu Bao,Tiangui Zhao,Kun Liu,Detai Shi,Siyu Li,Wei Zhu,Xiaolong Li,Jianer Zhou
A series of Zn 1 − x Fe x O ( x = 0 , 0.015, 0.045, 0.075) nanoparticles were synthesized using the solution co-precipitation method, and their structural and property characteristics were investigated. X-ray diffraction (XRD) analysis revealed that all Zn 1 − x Fe x O samples exhibited a hexagonal wurtzite crystal structure with the P63mc space group. The introduction of Fe doping led to a slight lattice distortion in the samples. The morphology of the nanoparticles, including polydispersion and agglomeration, as well as the presence of the second phase ZnFe 2 O 4 , was examined by scanning electron microscope (SEM) and transmission electron microscope (TEM). UV–Vis diffuse reflectance spectroscopy demonstrated that the band gap of Zn 1 − x Fe x O lies between 3.152 and 3.163 eV. With the increase in Fe ion doping, the band gap shows a slight decreasing trend. Mössbauer spectroscopy revealed that iron ions in the nanoparticles existed in a trivalent state and exhibited two different configurations: One involved iron replacing zinc without creating a vacancy, while the other involved iron substituting zinc with a vacancy. The ferromagnetic nature of the Fe-doped samples can be attributed to the exchange interaction between two Fe 3 + ions mediated by the F-center mechanism.
研究领域:
材料科学
·
物理学
✓ 已验证
DOI
高影响因子
PHYSICA B-CONDENSED MATTER
·
2022
·
IF 2.988
Jiyu Shen,Jiajun Mo,Zeyi Lu,Yucheng Tao,Kaiyang Gao,Min Liu,Yanfang Xia
The wide application of LaMn 0.5 Fe 0.5 O 3 perovskite is due to its very complex magnetic and structural properties. Orthorhombic perovskite structure samples were prepared by sol-gel method. The system has a special spin glass state (Néel temperature below freezing temperature). Therefore, there is a transition for the main magnetic phase from strong antiferromagnetism to ferrimagnetism and finally to superparamagnetism as the temperature increases. The typical ferromagnetic and antiferromagnetic competing exchange bias phenomenon appears in the M − H curve at 5 K. We have simulated the thermal and magnetic characteristics of the system through the XYZ model and particle swarm optimization and obtained accurate anisotropy parameters. The transitions of the Mössbauer spectra at different temperatures reflect the changes in the macroscopic magnetic properties of the system. Finally, we can explain the relaxation peak behavior of Mössbauer spectra well by the relationship between the relaxation hyperfine field and temperature. This study will provide a good illustration and reference for the magnetic nature of strongly magnetic disordered LaMn 0.5 Fe 0.5 O 3 systems.
研究领域:
材料科学
·
物理学
✓ 已验证
产品关联
DOI
高影响因子
CERAMICS INTERNATIONAL
·
2024
·
IF 5.1
Zhenyu Xu,Han Liu,Weiping Zhou,Wanchun Yu,Guoqiang Xiao,Di Lu,Fei Gao,Zhenzhi Cheng,Guangsheng Luo
In this study, the impact of Gd 3+ doping on the structural, magnetic and dielectric properties of BaSrCo 2 (Fe 1- x Gd x ) 11 AlO 22 ( x = 0, 0.02, 0.04, 0.06, 0.08, 0.1) ferrite ceramics synthesized by the conventional solid-state reaction method are investigated. XRD results reveal that all the samples crystallize in the R 3 ‾ m space group. With the increase of Gd content, the formation of M-type phase is effectively inhibited due to Gd 3+ ions may change the activation energy of nucleation of the grains and the formation energy of hexaferrite. SEM analysis confirms the presence of hexagonal grains in samples with homogeneous elements distribution. The XPS results verify the coexistence of ferric and ferrous ions in the ceramics. The magnetization and coercivity are suppressed by Gd 3+ substitution. The permeability increases firstly and then decreases with the substitution of Gd ions. While the dielectric constant increases with the substitution of Gd. The real and imaginary parts of the dielectric constant in the frequency range of 2–18 GHz change slightly with doping amounts variation, and all the samples exhibit prominent peaks at about 14 GHz due to natural resonance.
研究领域:
材料科学
·
物理学
✓ 已验证
产品关联
DOI
高影响因子
Nanomaterials
·
2024
·Vol. 14
·期 10
·834
·
IF 4.4
Yuntian Du,Pengxiang Zhang
The value of two-dimensional (2D) materials in printed electronics has been gradually explored, and the rheological properties of 2D material dispersions are very different for various printing technologies. Understanding the rheological properties of 2D material dispersions plays a vital role in selecting the optimal manufacturing technology. Inkjet printing is suitable for small nanosheet sizes and low solution viscosity, and it has a significant advantage in developing nanosheet inks because of its masklessness, high efficiency, and high precision. In this work, we selected 2D Ti0.8Co0.2O2nanosheets, which can be synthesized in large quantities by the liquid phase exfoliation technique; investigated the effects of nanosheet particle size, solution concentration on the rheological properties of the dispersion; and obtained the optimal printing processing method of the dispersion as inkjet printing. The ultrathin Ti0.8Co0.2O2nanosheet films were prepared by inkjet printing, and their magnetic characteristics were compared with those of Ti0.8Co0.2O2powder. The films prepared by inkjet printing exhibited long-range ordering, maintaining the nanosheet powders’ paramagnetic characteristics. Our work underscored the potential of inkjet printing as a promising method for fabricating precisely controlled thin films using 2D materials, with applications spanning electronics, sensors, and catalysis.
研究领域:
材料科学
·
电子工程
✓ 已验证
产品关联
DOI
PubMed
高影响因子
BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA
·
2024
·Vol. 38
·期 5
·1251-1260
·
IF 1.3
Da-Chuan Ge,Wen Zhu,Yu-Xuan Li,Feng Zhang,Yun Chen,Jian-Hua Sun,Zhao-Xi Wang
Perovskite-like compounds have attracted great attention because of their good properties, such as electrical, optical, and magnetic properties, etc. Herein, a new perovskite-like anionic dicyanamidometallate, namely (Bu3MeP)[Ni(dca)3] (1) (Bu3MeP = tributylmethylphosphine cation, dca = dicyanamide), was synthesized and structurally characterized by elemental analysis, IR spectrum, thermogravimetric analysis, and single-crystal X-ray diffraction. The compound crystallizes in the tetragonal crystal system with the chiral space group P43212, and exhibits a three-dimensional anionic dicyanamidometallate framework from Ni2+ units bridged by dicyanamides, in which tributylmethylphosphine cations are accommodated in the voids. The butyl groups present two conformations in the tributylmethylphosphine cation, resulting in chirality character occurred in compound 1. Variable-temperature magnetic susceptibility analysis indicates that weak ferromagnetic interaction exists between the nickel(II) ions coupling by μ1,5-bridings.
KEY WORDS: Perovskite-like, Dicyanamidometallate, Crystal structure, Magnetic properties
Bull. Chem. Soc. Ethiop. 2024, 38(5), 1251-1260.
DOI: https://dx.doi.org/10.4314/bcse.v38i5.5
研究领域:
材料科学
·
化学
✓ 已验证
DOI
高影响因子
RSC Advances
·
2015
·Vol. 6
·期 1
·409-421
·
IF 3.84
Ayyakannu Sundaram Ganeshraja,Subramani Thirumurugan,Kanniah Rajkumar,Kaixin Zhu,Yanjie Wang,Krishnamoorthy Anbalagan,Junhu Wang
The structural, electronic, magnetic and photocatalytic properties of Sn doped TiO2 diluted magnetic semiconductor nanoparticles (NPs) prepared by a simple hydrothermal method were systematically investigated by various conventional techniques and 119Sn Mössbauer spectroscopy. Anatase, mixed (anatase–rutile) and rutile phases of Sn–TiO2 NPs were obtained by adding different amounts of SnCl4 into a titanium nitrate aqueous solution. Photocatalytic degradation of methyl orange and phenol derivatives (RPhOH) were studied under visible and UV light irradiation in water, respectively. The photocatalytic activities of prepared NPs were found to be drastically related to the structural, optical and ferromagnetic properties. A significant relationship was observed between the Hammett substitution constants of RPhOH and the photocatalytic activity. Among all the samples, the anatase phase with low Sn content performed with the best photocatalytic and ferromagnetic characteristics at room temperature.
研究领域:
材料科学
·
环境科学
·
物理学
✓ 已验证
产品关联
DOI
高影响因子
CERAMICS INTERNATIONAL
·
2024
·
IF 5.1
Huan Li,Jie Wang,Shoutao Lv,Chuming Chen,Haocheng Luo,Qiong Wu,Qiangyuan Zhang,Hui Zheng,Liang Zheng
The controllable Curie temperature and high magnetic permeability of NiCuZn ferrites make them promising candidates for magnetic thermal medium. However, the temperature control of existing NiCuZn ferrite materials is not accurate enough to achieve the low Curie temperature required for tumor hyperthermia. In order to further achieve the desired Curie temperature and facilitate the advancement of temperature control materials for tumor hyperthermia, Cr–Mg co-doped NiCuZn ferrite was studied. The study investigated the influence of varying concentrations of Cr 3+ on the crystal structure and magnetic properties of Mg–NiCuZn ferrites. The results of structural characterization demonstrate that Cr–Mg co-doped NiCuZn ferrites exhibit high density and uniform distribution of elements. The introduction of Cr 3+ leads to a reduction in lattice parameters and a preference for octahedral B-sites. The hysteresis loop results show that the saturation magnetization first increases and then decreases with the increase of Cr 3+ concentration. Ni 0.09 Mg 0.20 Cu 0.14 Zn 0.60 Fe 1.89 Cr 0.050 O 3.94 ferrite at 0.30 wt% of Bi 2 O 3 exhibits optimal magnetic characteristics, including a saturation magnetization of ∼36.7 emu/g, low coercivity of ∼0.07 kA/m, high permeability of ∼982.43 @1 MHz, and an appropriate Curie temperature of 45.59 °C. Such permeability and Curie temperature can be used in the body cavity perfusion hyperthermia and deep thermal therapy.
研究领域:
材料科学
·
生物医学工程
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
·
2021
·Vol. 32
·期 8
·11028-11042
·
IF 2.478
Tang Ping,Cao Ming,Yu Jian,Wang Lifang,Zhang Deqin
Bi 1− x Ba x Fe 1− y Cr y O 3 (BBFCO: x = 0, y = 0; x = 0.05, y = 0; x = 0, y = 0.05; x = 0.05, y = 0.05; x = 0.1, y = 0; x = 0, y = 0.1; x = 0.1, y = 0.1; x = 0.2, y = 0) nanoparticles were prepared by a simple cost effective ethylene glycol-based sol–gel technique. The calcination temperature was set at 600 °C for 120 min with a heating rate of 10 °C/min. Effects of Ba, Cr dopant on structural, optical and magnetic properties of BiFeO 3 (BFO) nanoparticles have been studied. Perovskite structure was confirmed by the metal-oxide absorption bands appeared at 559 cm −1 and 438 cm −1 in Fourier-transform infrared spectroscopy spectra, which are the characteristic bands of FeO 6 octahedral groups in perovskite structure. X-ray diffraction patterns confirmed that Barium (Ba) is an effective dopant to suppress the impurity phases in Cr-doped BFO. Phase transitions from rhombohedral to orthorhombic phase in all doped samples were verified by Rietveld refinement and Raman analysis. Rhombohedral, orthorhombic and tetragonal phases coexist in Bi 0.9 Ba 0.1 FeO 3 and Bi 0.8 Ba 0.2 FeO 3 , which can be ascribed to the serious lattice distortion due to high-level Ba doping. Well-crystalline BBFCO nanoparticles were observed and the particle size distribution of all samples was calculated from transmission electron microscope images. Ba–Cr co-doping resulted in a dramatic reduction in the particle size. Optical absorption spectra indicated that the optical bandgaps of the doped samples are about 2.20 eV. Clear hysteresis loops were observed in all doped BFO, which indicate their ferromagnetic order at room temperature. Gradually enhanced ferromagnetic property was realized in Ba-doped BFO. The magnetization (at 20 kOe) of BFO, BFO-5Ba, BFO-10Ba and BFO-20Ba are 0.24, 0.33, 1.00 and 1.25 emu/g, respectively. The remanent magnetization of them are near zero, 0.08, 0.44 and 0.53 emu/g, respectively. Particular shape of wasp-waist hysteresis loops observed in BFO-5Ba, BFO-5Cr and BFO-5BaCr can be ascribed to the coexistence of different magnetic phases, and the mixture of single domain and superparamagnetic particles.
研究领域:
材料科学
·
物理学
✓ 已验证
DOI
高影响因子
CERAMICS INTERNATIONAL
·
2025
·
IF 5.6
Chunlin Yang,Donghao Sun,Meigui Ou
In this paper, three kinds of nano-composites (Ho 2 O 3 /GQD, Ho 2 O 3 /N-GQD, Ho 2 O 3 /N,S-GQD) were prepared by hydrothermal synthesis, and their fluorescence and magnetic properties were characterized. The results show that elemental doping could promote the electronic Cπ-Nπ∗ leaps. In the composite process of Ho 2 O 3 and GQD or doped GQD, Ho and C are connected by O to form a new HO-O-C covalent bond. Compared with Ho 2 O 3 /GQD, the fluorescence intensity of Ho 2 O 3 /N-GQD and Ho 2 O 3 /N,S-GQD increased by 26.9 % and 61.4 % respectively, The magnetization of Ho 2 O 3 /N-GQD (VO1) (2.84emu/g) is slightly higher than that of Ho 2 O 3 /GQD (2.05emu/g). The magnetization of Ho 2 O 3 /N,S-GQD (VO2) is 3.09emu/g, about 1.5 times that of Ho 2 O 3 /GQD. After 2 h and 4 h of ultrasonic vibration treatment, the magnetic properties of doped Ho 2 O 3 /GQD were significantly improved due to the increase of oxygen-vacancy induced activation sites.
研究领域:
纳米材料科学
·
物理化学
✓ 已验证
产品关联
DOI
高影响因子
RARE METALS
·
2021
·Vol. 40
·期 6
·1554-1560
·
IF 4.003
Hu Zhi-Da,Sun Xi-Yu,Li Hang-Fei,Kang Ya-Ru,Song Xian-Qiang,Wang Peng,Luan Qiao-Tong,Wang Xue-Dong,Chi Zong-Tao,Xie Wan-Feng
Abstract Metal sulfide nanomaterials have attracted great interest because of their excellent properties and promising applications in sensing, energy harvesting, magnetic and optoelectronic devices, especially their well-aligned crystalline nanostructures are highly desirable for the enhanced performance and novel applications. In this study, the cobalt monosulfide (CoS) nanofibers with uniform shape and good crystallinity were firstly obtained via electrospinning and atmospheric calcination routes under controllable conditions. It was found that the CoS nanofibers exhibited ethanol sensing properties at the optimum working temperature of 200 °C, the response was 11.6 toward 100 × 10 −6 ethanol gas, and the CoS nanofibers-based sensor exhibits a short response time and recovery time of 5 and 6 s at the optimum temperature, respectively, the result also shows that the sensor has good stability after 50 days, which would be a favorable characteristic as a promising sensor. In addition, the Pauli paramagnetic property of CoS nanofibers was also investigated at room temperature. Graphic abstract
研究领域:
材料科学
·
传感技术
·
磁学
✓ 已验证
产品关联
DOI
高影响因子
CHEMICAL PHYSICS
·
2020
·
IF 1.771
M. Khizar Shafique,Tahir Muhmood,S. Lin,Z. Cai,J. Xiao,H. Xiaobin
Single-crystal nickel micro-particles have been synthesized using oleylamine which perform both functions, as solvent and as reductant, along with nickel nitrate hexahydrate as the metallic salt and C-TAB as a surfactant. SEM imaging and X-ray techniques were used to confirm the presence of the single-crystal structure of nickel micro-particles. The effect of crystallinity on field-based and especially temperature based magnetic properties resulting in higher curie temperatures of nickel micro-particles was also analyzed. Their morphology and magnetic properties were compared with commercially obtained nickel micro-particles and a variety of other nickel microparticles prepared by using different surfactants in the same system.
研究领域:
材料科学
·
物理学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
·
2022
·Vol. 53
·期 1
·145-151
·
IF 0.582
Zhang Lirong,Qi Feiyan,Shele Muge,Namila E.,Qi Liming,Baiyin Menghe
One quaternary selenidoantimonate of [Mn(en) 3 ]CdSb 2 Se 5 ( 1 ) (en = ethylenediamine) was prepared under 1,2-propanediamine condition by mild solvothermal method. Single-crystal X-ray diffraction analysis reveals that compound 1 crystallizes in the monoclinic space group C 2/c. Its structure consists of infinite 1D [CdSb 2 Se 5 ] n 2n− anionic chains and [Mn(en) 3 ] 2+ cations. Meanwhile, “Z” shaped eight-membered [Cd 2 Sb 2 Se 4 ] and six-membered [CdSb 2 Se 3 ] rings are alternately found. As estimated from UV–Vis absorption spectrum, the band gap of 1 is 2.58 eV. Compound 1 also showed rapid response and excellent reproducibility based on photoelectric test. In addition, the magnetic and other properties of 1 were studied. Graphical Abstract The manuscript describes the synthesis, crystal structure, single-crystal X-ray diffraction, elemental analysis, photoelectric response, thermogravimetric analysis, magnetic properties, infrared spectroscopy and UV-Vis diffuse reflectance spectroscopy of [Mn(en) 3 ]CdSb 2 Se 5 . The photoelectric response of compound 1 was explored, and a highly repetitive and stable photocurrent curve was found, indicating that 1 is a typical p-type semiconductor. In addition, the magnetism of compound 1 was also studied, which showed that 1 had antiferromagnetic behavior.
研究领域:
材料科学
·
化学
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）