Zexuan He,Jifei Chang,Yujie Feng,Shu Wang,Qing Yuan,Danhui Liang,Jia Liu,Nan Li
Vivianite widely existed in digested sludge and activated sludge as a potential phosphate resource recovered from wastewater treatment plants (WWTPs). As an important product of extracellular electron transfer (EET) and biological iron reduction, the production of vivianite can be enhanced by conductive materials. Carbon nanotubes (CNTs) with excellent electrical conductivity have been reported to promote electron transfer, which was applied in wastewater treatment to accelerate the degradation of the contaminants. However, the impact of CNTs on vivianite formation was barely reported. In this study, the iron reduction, vivianite recovery, and the biotoxicity of CNTs were investigated in order to determine the influence of CNTs towards the vivianite production. The enhancement of vivianite production after CNTs adding reached up to 17 % by promoting the electron transfer between dissimilative iron-reducing bacteria (DIRB) and Fe(III). However, at the initial stage (0–24 h), Fe(III) reduction efficiency decreased by 81 % after inoculating with sewage sludge, which was attributed to CNTs destroying of the cell membrane (as indicated by SEM, CLSM and AFM analysis). The biotoxicity of CNTs stimulated DIRB to secret extracellular polymeric substances (EPS) and form bio-flocs to resist the physical puncture. After 48 h, the proportion of living DIRB in 1000 mg/L CNTs batch increased to 98 %, which was 79 % higher than 12 h. As a result, the vivianite recovery of raw sewage with 1000 mg/L CNTs increased to 44 ± 1 %, which was 33 % higher than that in the CNT-0.
In this study, nanoscale zero-valent iron (NZVI) was synthesized by conventional liquid-phase chemical reduction methods without a support material and then characterized by transmission electron microscopy (TEM), scanning electron microscopy (SEM) and X-ray diffraction (XRD). The effect of NZVI particles on phosphate removal from aqueous solutions was examined. The results showed that the phosphate removal efficiency increased from 34.49% to 87.01% as the dosage of nanoscale iron particles increased from 100 to 600 mg L−1 with an initial phosphate concentration of 10 mg L−1, and the phosphate removal efficiency decreased from 72.89% to 51.39% as the initial phosphate concentration increased from 10 to 90 mg L−1, with 400 mg L−1 NZVI. Phosphate removal efficiencies of 99.41% and 95.09% were achieved at pH values of 2 and 4, respectively, with an initial phosphate concentration of 20 mg L−1 and 400 mg L−1 NZVI. The use of NZVI particles synthesized in a carboxymethyl cellulose (CMC)–water solution significantly enhanced phosphate removal from an aqueous solution compared with the use of NZVI synthesized in an ethanol–water solution. NZVI particles achieved 71.34% phosphate removal, which was remarkably higher than that of microscale zero-valent iron (MZVI) particles (16.35%) with 10 mg L−1 of phosphate and 400 mg L−1 iron. Based on the removal mechanism analysis performed in this study, we recommend that phosphate removal be accomplished by simultaneous adsorption and chemical precipitation. The XRD patterns of the NZVI before and after the reactions indicated the formation of crystalline vivianite (Fe3(PO4)2·8H2O) during the procedure.
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