In this paper, low-temperature preparation of rice husk char/TiO2 composite was developed by utilizing agriculture waste. nanosized TiO2 particles were successfully loaded to rice husk char by in-situ thermal treatment of impregnated rice husk. The structural characteristics and photocatalytic activities of obtained composites were investigated. The specific surface area of rice husk char was enlarged due to the catalytic effect of loaded TiO2 during thermal treatment. The porous rice husk char matrix combined with nanosized TiO2 particles offered large specific surface area and good photocatalytic property. This low-temperature preparation method provided a promising way to reuse the waste biomass and extended the applications of charcoal.
Wang Y. B.,Deng X. L.,Cao B. Y.,Feng H. P.,Chen J.,Li P. D.,Ren L.,Zhang M. Y.
In this article, a strategy is proposed to prepare highly toughened composites from polypropylene (PP), rice husk charcoal (RHC) and glycidyl methacrylate (GMA)-modified EPDM using melt blending and hot pressing. The structure of GMA-modified EPDM is confirmed by Fourier transform infrared spectroscopy (FTIR). The influences of the amounts of EPDM and GMA-modified EPDM on PP composites are investigated by virtue of mechanical properties testing, dimensional stability analysis, thermogravimetric analysis (TGA), X ray diffraction (XRD) and scanning electron microscopy (SEM). The results indicate that the incorporation of GMA-modified EPDM significantly improves the toughness of PP composites and compared to PRHC the impact strength of PRKEG10 is up to the value of 537 J/m and increases by 555%, concurrently the tensile strength and modulus exhibit less decrease with the value of 8.22 MPa and 353 MPa, respectively. Shrinkage measurements show the dimensional change rates of length, width, and height decrease from 3.2%, 2.9%, and 3.3% to 1.73%, 1.46%, and 1.93%, respectively, improving the dimensional stability of PP composites. SEM reveals that shear yield and cavitation during the loading process lead to the excellent toughness of PP composites. This strategy provides a novel route to fabricate high ductility rice husk charcoal-based PP composites and expand certain industrial application.