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JOURNAL OF APPLIED POLYMER SCIENCE · 2022 ·Vol. 139 ·期 23 ·52314 · IF 3.057

Voltage stabilizer and nanofiller in enhancement of insulation properties of cross-linked polyethylene

Xiangrong Chen,Zelin Hong,Chao Dai,Muhammad Awais,Fan-Bo Meng,Ashish Paramane,Hao Li

This paper investigates the influence of voltage stabilizer and nanofiller addition on the insulation performance of the cross-linked polyethylene (XLPE). The test samples of XLPE/stabilizer blends consisting of 1 wt% m-aminobenzoic acid, XLPE nanocomposites consisting of 0.5 wt% nano MgO and XLPE hybrid composite consisting of both voltage stabilizer and nanofillers were prepared. Various physicochemical and electrical properties were measured to analyze the performance of prepared samples. The obtained results show that the addition of nanofillers deteriorates the electrical insulation performance of the XLPE. On the other hand, the voltage stabilizer addition proves to be suitable for enhancing the electrical insulation performance of the XLPE. Meanwhile, the hybrid XLPE composites have shown medium behavior. The voltage stabilizer addition reduces, but the nanofillers increase the space charge density inside the XLPE compared to pure XLPE. It is also found that the dispersion of the voltage stabilizer in the material is uniform, whereas the nanofillers are aggregated. Furthermore, both additives slightly improve the thermal stability of the XLPE. The trap level theory based on quantum chemical calculation is proposed to explain the influence mechanism of the additives on the XLPE.

研究领域: 高分子材料科学 · 电气工程 · 绝缘材料 · 介电物理 · 材料化学 · 聚合物纳米复合材料
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JOURNAL OF APPLIED POLYMER SCIENCE · 2015 ·Vol. 133 ·期 1 · IF 1.768

Surface-modified MgO nanoparticle enhances the mechanical and direct-current electrical characteristics of polypropylene/polyolefin elastomer nanodielectrics

Yao Zhou,Jinliang He,Jun Hu,Bin Dang

Polypropylene (PP)/polyolefin elastomer (POE) blends and MgO/PP/POE nanocomposites were fabricated by melt blending. The morphology, mechanical, and electrical properties of the nanocomposites were investigated. Scanning electron microscopy showed that the surface-modified MgO nanoparticles were well dispersed in the polymer matrix at low loadings of less than 3 phr. X-ray diffraction demonstrated that the crystalline phases of PP in the composites were changed and that the β phase significantly increased. An examination of the electrical properties revealed that the direct-current (dc) electric breakdown strength and space-charge suppression effect were remarkably improved by the introduction of the surface-modified MgO nanoparticles. In addition, obvious enhancements in the tensile modulus and strength were obtained as a result of the synergistic toughening of the POE and MgO nanoparticles. Thus, MgO/PP/POE nanocomposites with enhanced mechanical and electrical properties have great potential to be used as recyclable insulation materials for high-voltage dc cables with large transmission capacities and high operating temperatures. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 132 , 42863.

研究领域: 高分子材料科学 · 电气工程材料 · 纳米复合材料 · 介电物理 · 绝缘材料
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