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JOURNAL OF COLLOID AND INTERFACE SCIENCE · 2019 · IF 6.361

Functionalization of polyethylene terephthalate knitted fabric with cowpea protein and biopolymer complex: Applications for enhancing wettability and UV-Protection properties

Hashim Sliman,Xue Dong,Tao Zhao

In recent years, increasing environmental awareness and human skin protection from harmful radiation of the sun has attracted attention amongst numerous researchers. Here, a simple strategy was developed to enhance the hydrophilicity and ultraviolet (UV) protection of polyethylene terephthalate (PET) knitted fabric surface via grafting green cowpea protein (CP) with gum arabic modified epoxy (GAE) as a cross-linking agent. Chemical grafting between pretreated PET and GAE as well as between GAE and CP improved the hydrophilicity and UV protection of PET knitted Fabric. The enhanced surface wettability was confirmed by the decreased water contact angle from 135° to zero °. Moreover, the UV protection factor rating of modified PET knitted fabric was higher, indicating that the modifier layer caused scattering and absorbance of UV light. This approach has shown promising results for improving hydrophilicity and UV protection with sustained mechanical durability of 7 washing cycles.

研究领域: 材料科学 · 纺织化学 · 表面工程 · 生物高分子 · 功能纺织品
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Small · 2024 ·Vol. 20 ·期 40 ·2400578 · IF 13

Anti-UV Passive Radiative Cooling Chiral Nematic Liquid Crystal Films for Thermal Management

Yike Du,Aotian Li,Fan Zhang,Han Gao,Xuan Zhou,Jiliang Zhu,Zhicheng Ye

Passive radiative cooling (PRC) can spontaneously dissipate heat to outer space through atmospheric transparent windows, providing a promising path to meet sustainable development goals. However, achieving simultaneously high transparency, color-customizable, and thermal management of PRC anti ultraviolet (anti-UV) films remains a challenge. Herein, a simple strategy is proposed to utilize liquid crystalline polymer, with high mid-infrared emissive, forming customizable structural color film by molecular self-assembly and polymerization-induced pitch gradient, which guarantees the balance of transparency in visible spectrum and sunlight reflection, rendering anti-UV colored window for thermal management. By performing tests, temperature fall of 5.4 and 7.9 °C are demonstrated at noon with solar intensity of 717 W m −2 and night, respectively. Vivid red-, green-, blue-structured colors, and colorless films are designed and implemented to suppress the solar input and control the effective visible light transmissivity considering the efficiency function of human vision. In addition, temperature rise of 11.1 °C is achieved by applying an alternating current field on the PRC film. This study provides a new perspective on the thermal management and aesthetic functionalities of smart windows and wearables.

研究领域: 材料科学 · 高分子化学 · 光学工程 · 能源材料 · 纳米科技
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Sustainable Materials and Technologies · 2024 · IF 8.6

Phosphonitrile hybrid metal-polyphenol network: An effective strategy for developing functional PVA composites with flame retardancy, antibacterial and UV resistance

Wei Tan,Chunlong Zuo,Yin Tian,Lu Bai,Lina Jiang,Jieyun Zhao,Xiaoyu Liu,Yuanlin Ren,Xiaohui Liu

The white pollution caused by non-degradable plastics poses a serious threat to human society and the environment, thus developing biodegradable material is urgent. In this work, a novel phosphonitrile hybrid metal-polyphenol network was constructed and used for the preparation of flame retardant , UV resistant and antibacterial multifunctional polyvinyl alcohol composite (PVA@HCPD-Ag). The limiting oxygen index (LOI) value of PVA@HCPD-Ag was improved to 33.5%, while the peak heat release rate (PHRR) and total heat release (THR) decreased by 35.62% and 47.76%. Besides, the ultraviolet protection factor (UPF) value of PVA@HCPD-Ag was significantly improved from 4.63 of the original PVA to 482.79, while the tensile strength was increased by 10.23%. Furthermore, the inhibition efficacy of PVA@HCPD-Ag for E. coli and S. aureus was up to 98.12% and 99.99%. This work explored the synergistic flame retardant effect of in-situ reduced Ag 0 and phosphonitrile crosslinked polyphenol network and proposed an advanced strategy for developing high value-added functionalized PVA materials.

研究领域: 高分子材料科学 · 功能材料 · 纳米复合材料 · 生物医用材料 · 环境友好材料
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APPLIED SURFACE SCIENCE · 2018 · IF 4.439

Hydrothermal growing of cluster-like ZnO nanoparticles without crystal seeding on PET films via dopamine anchor

Deshan Cheng,Mantang He,Wenbin Li,Jihong Wu,Jianhua Ran,Guangming Cai,Xin Wang

Growing of ZnO nanoparticles on PET films without crystal seeding has been achieved by employing polydopamine as the anchor. The PDA layer was formed on the surface of PET film by the polymerization of dopamine. The PDA-PET was dipped into zinc precursors for hydrothermal growth of ZnO nanoparticles. Cluster-like ZnO nanoparticles were obtained and the special structure was affected by the growing time and zinc ion concentration. The surface morphology, structure and properties were characterized, and the functions including antimicrobial activity and UV protection of the ZnO-coated PET film were investigated. The developed facile hydrothermal approach without seeding will benefit the development of UV resistant and antimicrobial PET films.

研究领域: 材料科学 · 纳米技术 · 表面功能化 · 生物医用材料 · 高分子材料
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