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Directional growth of quasi-2D Cu2O monocrystals on rGO membranes in aqueous environments

Yimin Zhao,Quan Zhang,Jianbing Ma,Ruobing Yi,Lu Gou,Dexi Nie,Xiaona Han,Lihao Zhang,Yuetian Wang,Xintong Xu,Zhe Wang,Liang Chen,Ying Lu,Shengli Zhang,Lei Zhang

The preparation technology of unconventional low-dimensional Cu 2 O monocrystals, which exhibit specific crystal planes and present significantly unique interfacial and physicochemical properties, is attracting increasing attention and interest. Herein, by integrating a high-temperature oxidation process under vacuum and a pure-water incubation process under ambient conditions, we propose the self-assembled growth and synthesis of quasi-two-dimensional Cu 2 O monocrystals on reduced graphene oxide (rGO) membranes. The prepared Cu 2 O crystals have a single (110) crystal plane, regular rectangular morphology, and potentially well conductivity. Experimental and theoretical results suggest that this assembly is attributed to the pre-nucleation clusters aggregation and directional attachment of Cu and O on the rGO membranes in aqueous environment and cation-π interactions between the (110) crystal plane of Cu 2 O and rGO surface. Our findings offer a potential avenue for the discovery and design of advanced low-dimensional single-crystal materials with specific interfacial properties in a pure aqueous environment.