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Polymers · 2023 ·Vol. 15 ·期 17 ·3551 · IF 5

Effect of Fabric Substrate and Introduction of Silk Fibroin on the Structural Color of Photonic Crystals

Shu Yang,Hongming Xiang,Yingwen Wang,Kaikai Chen,Weihong Gao

Monodispersed polystyrene (PS) particles were prepared and deposited onto various kinds of textile fabrics using a gravity sedimentation method. The monodispersed PS particles were self-assembled on fabrics to form a photonic crystal, which has an iridescent structural color. The structural color of fabrics was determined by the bandgaps of photonic crystals. Moreover, the effect of the fabric substrate, including the raw materials, base color, and fabric weave, etc., on the structural color of the photonic crystals was studied. Scanning electron microscopy and UV-vis spectrometry were adopted to characterize the structure and optical performance of photonic crystals. The results indicate that the silk fabric with a black base color and satin weave contribute to a bright and pure textile structural color. In order to solve the problem of low color fastness of the structural color on the fabric surface, silk fibroin (SF) was introduced to the PS microsphere solution. Results show that the addition of SF slightly affects the brightness of the structural color, while it has a certain reinforcing effect on the structural color fastness to rubbing and washing.Keywords:photonic crystals;structural color;fabric substrate;silk fibroin;color fastness

研究领域: 材料科学 · 纺织工程 · 光学
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Advanced Energy Materials · 2024 · IF 24.4

Fabric-Based Stretchable and Breathable Backscattered Monitoring System

Hao Chen,Jun-Lin Zhan,Huan Xia,Jia-Ning Li,Ze-Hui Chen,Ming-Yang Geng,Hong-Tu Qu,Xin-Yu Lv,Chao Zhang,Lu Ju,Tong-Shuai Sun,Bu-Yun Yu,Zheng-Hao Kou,Wen-Zhe Song,Wei Zhang,Zheng-Ming Sun,Wei-Bing Lu

The demand for wearable monitoring devices in contemporary medicine has significantly increased, especially in dynamic environments where traditional bulky equipment is impractical. Conventional flexible wearable devices or systems suffer from limited air and moisture permeability, lack of stretchability, and high power consumption, which restrict their long-term usage and comfort. Herein, a stretchable and breathable backscattered monitoring system (SBBMS) is introduced, integrated with a fabric substrate. To address the challenges associated with fabric substrate system fabrication and encapsulation, a printing-cutting-transfer technology is proposed. This method enables the creation of unique, low-cost, high-precision, and robust circuit routing and electronic devices on fabric, maintaining high compatibility with commercial surface mounting technology while minimizing sacrifices in breathability. Additionally, a backscatter communication mechanism is designed and implemented to achieve wireless data transmission, which significantly reduces power consumption. Combined with energy management technology and hydrogel batteries, the SBBMS receives safe, multi-source, and eco-friendly energy support. Furthermore, through meticulous design, all modules—including the antenna, circuit, and battery—are made stretchable, providing the system with excellent strain-resistive performance. The approach paves the way for the development of breathable, high-performance, and highly integrated fabric-based wearable systems, catering to specific user groups such as athletes, soldiers, and pilots.

CAS / MDL: 872-50-4 9002-89-5
研究领域: 生物医学工程 · 材料科学 · 电子工程
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DYES AND PIGMENTS · 2024 · IF 4.1

Humidity /temperature/ pH multi-responsive fabric-based colorimetric sensor for detection and information encryption

Xingyun Gao,Jiaguang Meng,Yongzhen Wang,Yaming Liu,Chao Zhi,Lu Yang,YuQing Chen,Chao Wang

Relative humidity (RH), temperature, and pH as important environmental parameters that are closely related to industry, agriculture, and people's life. Therefore, the development of a colorimetric sensor that can monitor the RH, temperature, and pH in real-time is highly desired. In this work, a fabric-based flexible colorimetric sensor is easily manufactured by screen printing the mixture of cresol red (CR), thymol blue (TB) and boric acid (H 3 BO 3 ) on the fabric. Compared with the traditional single stimulus colorimetric sensor, this fabric device can respond to multiple stimulus factors including humidity, temperature, or pH. The simple coating treatment can endow the colorimetric sensor with fast response without compromising its flexibility. Exposed to different stimulus conditions, the colorimetric sensor has a unique color change effect, such as humidity-responsive pink-yellow, temperature-responsive yellow-pink, and pH-responsive pink-purple. The flexibility and versatility of the fabric sensors are showcased with the applications in temperature/humidity/pH detection, cultural relics protection and information encryption. We believe the colorimetric sensor would have potential in environmental monitoring, health care, encrypted information patterns, and intelligent wearables, etc.

研究领域: 材料科学 · 环境科学 · 传感技术
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Materials Science and Engineering B-Advanced Functional Solid-State Materials · 2023 · IF 3.6

Textile-based dual-mode organic electrochemical transistors for lactate biosensing

Yang Tao,Rufeng Zhu,Panpan Hao,Wei Jiang,Mufang Li,Qiongzhen Liu,Liyan Yang,Yuedan Wang,Dong Wang

The dual-mode organic electrochemical transistors (OECT) were successfully assembled on fabric. The property of different devices has been compared. In the depletion mode, the PEDOT: PSS/textile-based OECT exhibit high transconductance of 75 mS, and the switching ratio of 8 × 10 2 . In accumulation mode, the PEDOT: PSS/DETA/textile-based OECT exhibit transconductance of 0.55 mS, switching ratio can reach 31.7. Both modes have good cycle stability. A lactate (LA) sensor was prepared by modifying the gate electrode with lactate oxidase. The sensitivity of the sensor is 69.97 mV/decade and 47.8 mV/decade in the depletion and accumulation mode, respectively. The LA sensor in both modes has good linear response in a wide concentration range of 100 pM-10 mM. The sensor has been successfully applied to the detection of LA in sweat sample. It has the advantages of simple preparation, good performance, and convenient integration into clothes, which provides a feasible platform for intelligent wearable and portable medical detection.

CAS / MDL: 50-21-5 69-93-2 50-70-4
研究领域: 生物医学工程 · 可穿戴设备 · 传感器技术
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Nano Energy · 2024 · IF 16.8

Multiphase soft metal enabled high-performance fabric-based wearable energy harvesting

Jiangtao Guo,Liangfei Duan,Wen Yang,Qin Wang,Yunbo Zhang,Yong Zhang,Zhong Lin Wang,Peizhi Yang

Highly efficient and flexible power sources have always been the focus and goal in the field of wearable electronics. However, the existing wearable power sources are limited by their large size, high weight, electrolyte leakage, and poor mechanical compliance, which seriously hinders their practical applications. Herein, we propose a novel strategy to achieve and demonstrate a fabric-based high-performance wearable triboelectric nanogenerator (TENG) structure. The metals of gallium (Ga), bismuth (Bi), indium (In), and tin (Sn) are mixed according to specific mass ratios, and then they are transformed in liquid phase to form room-temperature multiphase soft metals of GaBiInSn. The material exhibits both metallic and fluidic properties, and possesses a characteristic of multiphase structure. The GaBiInSn material is directly deposited between polytetrafluoroethylene (PTFE) layers and nonwoven fabrics to establish multi-level conductive and frictional interfaces, creating charge transfer and solid-liquid hybrid dielectric layers. Therefore, the thin film-type triboelectric nanogenerators with a structure of PTFE/GaBiInSn/nonwoven fabric (LM-P-TENGs) is manufactured. The LM-P-TENGs can be integrated onto fabrics without compromising their breathability, comfortableness, and flexibility. Particularly, LM-P-TENGs efficiently convert the mechanical energy of human limb movements into sustainable electrical energy output. Under the human limb mechanical triggering conditions, LM-P-TENG achieves a champion specific open-circuit voltage up to 900 V, peak short-circuit current density of 43.3 mA/m 2 , and high power density of 12.56 W/m 2 . This work demonstrates the application potential of room-temperature multiphase soft materials in flexible wearable power sources, while introducing a novel power supply mode for wearable electronics. Additionally, the LM-P-TENGs also present applications in self-powered wearables, medical biosensing systems, human-machine interaction systems, near-eye display systems, etc. for the flexible electronics.

研究领域: 材料科学 · 能源技术 · 柔性电子学
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ADVANCED FUNCTIONAL MATERIALS · 2024 · IF 18.5

Diamond-Structured Fabric-Based Triboelectric Nanogenerators for Energy Harvesting and Healthcare Application

Taosif Ahmed,Yuanyuan Gao,Mei Yi So,Di Tan,Jian Lu,Junze Zhang,Qian Wang,Xinlong Liu,Bingang Xu

Wearable technology is experiencing remarkable progress, prompting the need for sustainable power sources like triboelectric nanogenerators (TENGs). However, integrating TENGs into fabrics and insufficient power outputs that allows for comfortable wear without obstructing user's movements presents a significant challenge. In this study, a novel kind of diamond-structured fabric-based triboelectric nanogenerators (DSF-TENGs) is introduced utilizing an easy, economical, and scalable weaving method without any chemical modification. Owing to its 3D diamond pattern, surface interactions are enhanced for greater charge generation together with strengthened mechanical engagement for more effective charge transfer. The DSF-TENG, with its unique self-resilient structure, achieves impressive electric performance, including output voltage of ≈763 V, short-circuit current of ≈20.4 µA, and power density of 2862.78 mW m −2 , which is multiple times higher than most existing fabric-based TENGs. It also offers excellent air permeability of 560 mm s −1 , consistent electricity generation and sensing even after ten washing cycles, and incredible durability, withstanding over 30 000 cycles. Furthermore, DSF-TENG is included in an insole that is capable of sensing gait patterns, walking speed, and fall detections of patients with Parkinson's disease. The remarkable power generation capabilities of DSF-TENG indicate a strong potential for future developments in wearable electronics and healthcare applications.

CAS / MDL: 12047-27-7
研究领域: 能源材料科学 · 生物医学工程 · 电子纺织品
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Small Methods · 2023 ·Vol. 7 ·期 9 ·2300227 · IF 12.4

All-In-One Evaporators for Efficient Solar-Driven Simultaneous Collection of Water and Electricity

Can Ge,Duo Xu,Heng Du,Xiaohan Zhang,Zheheng Song,Haoyue Zhao,Ze Chen,Beibei Song,Zhuoer Shen,Chong Gao,Guilong Yan,Weilin Xu,Jian Fang

The shortage of fossil fuels and freshwater resources has become a serious global issue. Using solar energy to extract clean water with a photothermal conversion technology is a green and sustainable desalination method. Integrated electricity generation during the desalination process maximizes energy utilization efficiency. Herein, a solar-driven steam and electricity generation (SSEG) system based on an all-in-one evaporator is prepared via a scalable technology. Carbon black is selected as the absorber for solar energy harvesting as well as the functional substance for simultaneous electricity generation. Fabric substrate with flexible structure, porous channel, and capillary effect is vital for directional brine supply, multiple solar absorption, and thermal management. The high evaporation rate (1.87 kg m −2 h −1 ) and voltage output (324 mV) can be achieved with an all-in-one device. The stable electricity output can be maintained over 40000 s. The SSEG performance remains constant after 15 operation cycles or 20 wash cycles. The integrated device balances excellent effectiveness and practicality, providing a viable path for clean desalination and electricity generation.

研究领域: 可再生能源 · 环境科学 · 材料科学 · 水处理
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