查找使用阿拉丁产品的科研文献

One-step synthesis of polypyrazoles and self-assembled polypyrazole–copper catalysts for click chemistry

Longqiang Xiao,Shaojun Cai,Qingye Liu,Liqiong Liao,Xin Guo,Yan Li,Xiangxiang Jia,Feifei Li,Lijian Liu

Polypyrazoles with molecular weights in the range of 6500–9300 g mol−1 and yields in the range of 71.4–82.5% were synthesized successfully by catalyst-free 1,3-dipolar cycloaddition of bisdiazo compounds to bisalkynes under thermal conditions and lost merely 5% of their weights at temperatures higher than 298 °C. The porous polypyrazole–copper complex with pore diameters in the range of 1–2 μm was prepared by the coordination of polypyrazole and copper sulfate (CuSO4), which is a reusable catalyst for the Huisgen 1,3-diploar cycloaddition of alkynes and organic azides to give the corresponding triazoles with yields over 90%.