阿拉丁SCI论文搜索工具

MATERIALS LETTERS · 2014 · IF 2.269

Colloidal synthesis of chalcostibite copper antimony sulfide nanocrystals

Yu Zou,Jiang Jiang

We report the colloidal synthesis of monodisperse phase pure chalcostibite CuSbS 2 nanocrystals in high boiling point solvent. The use of dodecanethiol as ligands had an advantage over oleylamine on avoiding the hydrolysis of Sb precursor. The effect of reaction temperature and Cu/Sb feed molar ratio on the synthesis of copper antimony sulfide nanocrystals in dodecanethiol system was investigated. As a result of the reactivity difference between Cu and Sb precursors, the formation of CuSbS 2 nanocrystals involves the preferential nucleation of Cu-rich nanocrystals and their subsequent reaction with remaining Sb precursors. The band gap of the resulting CuSbS 2 nanocrystals was measured to be ~1.59 eV.

研究领域: 材料化学 · 纳米科学 · 无机化学 · 半导体材料 · 胶体化学

✓ 已验证 DOI 高影响因子

查看原文查看 PubMed

Nanoscale · 2015 ·Vol. 7 ·期 9 ·4171-4178 · IF 7.394

Colloidal synthesis of greigite nanoplates with controlled lateral size for electrochemical applications

Tingting Li,Huanhuan Li,Zhennan Wu,Hongxia Hao,Jiale Liu,Tingting Huang,Haizhu Sun,Jingping Zhang,Hao Zhang,Zuoxing Guo

The excellent electrochemical performance of greigite (Fe3S4) coupled with its vast abundance and low toxicity make it a good prospect as an anode material for lithium ion batteries (LIBs). In this research, a simple and feasible approach for producing pure phase, small sized, shape-controllable, and stable Fe3S4 nanoplates (NPs) through hot injection of sulfur solution into Fe(III) solution was demonstrated. The growth of Fe3S4 NPs involves the primary formation of a pyrite (FeS2) nucleus and subsequent Fe(III) doping. The lateral size of the Fe3S4 NPs was controlled further by tuning the experimental variable-dependent reactivity of Fe sources in the nucleation and growth stage. The Fe3S4 NPs embedded in LIBs present a low electrochemical resistance and are highly active in lithiation/delithiation processes.

研究领域: 材料科学 · 纳米科技 · 电化学 · 能源存储 · 无机化学

✓ 已验证 DOI 高影响因子

查看原文查看 PubMed

查找使用阿拉丁产品的科研文献

与阿拉丁产品相关的已发表科研成果

产品列表

Colloidal synthesis of chalcostibite copper antimony sulfide nanocrystals

Colloidal synthesis of greigite nanoplates with controlled lateral size for electrochemical applications