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Journal of Analysis and Testing · 2022 ·Vol. 7 ·期 2 ·157-162 · IF 0

Automatic Determination of Water Hardness by Vector Colorimetry with Acid Chrome Blue K

Gao Su,Ye Ming-Liang,Ma Rui,Liu Ai-Rong,Gao Hong-Wen

Based on the Mg 2 + complexation with acid chrome blue K (ACBK) at pH 10.2, an automatic system was designed to determine total hardness of water. The system consists of a vector colorimeter, a multi-channel sampling pump and both reagents A and B. Two kinds of reagent solutions were prepared and used in this system, i.e., ammoniacal buffer and ACBK—disodium magnesium EDTA solutions. The experimental results of the standard solutions containing 2 and 3 mg/L of total hardness showed that the relative standard deviations (RSDs) were 1.9% and 2.2%, respectively, and the limit of detection (LOD) was only 0.035 mg/L. The detection of four natural water samples showed that the recoveries were between 85.0% and 108.6%, consistent with those obtained by ICP-AES method.

CAS / MDL: 7732-18-5 7440-02-0
研究领域: 分析化学 · 环境科学
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