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ACS Applied Electronic Materials · 2023 · IF 4.7

Self-Encapsulated Breathable Reduced Oxide Graphene-Coated Melamine Foam for Stress Sensing

Tingting Yu,Yebo Tao,Yali Wu,Dongguang Zhang,Jiayi Yang,Xingjun Liu

Three-dimensional graphene foam (GF)-based flexible piezoresistive sensors have the advantages of high conductivity, large deformable range and light weight, which has been utilized in human health measurement, electronic skin, and wearable devices. However, the encapsulation and electrode connections of such sensors reduce breathability, resulting in discomfort and even skin irritation. In this study, a self-encapsulated breathable GF (SEB–rGO–MF) and an SEB–rGO–MF-based piezoresistive sensor (SEB–rGO–MF–PS) are proposed. The SEB–rGO–MF–PS consists of a SEB–rGO–MF and two electrodes, ensuring encapsulation and electrical connection without compromising breathability and stability. We performed material characterization and breathability tests of the SEB–rGO–MF and investigated the sensing mechanism of the SEB–rGO–MF–PS. The SEB–rGO–MF–PS exhibits a sensitivity of 0.108 Pa–1, a measurement range of 0.013–15 kPa, rapid response/recovery times (83 and 166 ms), and excellent stability (2000 cycles at 15 kPa). In addition, this study demonstrates the application of the SEB–rGO–MF–PS for human motion monitoring.

CAS / MDL: 1330-20-7
研究领域: 材料科学 · 生物医学工程
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INDUSTRIAL CROPS AND PRODUCTS · 2025 · IF 6.2

Self-encapsulation of Fe-Co Prussian blue analogue inside delignified bamboo for the removal of indoor free formaldehyde

Honghui Yan,Xiangyu Wang,Yi Zhu,Yuding Zhu,Ruiqi Xin,Shunze Zhang,Meiling Chen,Song Li,Jeonghun Kim,Wenkai Zhu

Free formaldehyde poses significant health risks as a prevalent indoor organic pollutant, driving demand for efficient and renewable adsorption solutions. While Fe-CoPBA bimetallic metal-organic frameworks show potential for formaldehyde removal, their powdered crystalline form presents practical limitations including poor recyclability and secondary contamination. Herein, we developed a novel Fe-CoPBA@bamboo composite (Fe-Co@B) through solution blending, leveraging bamboo's inherent micro-nano hierarchical pores for Fe-CoPBA encapsulation. The Fe-CoPBA nanoparticles (NPs) successfully integrated into delignified bamboo conduits through hydroxyl-mediated ligand bonding and van der Waals interactions. Formaldehyde removal tests demonstrated Fe-Co@B's dual adsorption-catalysis mechanism effectively eliminates indoor free formaldehyde. The Fe-Co@B maintained stable removal efficiency for formaldehyde through 10 regeneration cycles while preserving structural integrity. Furthermore, the Fe-Co@B exhibits high reusability along with moisture and deformation resistance. Therefore, this work contributes to solving the current problem of indoor free formaldehyde pollution and provides research ideas for the development of new functional bamboo-based products.

研究领域: 环境科学 · 材料工程 · 纳米技术 · 室内空气质量 · 可持续化学
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ADVANCED MATERIALS · 2025 ·Vol. 37 ·期 8 ·2404698 · IF 26.8

Scalable Synthesis of 2D ErOCl with Sub-meV Narrow Emissions at Telecom Band

Panqi Huang,Youxuan Wu,Meng Gao,Junxin Chen,Bowen Ma,Jiuxiang Dai,Jing Zhang,Ziye Zhu,Wen Xiao,Zhitong Jin,Wu Zhou,Wenbin Li,Ya-Qing Bie,Lin Zhou

Van der Waals (vdWs) materials are promising candidates for hetero-integration with silicon photonics toward miniaturization and integration. VdWs materials like molybdenum telluride and black phosphorus, despite being prominent, exhibit air sensitivity, and their room temperature emissions can be significantly broadened by tens of meV. Here, a self-encapsulation strategy is developed to scalably synthesize robust 2D vdWs ErOCl with sub-meV narrow emissions at the telecom C-band. Diverse 2D rare earth materials are also grown via chemical vapor deposition (TmOCl, YbOCl, HoOCl, DyOCl, SmOCl, NdOCl, TbOCl, GdOCl, EuOCl, and PrOCl), demonstrating the strategy's generalizability. The as-grown ErOCl exhibits high crystalline quality and excellent ambient and thermal stability (300 °C). Photoluminescence analysis reveals a series of narrow emissions across the visible to near-infrared spectrum. The ErOCl's emission at the telecom band is narrowest among 2D luminescent materials, and suitable for integrating with photonic chips. Temperature-dependent photoluminescence spectra facilitate the understanding of emission mechanisms, analyzed using a crystal field perturbation model. Moreover, these emissions can be tuned by external magnetic fields. This research not only pioneers a novel strategy for synthesizing 2D rare earth materials but also paves the way for innovative building blocks in the realm of on-chip optical communications.

CAS / MDL: 7447-40-7 7647-14-5
研究领域: 材料科学 · 纳米光子学 · 光电子学 · 量子材料 · 集成光子学
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Nature Communications · 2024 ·Vol. 15 ·期 1 ·1-12 · IF 14.7

Self-encapsulated ionic fibers based on stress-induced adaptive phase transition for non-contact depth-of-field camouflage sensing

Liu Ying,Wang Chan,Liu Zhuo,Qu Xuecheng,Gai Yansong,Xue Jiangtao,Chao Shengyu,Huang Jing,Wu Yuxiang,Li Yusheng,Luo Dan,Li Zhou

Ionically conductive fibers have promising applications; however, complex processing techniques and poor stability limit their practicality. To overcome these challenges, we proposed a stress-induced adaptive phase transition strategy to conveniently fabricate self-encapsulated hydrogel-based ionically conductive fibers (se-HICFs). se-HICFs can be produced simply by directly stretching ionic hydrogels with ultra-stretchable networks (us-IHs) or by dip-drawing from molten us-IHs. During this process, stress facilitated the directional migration and evaporation of water molecules in us-IHs, causing a phase transition in the surface layer of ionic fibers to achieve self-encapsulation. The resulting sheath-core structure of se-HICFs enhanced mechanical strength and stability while endowing se-HICFs with powerful non-contact electrostatic induction capabilities. Mimicking nature, se-HICFs were woven into spider web structures and camouflaged in wild environments to achieve high spatiotemporal resolution 3D depth-of-field sensing for different moving media. This work opens up a convenient route to fabricate stable functionalized ionic fibers.

CAS / MDL: 9002-98-6 9002-89-5
研究领域: 材料科学 · 电气工程 · 传感技术 · 仿生学
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