ANALYTICAL CHEMISTRY
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2025
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IF 6.7
Chengzhuo Yu,Jin Xu,Li Xiong,Yarui Wang,Silong Wang,Fanglan Geng,Zesen Shang,Huasheng Wu,Lixia Zhao,Yawei Wang
Luminol-based chemiluminescence (CL) systems, as a powerful tool for bioanalysis, are limited owing to their weak CL intensity and self-decomposition of the classic oxidant H2O2. Herein, we introduced a new luminol CL enhancer, the natural light-driven photocatalyst MIL-100(Fe)/TiO2, for the selective determination of dopamine (DA). By employing MIL-100(Fe)/TiO2 for the first time as an efficient enhancer, the MIL-100(Fe)/TiO2-luminol CL intensity was 100 times higher than that of the classical H2O2-luminol system. The CL spectrum, UV–vis absorption spectroscopy, radical scavenger experiments, and electron spin resonance spectroscopy were utilized to investigate the possible CL mechanism of the MIL-100(Fe)/TiO2-luminol system. All of the results indicated that MIL-100(Fe)/TiO2 can generate reactive oxygen species under mild natural light, which could react rapidly with the luminol anion radical and result in direct CL emission. The sensitive plate for DA was developed based on its inhibiting effect on CL intensity, and the linear range between CL intensity and DA concentration was 100 nM–1000 μM with a detection limit of 16.7 μM (S/N = 3). This study successfully achieved a stable reactant that can directly trigger the CL of luminol without the need for additional oxidizing agents under mild natural light and offers new possibilities for photoinduced amplification technology.
研究领域:
分析化学
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生物医学工程
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DOI
PubMed
高影响因子
INORGANIC CHEMISTRY
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2024
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IF 4.3
Xudong Wu,Kaifu Yu,Yizhou He,Xin Cao,Tao Chen,Wenkun Zhu
The phenomenon of rapid migration of photogenerated charges in natural photosynthetic systems has motivated the design of efficient photocatalysts capable of fast charge separation and efficient reaction kinetics for photocatalytically assisted enrichment and separation of uranium U(VI) in uranium wastewater. In this study, we developed a biomimetic photocatalytic system MnOx/NH2-UiO-66-rGO (M/UiO-rGO) with spatially separated dual cocatalysts. Among them, rGO functions to capture electrons and participates in reduction reactions, while MnOx captures holes and participates in oxidation reactions. The M/UiO-rGO catalyst exhibits excellent performance in photocatalytic reduction of uranium (reaching 91.8% in 1 h), and even under natural light conditions, it exhibits excellent uranium removal ability (80.4%). Using multispectral coupling technology, we further confirmed that enriched uranium undergoes a continuous and complex reaction process of “capture-reduction-free radical oxidation–nucleation–crystallization”. This work presents a viable strategy for designing biomimetic photocatalysts with efficient charge separation and rapid reaction kinetics for environmental purification purposes.
研究领域:
环境科学
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材料科学
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产品关联
DOI
PubMed
高影响因子
CHEMOSPHERE
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2023
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IF 8.8
Jinghang Feng,Qingge Feng,Jingbo Xin,Qihua Liang,Xiang Li,Kao Chen,Jiayang Teng,Sinan Wang,Lin Feng,Junyi Liu
The practical application of photocatalytic coating has been greatly challenged in terms of its long-term effective natural light photocatalytic degradation due to its vulnerability and easy contamination caused by poor self-cleaning properties. In this work, photocatalytic coating with self-cleaning properties was prepared by spraying fluorinated dual-scale TiO 2 on the inorganic lithium silicate adhesive, enabling excellent durability and long-term effective photocatalytic degradation performance under natural light. The coating exhibits superhydrophobic properties even after abrasion testing, acid and alkali immersion testing, and UV aging, laying a foundation for the practical use. Moreover, the coating can be applied to various substrates and its excellent self-cleaning properties make it resistant to particulate and liquid contamination that may occur in the environment. Besides, we evaluated the photocatalytic stability of the coating by subjecting it to acidic and alkaline environments and high pollution concentrations. Furthermore, benefiting from the synergistic effect of photocatalytic and self-cleaning properties, the coating achieves long-term effective photocatalytic degradation of dye wastewater under natural light, which still has a high removal rate of 95.8% for methylene blue even after 30 cycles of use. Meanwhile, due to the coating's excellent durability, the long-term quality loss rate of the coating still remained below 0.3%, which avoids the risk of secondary environmental pollution caused by nanoparticle leakage . Therefore, these excellent properties enable the coating to have a broad range of application prospects for the treatment of pollutants in water.
研究领域:
材料科学
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环境科学
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产品关联
DOI
PubMed
高影响因子
Surfaces and Interfaces
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2024
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IF 5.7
Wenhao Zhang,Libin Zhang,Houjin Luo,Ciyuan Huang,Shangfei Yao,Shangjing Li,Lan Shen,Tao Yang,Hongxiang Zhu,Hongmin Sun,Bin Hu,Bingsuo Zou,Tao Liu
With the increasing pollution of water bodies by herbicides, there is an urgent need to develop an efficient and environmentally friendly photocatalyst using natural light. In this work, we combine the organic heterojunction PBDB-T:BTTIC-TT with biochar to design a low-cost photocatalyst-adsorbent with a higher density of reaction site and reduce the aggregation of the organic catalysts. By tuning the thiophene side chains of the acceptor in organic heterojunction, the visible-light absorption can be enhanced ∼18 % for better catalytic efficiency. The ·O 2 − is verified to play a major role during the photocatalytic process, and the degradation pathway of 2,4,6-trichlorophenol to small carboxylic acids is also revealed. The broader natural light response with the good adsorption of the photocatalyst can effectively enhance the 2,4,6-trichlorophenol removal rate up to 97.4 % within 1 h, and the excellent adaptability over a wide pH range as well as the great stability during 15 catalytic cycles shows the practical applications in the treatment of water bodies with different levels of herbicide pollution.
研究领域:
环境科学
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材料科学
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DOI
高影响因子
ChemCatChem
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2024
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IF 3.8
Chengzhuo Yu,Jin Xu,Yarui Wang,Silong Wang,Li Xiong,Fanglan Geng,Zesen Shang,Huasheng Wu,Jitao Lv,Lixia Zhao,Yawei Wang
Graphical Untill now, reactive oxygen species (ROS) are difficult to generate in the natural light conditions, since most photocatalysts require external strong stimuli. We surprisingly found the ROS generation on MIL-100(Fe)/TiO 2 driven by mild natural light. The ROS generation patterns and mechanism of MIL-100(Fe)/TiO 2 was revealed by chemiluminescence (CL) and density functional theory (DFT). Reactive oxygen species (ROS), as one kind of the most highly oxidizing oxidants, are difficult to generate and utilize in the natural light conditions, since many materials require external strong stimuli for ROS release to be effective as pollutant degradation or biocide. In this work, we surprisingly found the ROS generation on MIL-100(Fe)/TiO 2 driven by mild natural light. Then ROS generation patterns and mechanism was revealed by chemiluminescence (CL) and density functional theory (DFT). Meanwhile, rhodamine B (RhB) can also be removed by MIL-100(Fe)/TiO 2 under natural light, which further evidence the ROS generation under the natural light. This work provides a new direction for spontaneously generating ROS releasing without external strong stimuli and has the broad potential applications in the field of pollutant degradation or antimicrobials under natural conditions.
研究领域:
环境科学
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材料科学
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DOI
高影响因子
ELECTROCHEMISTRY
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2025
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IF 1.7
Hongyu CHEN,Ru TIAN,Jianke LI,Beibei HAN,Guoku LIU,Shiyu YIN,Guiying XU,Kun WANG,Fukuan WANG,Baigang AN,Dongying JU,Weimin ZHOU
TiO2 as a semiconductor photocatalyst has been extensively utilized in the purifications of water and air. However, the wide band gap of TiO2 necessitates its activation by ultraviolet irradiation, when it is utilized as a photocatalyst. To enhance the photocatalyst performance of TiO2, constructing the heterojunction containing TiO2 is considered as a highly effective method. To unfold the actual application, iron metal oxides are firstly utilized to construct the heterojunction of TiO2/α-Fe2O3, and the synthesized TiO2/α-Fe2O3 heterojunction was successfully coated on the surface of coal tar pitch based spherical activated carbons (CTP-SACs). The structures of TiO2/α-Fe2O3/CTP-SACs are verified by the X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM). The results of UV-vis absorption spectroscopy supports that TiO2/α-Fe2O3/CTP-SACs are promising candidates for the natural light photoncatalysis. It is believed that the exceptional conductivity of CTP-SACs enhances the activity of the photocatalyst, resulting in the TiO2/α-Fe2O3/CTP-SACs exhibiting remarkable sterilization effects under natural light. For instance, the TiO2/α-Fe2O3-60-CTP-SAC shows an excellent sterilization rate (89 %) for the fish culture water under the irradiation of natural light for 20 min. Associating with the excellent liquidity of CTP-SACs, it is considerable that TiO2/α-Fe2O3/CTP-SACs possess the captivating application prospects in a field of the feeding water treatment.
研究领域:
材料科学
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环境科学
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产品关联
DOI
PubMed
高影响因子
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
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2024
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IF 4.9
Daiyao Jiang,Tingting Wei,Kai Li,Fei Wang,Xin Sun,Jie Zhao
In this study, novel mixed matrix membranes (MMMs) composed of MoO 3 /Poly (vinylidene fluoride-co-trifluoroethylene) (P(VDF-TrFE)) with distinctive piezo-photocatalytic properties were prepared. The membranes were made from dopes containing a high ratio of MoO 3 to P(VDF-TrFE) (2:1 wt%/wt%) through a modified solvent evaporation method. The addition of MoO 3 particles significantly impacted the crystallization and self-polarization of the P(VDF-TrFE) matrix, leading to a substantial increase in total crystallinity from 46.4% to 88.9% and a transformation from α to β phase. The flow-induced piezoelectric potential created an internal electric field, enhancing the spatial separation of photogenerated carriers through the piezoelectric effect. Controlled water flow further promoted the spatial separation of carriers. The developed MMMs demonstrated a high Rhodamine B degradation rate, reaching 83.1% within 45 minutes and over 99% within 90 minutes under natural light conditions. The MoO 3 /P(VDF-TrFE) MMMs exhibit promising piezo-photocatalytic attributes and hold potential for diverse applications due to their unique combination of piezoelectric and photocatalytic properties.
研究领域:
材料科学
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环境科学
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DOI
高影响因子
APPLIED SURFACE SCIENCE
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2024
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IF 6.3
Mengtian Cui,He Wang,Xia Fan,Jianhao Zhang,Changrui Xing,Wenjing Yan
The widespread use of organophosphorus pesticides (OPPs) in foods, poses a serious threat to human and environmental health, it is crucial to develop methods that can efficiently degrade residual OPPs . Herein, a chiral TiO 2 photocatalyst was developed by modification TiO 2 with D-cys/Au NPs (DAT) for the simultaneous degradation of four OPPs (chlorpyrifos, chlorpyrifos-methyl, malathion, and parathion) by natural light. The influence of D-Au NPs concentration on the degradation process was optimized, along with the initial pesticide concentration. Under optimal conditions, the photocatalytic degradation efficiencies of DAT for four OPPs were 96.7 %, 56.9 %, 42.6 %, and 49.2 %, respectively, after 12 h of natural light exposure. 12 degradation products of OPPs were identified, among which three products were identified for the first time. The degradation pathway revealed that the degradation of OPPs by DAT involves the oxidation of the P═S bond and the cleavage of the P-O bond and C-O bond. This study establishes a theoretical foundation for applying chiral TiO 2 nanomaterials for the photocatalytic degradation of OPPs in foods.
研究领域:
环境科学
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食品科学
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材料科学
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产品关联
DOI
高影响因子
International Journal of Green Energy
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2023
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IF 3.3
Zefeng Zhang,Xianli Fang,Haiyan Qian
ZnS is a well-known photocatalyst in the field of water treatment, but its applicability is limited due to poor visible light sensitivity, low photon efficiency, and photo corrosion. In this study, a new type of ZnS/Ti3C2Tx composite photocatalyst was developed by growing ZnS microspheres on a single-layer Ti3C2Tx, which is based on the sheet-like structure and metal-like characteristics of Ti3C2Tx. The resulting Ti3C2Tx-based composite photocatalyst with ZT0.35% showed superior catalytic activity in the degradation of methyl orange under natural light. The catalytic rate constant was 3.51 times higher than that of ZnS alone, reaching a maximum of 0.0244 min−1. Within 120 minutes, the degradation rate of methyl orange was 96.3%, while that of ZnS was only 41.6%. Photoluminescence and free radical scavenging experiments revealed that the composite structure is responsible for the improved photocatalytic activity and that the ZnS/Ti3C2Tx structure is favorable for the separation and transport of photogenerated carriers. The developed ZnS/Ti3C2Tx composite has great potential as a photocatalyst for the degradation of organic contaminants.
研究领域:
材料科学
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环境科学
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产品关联
DOI
高影响因子
SOLID STATE SCIENCES
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2023
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IF 3.5
Huadong Liu,Hao Sun,Du Ke Zhen,Cheng Jing liang,Sun XiaoYu
Monoclinic bismuth vanadate (m-BiVO 4 ) is a well-known photocatalytic material. However, its poor charge transport and photogenerated electron hole rapid recombination limit the application of m-BiVO 4 . In this paper, we successfully constructed a novel copper-sulfur co-doped carbon quantum dots (Cu, S-CQDs)/BiVO 4 nanocomposite through a facile and efficient route, which significantly improved the photocatalytic performance of BiVO 4 . The physicochemical properties of Cu, S-CQDs and Cu, S-CQDs/BiVO 4 samples were studied by various characterization. It was concluded from the degradation experiments that the photocatalytic degradation rate of rhodamine B reaches 99% in 60 min under natural light. The degradation curve compounds the quasi-primary kinetic model, and the kinetic coefficient of degradation is 0.07831 min −1 , which is 5.37 times than that of pure BiVO 4 . Moreover, the free radical scavenging experiments reveal that the hole and superoxide radicals play a major role in the photocatalysis process. After four cycles, the activity of photocatalyst exhibits high stability, which is extremely important for the photocatalytic process. In the summery, the prepared Cu, S-CQDs/BiVO 4 has many advantages, such as environmental-friendly, low cost and a wide range of applications.
研究领域:
材料科学
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环境科学
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产品关联
DOI
高影响因子
Journal of Chemistry
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2020
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IF 1.79
Liping Zhang,Xin Zhang,Jun Xiang,Jingwen Xue,Xuejing Song
Salicylhydroxamic acid is an excellent collector of oxidizing ore, and it has an efficient collection performance for tungsten molybdenum ore. However, the utilization ratio of salicylhydroxamic acid is relatively low in the flotation process, and a large amount of flotation wastewater discharged might cause damage to the water environment. This study mainly compared the effects of natural sunlight degradation, ozonation, and Fenton oxidation processes on the treatment of salicylchydroxamic acid wastewater from W–Mo mineral processing. The results showed after 30 hours degradation by natural sunlight, the CODcr removal rate of wastewater was only 25.99%. When the initial pH was 8, the dosage of O3 was 1.3 mg/L and the reaction time was 60 minutes; O3 oxidation could remove 40.37% CODcr from wastewater, and the BOD5/CODcr value increased to higher than 0.3 after 15 min reaction. Under the Fenton oxidation conditions such as initial pH 3, H2O2 dosage 0.96 g/L, and the molar ratio of H2O2 to Fe2+ 2 : 1, 90.43% CODcr could be removed from flotation wastewater after 90 min reaction, and the BOD5/CODcr value was obviously improved. Fenton oxidation was a high efficient processing technology for salicylhydroxamic acid wastewater, and the effluent could meet the discharge and reuse emission standard requirements in China.
研究领域:
环境工程
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化学工程
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矿物加工
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水处理
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产品关联
DOI
高影响因子
Chemical Engineering and Processing-Process Intensification
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2018
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IF 2.826
Ding Chen,Peng-fei Feng,Fu-hua Wei
Fe-based metal-organic frameworks(Fe(III)-MOFs)were synthesized by Fe 2 (SO 4 ) 3 and trimesic acid using microwave-assisted ball milling method. The structure of the Fe(III)-MOFs was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and Fourier transform infrared spectrometry (FTIR). The thermostability of the MOFs was analyzed by thermogravimetric analysis (TGA). Fe(III)-MOFs were added in aqueous solutions to remove organic dyes. The removal efficiencies of Orange II, CR and MB reached 95.9%, 98.7%, 95.7% respectively at 10℃ and reached 97.7%, 99.7%, 97.5% respectively at 35℃ in 300 min.
研究领域:
材料科学
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环境科学
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化学
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产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）