Constructing Micro-/Nano-Aramid Pulp (MAP)–Epoxy Coatings on Laser-Engraved Titanium Alloy Surfaces for Stronger Adhesive Bonding with Carbon Fiber-Reinforced Polymer Panel
A shape-controllable laser-engraving treatment (LET) and aramid pulp (AP)-reinforced resin pre-coating (RPC) were used on a titanium (Ti) alloy surface to construct micro-/nano-aramid pulp and epoxy (MAPE) coatings for greater bonding strength with carbon fiber-reinforced polymers (CFRPs). The array pits of regular hexagon on the Ti alloy surface were engraved and vertical spaces between the array pits were created to place the AP-reinforced epoxy for stronger mechanical interlocking. The specimen treated with laser engraving (side length of 0.3 mm) and AP-reinforced RPC yielded the greatest bonding strength of 27.1 MPa, 67.4% higher than the base strength. The failure modes of the Ti-CFRPs composites changed from debonding failure at the Ti/epoxy surface to fiber-damaged failure of the laminated CFRPs panels. The shape-controllable LET and simple AP-reinforced RPC were confirmed as the most feasible and effective combined methods for use on titanium alloy surfaces for manufacturing stronger Ti-CFRPs composites, which exhibited the potential for application in other metal–matrix-bonding composite systems.
危险品化学品经营许可证（带存储）