CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
·
2021
·Vol. 37
·期 3
·623-628
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IF 1.307
Zong Siyu,Wang Bolun,Ma Wenyan,Yan Yan,Li Jiyang
A facile method was developed to prepare carbon dots(CDs) by pyrolysis and etching of coffee residue. The as-prepared CDs show uniform spherical nanoparticles with an average size of 2.3 nm and exhibit excitation-dependent fluorescence emissions. Moreover, CDs also exhibit strong fluorescence quenching to nitro compounds and metal ions in both water and ethanol solutions, which could act as a platform for dual detection of PA(picric acid) and Fe 3+ ions with low detection limits of 0.26 and 0.83 µmol/L, respectively. This work provides a novel method for preparation of environmental-friendly fluorescent CDs and shows their potential applications in photoluminescence sensors.
研究领域:
材料科学
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环境科学
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分析化学
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产品关联
DOI
高影响因子
MICROCHIMICA ACTA
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2018
·Vol. 186
·期 1
·1-7
·
IF 5.705
Qi Wenjing,He Hongkun,Fu Yuling,Zhao Maoyu,Qi Lin,Hu Lianzhe,Liu Chun,Li Rong
Water-dispersed fluorescent silicon nanodots (SiNDs) were synthesized by a one-pot hydrothermal method starting from tetraethyl orthosilicate (TEOS) as silicon source and trisodium citrate as reducing reagent. The method is simple and convenient. The SiNDs, with excitation/emission peaks at 347/440 nm and with fluorescence quantum yield of 18% are shown to be viable fluorescent probes for picric acid (PA). The SiNDs strongly bind PA, and their blue fluorescence is quenched. The distance between the donor and acceptor (R 0 value) is calculated from fluorescence data to be 2.1 nm. A fluorometric method was worked out that has a linear response in the 8 nM to 50 μM PA concentration range and a 0.92 nM limit of detection. The method has a fast response (2 min) and is well selective over other nitroaromatic compounds and metal ions. The average recoveries from spiked lake water samples ranged between 98.4 and 100.8%.
Water-dispersed fluorescent silicon nanodots (SiNDs) are synthesized using tetraethyl orthosilicate (TEOS) and trisodium citrate. Based on spectral overlap of fluorescent spectrum of SiNDs and absorption spectrum of picric acid (PA), fluorometric determination of PA at concentrations as low as 0.92 nM is achieved.
研究领域:
分析化学
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纳米材料科学
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环境科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
Analytical Methods
·
2018
·Vol. 10
·期 35
·4251-4256
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IF 2.073
Wen Jie Zhang,Shi Gang Liu,Lei Han,Yu Ling,Liu Li Liao,Shi Mo,Hong Qun Luo,Nian Bing Li
A facile, low-cost, and effective sensing strategy for detection of picric acid (PA) was developed based on copper nanoclusters (CuNCs). In this strategy, highly fluorescent CuNCs were prepared by using copper nitrate and ascorbic acid through an environmentally friendly process. Also, the PA-induced fluorescence quenching mechanism was investigated through ultraviolet-visible absorption spectra, fluorescence spectra, and fluorescence lifetimes, and might be ascribed to the molecular interactions and the strong inner filter effect between the CuNCs and PA. Under the optimal conditions, the fluorescence quenching degree of as-synthesized CuNCs was linearly dependent on the concentration of PA within a wide linear range of 2–40 μM, and the limit of detection was 0.98 μM. Finally, the proposed method was successfully applied to detect the levels of PA in real water samples.
研究领域:
分析化学
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环境科学
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材料科学
✓ 已验证
产品关联
DOI
高影响因子
INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY
·
2023
·
IF 2.6
Yanteng Xiao,Junqiu Zhang,Yaoming Liu,Yingte Wang,Sijie Cheng,Yong Zhang
Here, yellow fluorescent sulphur-doped carbon dots (S-CDs) with high quantum yield (QY) of ~27.9% were synthesised from m-cresol purple by a fast and low-cost one-step hydrothermal method without other reagents. The surface morphology, functional groups and optical properties of S-CDs were characterised by high-resolution transmission electron microscope (HRTEM), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared (FTIR) spectrum and ultraviolet visible (UV-vis) absorption. The fluorescence intensity of S-CDs can be specifically and stably quenched by picric acid (PA) through inner filtration effect (IFE). The linearity between fluorescent intensity and PA concentration was used for developing a fluorescent probe with detecting range of 0–259.0 μM and a detection limit as low as 14.6 nM. We developed the method by applying S-CDs to determine PA in lake water with recoveries in the range of 93.0–103.7%, which verified the feasibility of this probe in practical analysis. In addition, due to the low toxicity and good biocompatibility, S-CDs can be applied to biological imaging.
研究领域:
分析化学
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环境科学
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生物医学
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产品关联
DOI
高影响因子
RSC Advances
·
2015
·Vol. 5
·期 106
·87157-87167
·
IF 3.84
Ma Hengchang,Zhang Zhongwei,Jin Yuanyuan,Zha Lajia,Qi Chunxuan,Cao Haiying,Yang Zengming,Yang Zhiwang,Lei Ziqiang
Triphenylamine-decorated BODIPY derivative TBMA was designed and synthesized. Luminogen aggregation was developed by taking advantage of twisted intramolecular charge transfer (TICT) and aggregation-induced emission (AIE) processes. In non-polar solvents, the locally excited (LE) states of BODIPY luminogens emitted intense yellow light. Increasing solvent polarity brought the luminogens from an LE to a TICT state, causing a large bathochromic shift in the emission color and a dramatic decrease in emission efficiency. The red emission was greatly boosted by aggregate formation or AIE effect. We also discovered that TBMA could be applied as an efficient chemical sensor for picric acid (PA) detection. The detection limit and quenching constant (KSV) were determined as 30 ppb and 2.1 × 10−6 M−1 respectively. 19F NMR and 1H NMR titration analysis verified that F⋯H hydrogen bonding is demonstrated as the mode of interaction, which possibly facilitates effective exciton migration.
研究领域:
分析化学
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材料科学
✓ 已验证
DOI
高影响因子
Journal of Materials Chemistry A
·
2015
·Vol. 3
·期 8
·4604-4611
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IF 7.443
Wei Wei,Rongjie Lu,Shuyuan Tang,Xiaoya Liu
Highly cross-linked and organic–inorganic hybrid poly(cyclotriphosphazene-co-curcumin) microspheres (PCPC-MS) were facilely prepared by a one-step precipitation copolymerization method, and served as a fluorescent chemical sensor for the detection of picric acid (PA) in solution phase. The photochemically inert cyclotriphosphazene moieties intentionally introduced into the structure of the sensor could play a role not only in connecting curcumin fluorophores to construct a highly cross-linked fluorescent architecture with excellent thermal stability and photobleaching stability, but also in effectively enriching PA from bulk solution to the surface of the sensor by the acid–base interaction between the acidic phenolic hydroxyl groups of PA molecules and the electron-rich nitrogen atoms of the cyclotriphosphazene units, which might facilitate the formation of a ground-state non-fluorescent complex of the microspheres and PA as well as the excited-state energy transfer from the microspheres to PA. Therefore, PCPC-MS exhibited a fluorescence quenching response towards PA with high sensitivity, efficiency, and selectivity over a number of other analytes such as 2,4,6-trinitrotoluene, 2,4-dinitrotoluene, 1,3-dinitrobenzene, 4-nitrotoluene, nitrobenzene, 4-benzoquinone, chlorobenzene, and nitromethane in methanol. In addition, PCPC-MS could also effectively detect PA in the presence of the other analytes, indicating their remarkable ability for resisting interferences and specific recognition of PA. This study provides new insights into the design and preparation of a polymer-based fluorescence chemical sensor for PA with low toxicity, a simple preparation process, and high selectivity.
研究领域:
材料科学
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分析化学
✓ 已验证
产品关联
DOI
高影响因子
PROPELLANTS EXPLOSIVES PYROTECHNICS
·
2017
·Vol. 43
·期 3
·286-293
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IF 1.908
Shuangfei Zhao,Fanyuhui Yan,Peng Zhu,Yong Yang,Huanming Xia,Ruiqi Shen,Yinghua Ye
In this study, the technology of micro-segmented flow was applied for continuous synthesis safely and shape control accurately to lead trinitroresorcinate (LTNR) particles. Besides, a micro chemical reaction and crystallization system were built. Crystal shape control technology of LTNR and micro-segmented flow technology were first combined using the system. Additionally, the effects of the flowing rate and chemical additives on LTNR micro-particles preparation were researched for shape control. The LTNR micro-particles were analyzed by XRD, DSC, laser scanning confocal microscope and laser particle size analyzer. The results shows that the LTNR particles size can be controlled from 20 to 400 μm by the flow rate and the concentration of hexadecyl trimethyl ammonium bromide (CTAB), while the shape of LTNR can be controlled by the concentration of glycerol and CTAB. Besides, there is a good linear relationship between the size and the activation energy. This illustrates that the LTNR particles with smaller size are more stable and have higher heat release. This study demonstrated the power of micro-segmented flow for generation of LTNR micro-particles with high quality and for tuning of particle properties.
研究领域:
化学工程
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材料科学
✓ 已验证
产品关联
DOI
高影响因子
SENSORS AND ACTUATORS B-CHEMICAL
·
2018
·
IF 5.667
Kai Li,Run-Hui Yu,Cheng-Mei Shi,Fu-Rong Tao,Tian-Duo Li,Yue-Zhi Cui
An electrospun membrane (CB-PS) was prepared by electrospinning technique from a solution of aggregation induced emission (AIE) active compound 5-( N -carbazole styryl)-1,3-dimethyl-barbituric acid (CB) and polystyrene (PS) in DMF/THF. The membrane was electrospun upon amino-functionalized glass [G-NH 2 ], producing a fluorescent sensor [CB-PS]/[G-NH 2 ] for detecting picric acid (PA). The AIE-active compound were highly photostable and the sensor [CB-PS]/[G-NH 2 ] exhibited high selectivity and sensitivity for the detection of PA over nitroaromatics (NACs) in aqueous phase. The quenching constant ( K SV ) to PA was obtained to be 3.29 × 10 4 M −1 in aqueous phase with a limit of detection (LOD) up to 228 ppb. Selectivity study demonstrates that common interferents have an insignificant effect on the emission intensity of the fluorescent nanofibers in aqueous phase, while reusability study indicates that the fluorescent nanofibers can be regenerated. Real water sample was also tested, and negligible matrix effect on explosives detection was observed. The fluorescence quenching by PA can be attributed to the photo-induced electron transfer (PET) in the quenching process. This research provides new insights into the application of AIE-active materials in fluorescent nanofibrous explosive sensor.
研究领域:
材料科学
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环境科学
·
化学
✓ 已验证
产品关联
DOI
高影响因子
ANALYTICAL SCIENCES
·
2018
·Vol. 35
·期 2
·147-152
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IF 1.355
Ju Yan Jun,Li Na,Liu Shi Gang,Fan Yu Zhu,Ling Yu,Xiao Na,Luo Hong Qun,Li Nian Bing
A fluorescence method for the determination of picric acid (PA) using phosphorus-doped carbon dots (P-CDs), synthesized from β-cyclodextrin and sodium pyrophosphate, is described. The P-CDs are very uniform and monodisperse with a diameter of about 2.8 nm. Under an excitation of 350 nm, the P-CDs emit bright blue fluorescence with an emission peak at 440 nm. The as-synthesized P-CDs serve as a sensitive, selective, and label-free fluorescent probe for the detection of PA. Based on an inner filter effect between PA and P-CDs, a linear response is obtained for PA from 0.1 to 10 μM with a detection limit of 82 nM. Finally, this sensing system has been demonstrated to have practicability for PA detection in the environmental water samples.
研究领域:
分析化学
·
环境科学
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材料科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
SENSORS AND ACTUATORS B-CHEMICAL
·
2017
·
IF 5.401
Tingting Luo,Yiqi Li,Yanxue Xu,Shiting Zhang,Yujue Wang,Xingming Kou,Dan Xiao
In this article, a hyperfluorescence 2-pyridone derivative (D-TPCA) has been synthesized within 5 min by the microwave-assistant heat treatment of the aqueous mixture of citric acid and 2-aminoethanethiol hydrochloride. The as-prepared D-TPCA exhibited good aqueous solubility and excellent fluorescent property with a quantum yield of 89.9%. Because the fluorescence of D-TPCA could be effectively quenched by picric acid (PA), D-TPCA could be served as a “turn-off” fluorescence sensor for PA in aqueous solution. The proposed sensing method permitted a selective and sensitive detection of PA in a linear range of 0–45 μM with a detection limit of 56.0 nM. The determination results of PA in real water samples with a recovery range of 95.4–107.3% confirmed a good analytical performance of this sensor. In addition, the possible sensing mechanism has been discussed in detail.
研究领域:
分析化学
·
材料科学
✓ 已验证
DOI
高影响因子
RSC Advances
·
2014
·Vol. 4
·期 74
·39351-39358
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IF 3.708
Li Wenfeng,Ma Hengchang,Lei Ziqiang
Detection of explosives is of utmost importance due to the threat to human security as a result of illegal transport and terrorist activities. Picric acid (PA) is widely used in the industrial and military fields, and is inadvertently able to contaminate the environment and groundwater, posing a threat to human health. Achieving the detection of explosives at the parts per billion (ppb) level using chemosensors is a great challenge. Herein, we demonstrate that triphenylamine based fluorescent chemosensors tris(4′-carbethoxybiphenyl) amine (TCEPA) and tris(4′-carboxybiphenyl) amine (TCPA) exhibit superior detection capability for PA in solution state at the ppb level (40 ppb and 5 ppb respectively) and efficient quenching behaviours in the vapor phase at room temperature. In addition, fluorescent test strips have been prepared by dip-coating Thin Layer Chromatography (TCL) for trace detection of PA at the attogram level.
研究领域:
分析化学
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环境科学
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材料科学
✓ 已验证
DOI
高影响因子
CHEMICAL ENGINEERING JOURNAL
·
2019
·
IF 8.355
Xinfeng Chen,Congming Sun,Yang Liu,Long Yu,Kui Zhang,Abdullah M. Asiri,Hadi M. Marwani,Hua Tan,Yuejie Ai,Xiangke Wang,Suhua Wang
As a new family of fluorescent materials, all inorganic perovskite quantum dots (PQDs) CsPbX 3 (Cl, Br, I) have attracted rising attention due to their intrinsic optical superiorities and potential applications in various fields. This work takes advantage of the bright fluorescence of PQDs and the strong electrophilic properties of picric acid (PA) to construct an analytical method for sensitive and selective discrimination of PA against other nitroaromatic explosives, and the limit of detection is as low as 0.8 nM. The quenching mechanism was elucidated as the formation of electrostatic complex and the electron transfer between PA and PQDs. To facilitate visual and on-site detection, the CsPbBr 3 PQDs were printed onto microfiltration membrane by inkjet printing to fabricate test papers for rapid and on-site detections of explosive and pollutant PA, showing a great research prospect in the detection of ultratrace PA at different sites.
研究领域:
材料科学
·
分析化学
·
环境科学
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）