Benzene-1,2-dithiolato complexes as cathode materials for rechargeable lithium batteries
Organosulfides are a class of promising cathode materials for rechargeable lithium batteries. In order to overcome their disadvantages of solubility and low mass density, we prepare benzene-1,2-dithiolato complexes with metal ions (Sn 4+ and Cu 2+ ) by a facile method, which are designated as Sn-(BDT) 2 and Cu-BDT, respectively. The synthesized compounds are colored solids and insoluble in liquid ether electrolyte. Their mass densities are about 2.0 mg cm −3 , which are much higher than that (1.2 mg cm −3 ) of the starting material 1,2-benzenedithiol. When evaluated in Li half cells, Sn-(BDT) 2 delivers a capacity of 221.2 mAh g −1 rendering a volumetric energy density of 973.2 Wh L −1 . Cu-BDT can deliver a capacity of 234.2 mAh g −1 and its volumetric energy density is 1044.5 Wh L −1 . Both volumetric capacities and energy densities are higher than those of the starting material. In the discharge, the metal ions serve as electron receptors and 1,2-benzenedithiolate holds lithium ions. The separate electron/lithium ion storage process is highly reversible, which is evidenced by the cycling performances of 200 and 500 cycles for the Li/Sn-(BDT) 2 and Li/Cu-BDT cells, respectively. This strategy is promising to overcome the intrinsic disadvantages of organosulfides as cathode materials for lithium batteries.
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