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APPLIED SURFACE SCIENCE · 2020 · IF 6.182

Conductive WS2-NS/CNTs hybrids based 3D ultra-thin mesh electromagnetic wave absorbers with excellent absorption performance

Deqing Zhang,Honghan Wang,Junye Cheng,Changyu Han,Xiuying Yang,Jingyu Xu,Guangcun Shan,Guangping Zheng,Maosheng Cao

Herein, ultra-thin tungsten disulfide nanosheets/carbon nanotubes (WS 2 -NS/CNTs) hybrids were successfully synthesized by using a one-step hydrothermal method. The WS 2 -NS is evenly grown on the surfaces of CNTs , leading to a remarkable three-dimensional (3D) heterostructure. Outstanding electromagnetic wave absorption performance of the WS 2 -NS/CNTs hybrids can be achieved by tuning the amount of CNTs. The minimum reflection loss can reach up to −51.6 dB at 14.8 GHz, and the effective absorption bandwidth is 5.4 GHz for the hybrids with a thickness of 1.95 mm. Comparison of the results with those of simple mixtures of WS 2 -NS and CNTs prepared by using ultrasonic methods indicates that the absorption performance of the optimized WS 2 -NS/CNTs hybrids are closely related to that of the 3D mesh conductive network constructed by the addition of CNTs and the synergistic effect of WS 2 -NS and CNTs in the hybrids. These WS 2 -NS/CNTs hybrids open a new avenue for the development of electromagnetic wave absorbers with extraordinary absorption performance, light weight, small thickness, broad absorption bandwidth, and low cost.

CAS / MDL: 13283-01-7
研究领域: 材料科学 · 电磁学
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CHINESE JOURNAL OF POLYMER SCIENCE · 2024 · IF 4.1

Holographic Polymer Nanocomposites with High Refractive Index Modulation by Doping Liquid Crystal E6M

Wang Meng-Yun,Zhang Yue,Wang Dan,Yao Ming,Wang Yi-Xuan,Zhou Xing-Ping,Peng Hai-Yan,Xie Xiao-Lin

Holographic optical elements (HOEs) based on polymer composites have become a research hot spot in recent years for augmented reality (AR) due to the significant improvement of optical performance, dynamic range, ease of processing and high yield rate. Nevertheless, it remains a formidable challenge to obtain a large field of view (FOV) and brightness due to the limited refractive index modulation. Herein, we report an effective method to tackle the challenge by doping an epoxy liquid crystal termed E6M, which enables a large refractive index modulation of 0.050 @ 633 nm and low haze of 5.0% at a doping concentration of 5 wt%. This achievement may be ascribed to the improved molecular ordering of liquid crystals within the holographic polymer composites. The high refractive index modulation can endow transmission-type holographic polymer composites with a high diffraction efficiency of 96.2% at a small thickness of 5 µm, which would promise the design of thin and lightweight AR devices.

研究领域: 光学 · 材料科学 · 光子学 · 增强现实
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ADVANCED MATERIALS · 2024 · IF 27.4

A Dopamine-Modified Hyaluronic Acid-Based Mucus Carrying Phytoestrogen and Urinary Exosome for Thin Endometrium Repair

Chenchen Li,Xiyang Tan,Dashi Deng,Chenfan Kong,Lida Feng,Weijing Wang,Kaida Lin,Yuqing Li,Qifang Lei,Lisha Liu,Tao Tao,Ruile Pan,Guangzhi Li,Song Wu

Thin endometrium (TE) is closely associated with infertility in reproductive medicine. Estrogen therapy gains unsatisfactory outcomes. In this study, an artificial mucus based on dopamine (L-DOPA)-modified hyaluronic acid combining phytoestrogen cajaninstilbene acid and rat urinary exosomes (CUEHD) is constructed for TE treatment using a rat TE model. In the rat TE model, the dominant elastic behavior and adhesive properties of CUEHD guarantee adequate retention, rendering superior synergistic treatment efficacy and favorable biosafety characteristics. CUEHD treatment significantly increases endometrial thickness and promotes receptivity and fertility. Mechanistically, estrogen homeostasis, inflammation inhibition, and endometrial regeneration are achieved through the crosstalk between ER-NLRP3-IL1β and Wnt-β catenin-TGFβ-smad signaling pathways. Moreover, the therapeutic potential of exosomes from human urine and adipose tissue-derived stem cells (ADSCs) and rat ADSCs are also demonstrated, indicating extensive use of the artificial mucus system. Thus, this study illustrates a platform combining phytoestrogen and exosomes with promising implications for TE treatment.

研究领域: 生殖医学 · 药理学 · 生物医学工程 · 分子生物学
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Stem Cell Research & Therapy · 2022 ·Vol. 13 ·期 1 ·1-19 · IF 8.079

Synergistic regenerative therapy of thin endometrium by human placenta-derived mesenchymal stem cells encapsulated within hyaluronic acid hydrogels

Lin Yifeng,Dong Shunni,Ye Xiaohang,Liu Juan,Li Jiaqun,Zhang Yanye,Tu Mixue,Wang Siwen,Ying Yanyun,Chen Ruixue,Wang Feixia,Ni Feida,Chen Jianpeng,Du Binyang,Zhang Dan

Background Thin endometrium is a primary cause of defective endometrial receptivity, resulting in infertility or recurrent miscarriage. Much effort has been devoted toward regenerating thin endometrium by stem cell-based therapies. The human placenta-derived mesenchymal stem cells (HP-MSCs) are emerging alternative sources of MSCs with various advantages. To maximize their retention inside the uterus, we loaded HP-MSCs with cross-linked hyaluronic acid hydrogel (HA hydrogel) to investigate their therapeutic efficacy and possible underlying mechanisms. Methods Ethanol was injected into the mice uterus to establish the endometrium-injured model. The retention time of HP-MSCs and HA hydrogel was detected by in vivo imaging, while the distribution of HP-MSCs was detected by immunofluorescence staining. Functional restoration of the uterus was assessed by testing embryo implantation rates. The endometrial morphological alteration was observed by H&E staining, Masson staining, and immunohistochemistry. In vitro studies were further conducted using EdU, transwell, tube formation, and western blot assays. Results Instilled HP-MSCs with HA hydrogel (HP-MSCs-HA) exhibited a prolonged retention time in mouse uteri than normal HP-MSCs. In vivo studies showed that the HP-MSCs-HA could significantly increase the gland number and endometrial thickness ( P  < 0.001, P  < 0.05), decrease fibrous area ( P  < 0.0001), and promote the proliferation and angiogenesis of endometrial cells (as indicated by Ki67 and VEGF, P  < 0.05, P  < 0.05, respectively) in mice injured endometrium. HP-MSCs-HA could also significantly improve the embryo implantation rate ( P  < 0.01) compared with the ethanol group. Further mechanistic study showed the paracrine effects of HP-MSCs. They could not only promote the proliferation and migration of human endometrial stromal cells via the JNK/Erk1/2-Stat3-VEGF pathway but also facilitate the proliferation of glandular cells via Jak2-Stat5 and c-Fos-VEGF pathway. In turn, the increased VEGF in the endometrium promoted the angiogenesis of endothelial cells. Conclusion Our study suggested the potential therapeutic effects and the underlying mechanisms of HP-MSCs-HA on treating thin endometrium. HA hydrogel could be a preferable delivery method for HP-MSCs, and the strategy represents a promising therapeutic approach against endometrial injury in clinical settings. Graphical abstract

研究领域: 生殖医学 · 干细胞治疗 · 组织工程 · 再生医学
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ELECTROCHIMICA ACTA · 2022 · IF 7.336

A light-weight, thin-thickness, flexible multifunctional electrochromic device integrated with variable optical, thermal management and energy storage

Junlong Niu,Jiaqiang Zhang,Yi Wang,Lei Hu,Shengwei Tang,Zhongquan Wan,Chunyang Jia,Xiaolong Weng,Longjiang Deng

Multifunctional electrochromic devices with diversified functions are highly desirable for intelligent electronic systems compared to conventional electrochromic devices with sole applicability. Herein, a multifunctional electrochromic device integrated with variable optical, thermal management and energy storage is realized by preparing nanowire‐structured coral-like PANI films on a flexible gold-plated membrane through the combination of galvanostatic and cyclic voltammetric electrodeposition techniques. The multifunctional electrochromic devices achieve reversible color changes between brownish-yellow, green and dark-green. The maximum emissivity changes of the multifunctional electrochromic device in the ranges of 3–5 μm, 8–14 μm and 2.5–15 μm are 0.42, 0.49 and 0.47, respectively. Moreover, a specific capacitance of 355 F g −1 is obtained for the multifunctional electrochromic devices at a current density of 1 A g −1 . The multifunctional electrochromic devices also have such advantages as light-weight, thin-thickness, flexible and can be fabricated in a multipixel and large area. With versatility characteristics, the multifunctional electrochromic devices are highly promising for intelligent electronic systems in electronic clothing, military camouflage and thermal control system of spacesuits.

研究领域: 材料科学 · 电化学 · 纳米技术 · 能量存储 · 热管理 · 智能纺织品 · 军事技术 · 航天技术
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