A study on using a binder-free TiO2 paste with sodium dodecylbenzene sulfonate addition to improve the performance of low-temperature DSSCs
The utilization of binder-free TiO 2 paste allows for the dye-sensitized solar cells (DSSCs) TiO 2 electrode fabrication at low temperatures, thus making it a potential material for flexible solar cell devices. However, the physical robustness of formed electrodes using TiO 2 paste at low temperatures remains challenging, including issues such as cracking due to film stress and challenges in adjusting the viscosity of the TiO 2 paste. In this study, we enhanced the binder-free TiO 2 paste performance by incorporating sodium dodecylbenzene sulfonate (SDBS) as an additive for TiO 2 electrode precursor solution. It demonstrated that SDBS additives help to relieve internal stress and ultimately enhance the physical and structural characteristics of the films by improving the viscosity in the TiO 2 paste and promoting the dispersed pinholes within the TiO 2 films. Furthermore, implementing TiO 2 paste with varying ratios of SDBS has enabled the fabrication of DSSCs with the highest achieved power conversion efficiency (PCE) of 4.53%, representing an enhancement of nearly 15% compared to TiO 2 paste without SDBS. This research presents a practical and effective approach for preparing highly efficient binder-free TiO 2 paste.
危险品化学品经营许可证（带存储）