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INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES · 2016 · IF 1.956

Preparation and characterization of green adhesives using modified tannin and hyperbranched poly (amine-ester)

Abbas Hasan Faris,Mohamad Nasir Mohamad Ibrahim,Afidah Abdul Rahim

Tannin-glyoxalated Kraft lignin (TGKL) resin is a successful substitution for phenol formaldehyde resin in the production of wood adhesives, however it has a poor water resistance. To overcome this obstacle, this research was focused on scalable adhesive through the modified tannin adhesive and oligomeric precursors of a hyperbranched poly (amine-ester) (HBPAE). The prepared glyoxalated Kraft lignin resin (MTGKL), TGKL, HBPAE and commercial phenol formaldehyde (CPF) resin were evaluated by FTIR , 1 H and 13 C NMR spectroscopy . The tensile strengths and thermal stability were determined. The results indicated that the addition of HBPAE to tannin adhesive could improve the water resistance of MTGKL. This was evident when soaking plywood bonded with TGKL in cool water, where delamination occurred, but it was not evident with MTGKL. The tensile results indicated that the adhesive strengths of MTGKL, 39.72   MPa (dry) and 27.62   MPa (wet), were higher compared to TGKL and CPF resins.

研究领域: 高分子材料 · 林产化学加工 · 胶体与界面科学 · 可持续材料 · 生物质转化
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POLYMERS FOR ADVANCED TECHNOLOGIES · 2011 ·Vol. 22 ·期 12 ·2237-2243 · IF 1.776

Enhancement of a hyperbranched charring and foaming agent on flame retardancy of polyamide 6

Chenhao Ke,Juan Li,Keyi Fang,Qiliang Zhu,Jin Zhu,Qing Yan

A hyperbranched polyamine was prepared using an A 2 + B 3 approach. It acted as a hyperbranched charring and foaming agent (HCFA) in combination with ammonium polyphosphate (APP) to form a new intumescent flame retardant (IFR) system for polyamide 6 (PA6). Effect of HCFA on flame retardant and thermal degradation properties of IFR-PA6 was investigated by limiting oxygen index (LOI), UL-94 vertical burning, cone calorimeter, and thermogravimetric analysis (TGA) tests. The IFR system presented the most effective flame retardancy in PA6 when the weight ratio of APP to HCFA was 2:1. The LOI value of IFR-PA6 could reach 36.5 with V-0 rating when the IFR loading was 30 wt%. Even if the loading decreased to 25 wt%, IFR-PA6 could still maintain V-0 rating with an LOI value of 31. TGA curves indicated that APP would interact with both PA6 and HCFA in PA6/APP/HCFA composite under heating. The interaction between APP and HCFA improved the char formation ability of IFR system and then much more char was formed for PA6/APP/HCFA composite than for PA6/APP. Therefore, better flame retardancy was achieved. Moreover, the structure and morphology of char residue were studied by Fourier transform infrared (FTIR), X-ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM). The results indicated that compact and foaming char layer containing P-O-C structure was formed for PA6/APP/HCFA system during combustion. Copyright © 2010 John Wiley & Sons, Ltd.

研究领域: 高分子化学 · 材料科学 · 阻燃材料 · 热稳定性 · 聚合物复合材料
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