Surface Nanopatterning and Structural Coloration of Liquid Metal Gallium Through Hypergravity Nanoimprinting
Nanoscale structuring of gallium-based liquid metals has emerged as a promising approach for generating unique properties and functionalities in advanced materials and devices. However, their exceptionally high surface tension presents significant challenges for achieving surface nanostructuring using conventional fabrication techniques. Here, a hypergravity nanoimprinting method is introduced, which harnesses horizontal centrifugation to generate hypergravity fields that drive liquid gallium into nanoscale cavities on an elastic polymer stamp surface at subzero temperatures, where it solidifies and preserves imprinted features down to 100 nm lateral resolution. This surpasses previous limits of gallium patterning, enabling phenomena such as iridescent structural colors with a wide range of hues and high saturation. Numerical simulations reveal the intricate fluid dynamic behaviors and interfacial interactions during the imprinting process, providing valuable insights for process optimization and control. By synergistically combining advanced soft lithography techniques with the reversible solid-liquid phase transition properties of liquid metals, hypergravity nanoimprinting offers a practical nanofabrication approach, facilitating the development of next-generation nanoscale gallium devices with finely structured nanofeatures across diverse application domains, such as nanoelectronics and photonic metamaterials.
危险品化学品经营许可证（带存储）