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Foods · 2024 ·Vol. 13 ·期 2 ·191 · IF 4.7

Differences in the Chromogenic Effect of Corn Starch and Potato Starch on Paprika Red Pigment and Structural Characterisation

Fan Su,Yongqiang Wu,Yanping Cao,Shaojia Wang

The present study aims to investigate the chromogenic effect and the interaction between starch-pigment complexes of corn starch (CS) and potato starch (PS) complexed with paprika red pigment. Compared to PS, CS showed 12.5 times higher adsorption capacity for paprika red pigment. Additionally, the a* value of CS-P (26.90 ± 0.23) was significantly higher than that of PS-P (22.45 ± 1.84), resulting in a corn starch-paprika red pigment complex (CS-P) with a more intense red colour. The addition of paprika red pigment significantly decreased the particle size and porosity of CS by 48.14 ± 5.29% and 17.01 ± 3.80%, respectively. Conversely, no significant impact on PS was observed. Additionally, the Fourier transform infrared (FT-IR) spectroscopy results revealed that the starch molecules and paprika red pigment were bound to each other through strong hydrogen bonds. X-diffraction (XRD) results indicated that the starch-paprika red pigment complexes have a V-shaped structure. Furthermore, the relative crystallinity of the complexes between starch and red pepper pigment showed an increasing trend, however, the relative crystallinity of CS increased significantly by 11.77 ± 0.99–49.21 ± 3.67%. Consequently, the CS-P colouring was good.Keywords:corn starch;potato starch;paprika red pigment;chromogenic effect;structural characterisation

CAS / MDL: 9037-22-3 7235-40-7
研究领域: 食品科学 · 化学
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CARBOHYDRATE POLYMERS · 2023 · IF 11.2

Stabilization of capsanthin in physically-connected hydrogels: Rheology property, self-recovering performance and syringe/screw-3D printing

Hongxia Wang,Chaoyang Wu,Juncheng Zhu,Yang Cheng,Yuxin Yang,Shihao Qiao,Bo Jiao,Liang Ma,Yu Fu,Hai Chen,Hongjie Dai,Yuhao Zhang

This work presented a facile way of stabilizing capsanthin by physically-connected soft hydrogels via utilizing specially-structured polysaccharides , and investigated rheological properties, self-recovering mechanism and 3D printability. The functionalized hydrogels demonstrated excellent color quality including redness, yellowness index and hue with great storage stability and visual perception. The soft hydrogels fabricated with properly sequenced polyglyceryl fatty acid esters , β-cyclodextrin, chitosan, and low-content capsanthin possessed outstanding extrudability, appropriate yield stress, reasonable mechanical strength, rational elasticity and structure sustainability. Furthermore, the self-recovering properties based on hydrogen bonds , host-guest interactions and electrostatic interactions were revealed and verified by structural, zeta potential , micro-morphological, zeta potential, thixotropic, creep-recovery, and macroscopic/microscopic characterizations. Along with excellent antioxidant performance, the subsequent 3D printing onto bread with complex models elucidated the high geometry accuracy and great sensory characters. The sequenced physically-connected hydrogels incorporated with capsanthin can provide new insights on stabilizing hydrophobic biomaterials and developing the 3D printed exquisite, innovative food .

研究领域: 食品科学 · 材料科学
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DYES AND PIGMENTS · 2024 · IF 4.1

Capsanthin-iodonium salt system for free radical photopolymerization under LED irradiation

Jun Li,Xinyu Wu,Yue Chen,Junqian Deng,Hongping Yuan,Hailan Lian,Changlei Xia

The current photoinitiator (PI) is effective under mercury lamps but exhibits limited selectivity towards different radiation sources, which hinders its compatibility with eco-friendly LED lighting and raises concerns about toxicity and deep coloration. Capsanthin (Cap), with its strong photo-absorption in the 400–500 nm range, utilizes its conjugated structure to align the PI's absorption wavelength with the LED's emission spectrum . This study introduced Cap as a natural photosensitizer (PS) for free radical photopolymerization under LED irradiation. The Cap-based initiation system demonstrated promising photoinitiating capabilities under a 405 nm LED , achieving over 50 % double bond conversion in polymerized monomers . Furthermore, the system's photobleaching properties were exceptional, and its cytotoxicity was significantly lower than that of traditional PIs, such as benzoin methyl ether. The Cap's photochemical behavior under LED irradiation was explored, investigating its photoinitiating capacity and mechanism through fluorescence, photolysis, and electron paramagnetic resonance techniques. This research is vital for developing bio-based photoinitiating systems for photopolymerization in LED light environments.

研究领域: 高分子科学 · 材料科学 · 光化学 · 环境科学 · 生物技术
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