JOURNAL OF LUMINESCENCE
·
2022
·
IF 4.171
Yi Zhang,Cuiping Zhou,Qifeng Zhang,Pengfei Yin,Xiyuan Sun,Kaiming Wang,Jian Wang,Xing Feng
In this paper, a synthesized material change from perovskite-layer-structured La 2 Ti 2 O 7 to perovskite type LaTiO 3 induced by Li 2 CO 3 addition was observed. The [TiO 6 ] octahedral site symmetry and particle uniformity showed an obvious variation with the change from La 2 Ti 2 O 7 to LaTiO 3 . A broadband far-red emission from 670 to 780 nm emerged when Mn 4+ , Li + ions were co-doped. Furthermore, (Mn 4+ , Li + ) co-doped LaTiO 3 phosphor can be effectively excited by near-UV and blue lights, which is suitable for combining with commercial InGaN LED chips. The LaTiO 3 :0.4%Mn 4+ , 150%Li + phosphor exhibited a high quantum efficiency of 71.1% and a good thermal stability with emission intensity retained 65% at 423 K. Finally, a LED device was fabricated with the LaTiO 3 :0.4%Mn 4+ , 150%Li + phosphor, which matches well with the absorption of photochrome of P FR and shows a good potential for use in agricultural cultivation fields.
研究领域:
材料科学
·
农业科学
✓ 已验证
产品关联
DOI
高影响因子
Materials Today Chemistry
·
2024
·
IF 6.7
Weixi Xia,Yulong Ye,Qinan Mao,Yang Ding,Xinyue Li,Meijiao Liu,Jiasong Zhong
The combination of indoor plant growth lamps and soilless cultivation is considered as a promising direction for future agricultural technology. Its environmentally friendly, effective, and energy-saving characteristics make the plant lighting phosphor widely concerned. However, the phosphor with the required emission spectrum for plant growth while simultaneously achieving dual emission of blue and far-red light is still rarely developed. To address this challenge, a series of Sr 2 GdGaO 5 :Bi 3+ , Sr 2 GdGaO 5 :Mn 4+ , and Sr 2 GdGaO 5 :Bi 3+ , Mn 4+ phosphors have been designed and thoroughly characterized in terms of their phases, morphologies, and optical properties . Dual emission of Sr 2 GdGaO 5 : Bi 3+ , Mn 4+ in blue light (475 nm) and far-red light (726 nm) regions is observed under 350 nm ultraviolet light excitation, and the energy transfer mechanism determined to be dipole-dipole interaction. A high coincidence between plant growth absorption spectrum and co-doping induced double emission is realized. Tremendous acceleration of garlic and bean seedling growth can be observed under the illumination of phosphor-encapsulated LED in soil-free conditions. This comprehensive work contributes to the understanding and utilization of phosphors for efficient indoor plant lighting applications and opens new possibilities for energy-saving and effective plant cultivation.
研究领域:
农业技术
·
光学材料
✓ 已验证
产品关联
DOI
高影响因子
ADVANCED POWDER TECHNOLOGY
·
2020
·
IF 4.217
Renping Cao,Yuming Jiao,Xuantian Wang,Xun Ouyang,Huijun Wan,Ting Chen,Guotai Zheng,Shikun Xie
Novel Mg 2 La 3 NbO 9 :Mn 4+ powder phosphors are successfully synthesized by the high-temperature solid-state reaction method under ambient air. The crystal structure, morphology, decay lifetimes, time-resolved emission spectra, and luminescence properties are investigated. The excitation spectrum of Mg 2 La 3 NbO 9 :Mn 4+ phosphor monitored at 708 nm is observed in the region from 210 nm to 600 nm. Mg 2 La 3 NbO 9 :Mn 4+ phosphor with excitation at the ultraviolet (UV) and blue light can emit the far-red emission with the emission band peaking at ~708 nm because of the 2 E → 4 A 2 transition of Mn 4+ and the corresponding chromaticity coordinates (0.7322, 0.2678). The optimal doping concentration of Mn 4+ ion is ~0.6 mol%. The decay lifetime of Mg 2 La 3 NbO 9 :xMn 4+ phosphors decrease from 1.143 ms to 1.099 ms with increasing the Mn 4+ ion concentration from 0.2 mol% to 1.0 mol%. The good thermal stability of Mg 2 La 3 NbO 9 :Mn 4+ phosphor is confirmed by the temperature-dependent emission spectra. The luminous mechanism of Mg 2 La 3 NbO 9 :Mn 4+ phosphor is explained by using the Tanabe Sugano energy level diagram of Mn 4+ ion. All the experimental results imply that Mg 2 La 3 NbO 9 :Mn 4+ phosphor has a potential application in the white light-emitting diodes (LEDs) field.
研究领域:
材料科学
·
光学
✓ 已验证
DOI
高影响因子
JOURNAL OF ALLOYS AND COMPOUNDS
·
2025
·
IF 6.3
Zhenyu Tang,Peichang Ouyang,Yunfang Liu
Plant greenhouse planting has aroused great attention to the development of plant growth light-emitting diode (LED) light source. Far-red emitting phosphors as the main component of plant growth LED lighting have been studied more and more widely. In this study, Li 1.6 Mg 1.6 Sn 2.8 O 8 :Fe 3+ with far-red emission for plant LED lighting is synthesized in air. X-ray diffractometer (XRD) with the energy dispersive spectroscopy (EDS) is used to test XRD patterns, EDS, and the element mapping diagrams, confirming that Li 1.6 Mg 1.6 Sn 2.8 O 8 :Fe 3+ has a hexagonal crystal structure of with pure phase Li 1.6 Mg 1.6 Sn 2.8 O 8 . Photoluminescence excitation (PLE) spectrum, time-resolved PL spectra, decay curves, photoluminescence (PL) spectrum, as well as concentration and temperature dependent PL spectra are investigated in detail. Li 1.6 Mg 1.6 Sn 2.8 O 8 :Fe 3+ under excitation at 305 nm shows far-red emission peaking at ∼702 nm due to the transition 4 T 1 ( 4 G) → 6 A 1 ( 6 S) of Fe 3+ ion in octahedron [FeO 6 ]. PL spectrum of Li 1.6 Mg 1.6 Sn 2.8 O 8 :Fe 3+ matches with the absorption spectra of plants during the process of photosynthesis, indicating a promising application of Li 1.6 Mg 1.6 Sn 2.8 O 8 :Fe 3+ in plant growth LED lighting. Time-resolved PL spectra prove the only luminescence center (Fe 3+ ). Concentration dependent PL spectra confirm the optimal Fe 3+ concentration (0.8 mol%) and the concentration quenching mechanism is analyzed. The temperature dependent PL spectra show good thermal stability of Li 1.6 Mg 1.6 Sn 2.8 O 8 :Fe 3+ and the heat quenching mechanism is explained.
研究领域:
材料科学
·
园艺学
✓ 已验证
产品关联
DOI
高影响因子
INDUSTRIAL CROPS AND PRODUCTS
·
2018
·
IF 3.849
Jun Ni,Lixiang Dong,Zhifang Jiang,Xiuli Yang,Zhehang Sun,Jiaxun Li,Yuhuan Wu,Maojun Xu
Flavonoids play important roles in plant immune responses, but the molecular mechanism and influencing factors on flavonoid accumulation during Ginkgo immune responses are largely unknown. In this research, post-harvest Ginkgo leaves cultured in the dark were treated with salicylic acid (SA). A transcriptome analysis and total flavonoid measurement showed decreased flavonoid biosynthesis and accumulation in leaves. Experiments carried out in seedlings, young and adult trees, showed increased flavonoid content under light conditions but decreased content under dark conditions after treatment with SA. A detailed analysis of individual flavonoids showed similar changes for most of their contents, although some showed different change trends. Single-colored light experiments revealed that red and far-red light, but not blue light, were required in SA-induced flavonoid accumulation. The results clarified the importance of light in SA-induced flavonoid accumulation and provided valuable information to the Ginkgo related pharmaceutical industry.
研究领域:
植物学
·
分子生物学
✓ 已验证
DOI
高影响因子
Journal of Materials Chemistry C
·
2024
·Vol. 12
·期 32
·12451-12457
·
IF 5.7
Chaowei Yang,Xikun Zou,Mengqi Lyu,Mingkai Wei,Ziyi Wang,Xiaoyu Shuang,Xuejie Zhang,Bin Dong,Xinming Li,Yan Cong,Mingtao Zheng,Maxim S. Molokeev,Bingfu Lei
Far-red light plays a crucial role in plant growth, development, and flowering as a light signal. However, efficiently obtaining far-red light that well-matches the plant-photosensitive pigment Pfr remains a significant challenge in indoor agriculture. In this study, a far-red phosphor, BaGd2Al2Ga2GeO12:Cr3+(BGAGG:Cr3+), was successfully synthesized, using a high-temperature solid-phase method. Under 450 nm excitation, its emission maximum is at 712 nm with a full width at half maximum (FWHM) of 92 nm, which well-matches with Pfr. Combined with a blue LED chip, this phosphor was used to create a pc-LED device for bok choy and Micro-Tom cultivation experiments. Under the irradiation of far-red light, the biomass of bok choy increased by 39%, and the flowering and fruiting of Micro-Tom was promoted, demonstrating its potential in plant lighting applications.
研究领域:
植物学
·
材料科学
·
农业科学
✓ 已验证
DOI
高影响因子
Materials Today Chemistry
·
2023
·
IF 7.3
Haonan Yu,Jingming Chan,Balaji Devakumar,Xiaoyong Huang
High-efficiency far-red emitting phosphors with an emission peak of around 730 nm are urgently needed for indoor plant growth light-emitting diode (LED) lighting. In this article, we report on the synthesis, crystal structure, and luminescence properties of a new highly efficient Mn 4+ ion-activated Li 3 La 3 W 2 O 12 (LLWO) far-red emitting phosphor. A group of LLWO:Mn 4+ phosphors doped with different Mn 4+ ion concentrations have been prepared via the conventional high-temperature solid-state reaction route. X-ray diffraction Rietveld refinement reveals that the LLWO:Mn 4+ phosphor has the monoclinic structure with space group P2 1 /n , along with lattice parameters of a = 5.5396 Å, b = 5.6026 Å, c = 7.8802 Å, α = γ = 90°, β = 90.0988°, and V = 244.57 Å 3 . Interestingly, LLWO:Mn 4+ phosphors can generate bright narrowband far-red emission in the 650–800 nm wavelength range peaking at 719 nm due to the spin- and parity-forbidden 2 E g → 4 A 2g transition of Mn 4+ ions, matching well with the absorption spectrum of phytochrome P FR . The excitation spectrum monitored at 719 nm has a broad excitation band with the range from 250 to 550 nm centered at 339 nm and 472 nm, indicating that LLWO:Mn 4+ phosphors could be efficiently pumped by both ultraviolet and blue LED chips. The highest far-red emission is achieved for the sample doped with 1.2 mol% Mn 4+ ion, and this optimal LLWO:1.2%Mn 4+ sample shows a high internal quantum efficiency of 88.4% and a decay lifetime of 2.289 ms. Commission Internationale de l’Eclairage (CIE) color coordinates of LLWO:1.2%Mn 4+ are determined to be (0.7326, 0.2674). Besides, the crystal field analysis and temperature-dependent emission spectra of the as-prepared samples have been investigated in detail. The emission intensity of LLWO:1.2%Mn 4+ sample at 423 K remains about 40% of that at 303 K. Finally, a LED device is fabricated by integrating the LLWO:1.2%Mn 4+ phosphors and a 460 nm blue LED chip, which shows bright blue and far-red dual emission bands under 20–300 mA driving currents. This work demonstrates that these newly developed far-red emitting LLWO:Mn 4+ phosphors have excellent application prospects in plant growth LED lighting.
研究领域:
材料科学
·
园艺学
·
光学工程
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
·
2024
·Vol. 35
·期 27
·1-11
·
IF 2.8
Wu Keyue,Cui Jingbiao
Cr 3+ doped ZnMgTiO 4 phosphors were successfully prepared with a high-temperature solid-state reaction method. The Cr 3+ doped ZnMgTiO 4 phosphor exhibits a near-infrared emission around 620–870 nm with a peak at 720 nm under UV 325 nm excitation. The emission peak at around 720 nm is related to the 2 E → 4 A 2 transition of Cr 3+ , which matches the absorption spectra of phytochrome P FR . The structure and crystal field environment were studied and discussed. The Cr concentration and temperature dependent photoluminescence properties of ZnMgTiO 4 : Cr 3+ were also investigated. This study indicates that ZnMgTiO 4 : Cr 3+ phosphor has a promising potential for plant cultivation.
研究领域:
材料科学
·
植物学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF LUMINESCENCE
·
2021
·
IF 3.599
Xuefei Ren,Yi Zhang,Chang Su,Jingwen Zhan,Linyan Fu,Yunlong Yang,Xiyuan Sun,Jian Wang,Xing Feng
Far-red emitting Sr 3 NaTaO 6 : Mn 4+ and Sr 3 NaTaO 6 : Mn 4+ , Ba 2+ phosphors were successfully synthesized by high-temperature solid-state method for the first time. The crystal structure and luminescence properties of phosphors were studied by X-ray diffraction (XRD), photoluminescence (PL), thermal stability, UV–vis spectroscopy and CIE color coordinate in detail. The Sr 3 NaTaO 6 : Mn 4+ phosphor exhibits an intense emission peak at 692 nm under the excitation of 365 nm, which matches well with the absorption spectra of plant pigments of chlorophyll a and b , phytochrome P R and P FR . Besides, by co-doping of Ba 2+ ions, the emission intensity of Sr 3 NaTaO 6 : Mn 4+ phosphors were enhanced 1.1–1.5 times and an internal quantum efficiency (IQE) of 75.1% was obtained. Finally, a LED device was fabricated with the Sr 3 NaTaO 6 : 0.3%Mn 4+ , 0.45%Ba 2+ phosphor and showed an effective promotion on the average stem length, fresh weight, dry weight and chlorophyll content of wheat. The result shows that Sr 3 NaTaO 6 : 0.3%Mn 4+ , 0.45%Ba 2+ phosphor may have a potential application in the fields of plant growth lighting LEDs.
研究领域:
材料科学
·
植物学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF LUMINESCENCE
·
2023
·
IF 3.6
Chunyan Zhou,Hua Fan,Jinling Huang,Shu Li,Yaoyao Huang,Meiping Huang,Yin Huang,Xinjing Guo,Liya Zhou
Broad red emitting phosphors are essential for the growth of indoor plants. Previous Mn 4+ -activated far-red phosphors typically displayed narrow emission, which could not well overlap with plant pigment absorption. A high temperature solid state technique was used to create the unique double perovskite LaGeSbO 6 :Mn 4+ phosphor with an emission peak centered at 700 nm and an impressive full width at half maximum (FWHM) of 100 nm. The origin of ultra-broadband emission of LGS:Mn 4+ phosphors was confirmed by crystal structure and time-resolved spectra owing to the occupation of the two octahedral [SbO 6 ] and [GeO 6 ] centers by the Mn 4+ ion. The quenching mechanism is brought about by the dipole-dipole interaction. The broadband emission is substantially broader than that of other Mn 4+ -activated red emitting phosphors previously described. Besides, the emission spectrum of LaGeSbO 6 :0.4%Mn 4+ matches well with the phytochrome P FR absorption band for plant development. All of the findings suggested that the novel LaGeSbO 6 :Mn 4+ phosphor could be potentially used in light-emitting diodes for indoor plant culture.
研究领域:
园艺学
·
材料科学
✓ 已验证
产品关联
DOI
高影响因子
Plants-Basel
·
2024
·Vol. 13
·期 24
·3495
·
IF 4
Lishu Yu,Lijun Bu,Dandan Li,Kaili Zhu,Yongxue Zhang,Shaofang Wu,Liying Chang,Xiaotao Ding,Yuping Jiang
To investigate the effects of different light qualities on the growth, photosynthesis, transcriptome, and metabolome of mint, three treatments were designed: (1) 7R3B (70% red light and 30% blue light, CK); (2) 7R3B+ far-red light (FR); (3) 7R3B+ ultraviolet light A (UVA). The results showed that supplemental FR significantly promoted the growth and photosynthesis of mint, as evidenced by the increase in plant height, plant width, biomass, effective quantum yield of PSII photochemistry (Fv’/Fm’), maximal quantum yield of PSII (Fv/Fm), and performance index (PI). UVA and CK exhibited minimal differences. Transcriptomic and metabolomic analysis indicated that a total of 788 differentially expressed genes (DEGs) and 2291 differential accumulated metabolites (DAMs) were identified under FR treatment, mainly related to plant hormone signal transduction, phenylpropanoid biosynthesis, and flavonoid biosynthesis. FR also promoted the accumulation of phenylalanine, sinapyl alcohol, methylchavicol, and anethole in the phenylpropanoid biosynthesis pathway, and increased the levels of luteolin and leucocyanidin in the flavonoid biosynthesis pathway, which may perhaps be applied in practical production to promote the natural antibacterial and antioxidant properties of mint. An appropriate increase in FR radiation might alter transcript reprogramming and redirect metabolic flux in mint, subsequently regulating its growth and secondary metabolism. Our study uncovered the regulation of FR and UVA treatments on mint in terms of growth, physiology, transcriptome, and metabolome, providing reference for the cultivation of mint and other horticultural plants.
研究领域:
植物生理学
·
分子生物学
·
园艺学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
Journal of Materials Chemistry C
·
2024
·Vol. 12
·期 9
·3272-3279
·
IF 5.7
Sha Ouyang,Jiamai Yin,Liujuan Su,Maohai Yao,Guichao Wang,Jiayi Yang,Maxim S. Molokeev,Zhi Zhou,Sijin Zhang,Mao Xia
Phytochrome PFR plays a key role in plant photomorphogenesis, and its perception of far-red light is essential, but how to obtain an efficient far-red phosphor to achieve accurate light filling remains a huge challenge. In this study, Gd1−y−zAl3−x(BO3)4:xCr3+,yLu3+,zSm3+ (GAB:xCr3+,yLu3+,zSm3+) series phosphors were synthesized by a high-temperature solid-state method. By doping Lu3+, the emission intensity of Cr3+ could increase as high as 20%. With the introduction of Sm3+, the emission intensity of Cr3+ was further increased by 29%. Particularly, the emission spectra can be tuned by varying the concentration ratio of Sm3+ and Cr3+, more suitable for the absorption spectrum of PFR. Moreover, the internal quantum yield and external quantum yield of GL0.1AB:0.03Cr3+ and GL0.1AB:0.03Cr3+,0.003Sm3+ were 83.1% and 24.7% and 78.1% and 26.3%, respectively. There were high anti-thermal quenching properties in the prepared phosphors at 423 K, with 107.6% (GAB:0.03Cr3+), 103.1% (GL0.1AB:0.03Cr3+), and 102.7% (GL0.1AB:0.003Sm3+,0.03Cr3+). Finally, the phosphors were made into pc-LED devices, which can realize the adjustable orange-red and far-red luminescence and meet the needs of plant lighting applications. In the light-regulated plant growth experiment, compared with the control group, far-red light promoted root growth in plants, confirming the application potential of the prepared phosphors in indoor plant cultivation.
研究领域:
植物学
·
材料科学
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）