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JOURNAL OF APPLIED POLYMER SCIENCE · 2018 ·Vol. 136 ·期 3 ·46984 · IF 1.901

Synthesis of molecularly imprinted polymer by suspension polymerization for selective extraction of p-hydroxybenzoic acid from water

Xiaojuan Liu,Fengjing Wu,Chaktong Au,Qi Tao,Mingyu Pi,Wenhui Zhang

Molecularly imprinted polymer (MIP) for selective extraction of p -hydroxybenzoic acid ( p -HB) was synthesized by suspension polymerization using p -HB as template, 4-vinyl pyridine as functional monomer and ethylene glycol dimethacrylate as crosslinker. As characterized by scanning electron microscopy, the MIP particles are spherical, with size ranging from 1 to 8 μm. Compared with the non-imprinted polymer (NIP), the MIP shows higher binding capacity toward p -HB: maximum binding capacity for p -HB being 8.07 μmol g −1 over MIP and 3.88 μmol g −1 over NIP. The adsorption of p -HB on MIP follows the Freundlich model and displays pseudo-second-order kinetics. The results of selective and competitive binding experiments confirm that the molecularly imprinted sites have excellent recognition ability toward p -HB. The results reveal that the MIP is a promising adsorbent for selective extraction of p -HB from water samples. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136 , 46984.

研究领域: 环境科学 · 分析化学 · 高分子材料 · 污染物去除 · 分子识别
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JOURNAL OF MOLECULAR LIQUIDS · 2020 · IF 5.065

A novel amidoxime functionalized porous resins for rapidly selective uranium uptake from solution

Jianwei Bai,Xiaofei Ma,Cen Gong,Yiming Chen,Huijun Yan,Kewei Wang,Jun Wang

Traditional adsorption resin prepared by a low efficiency method has a low porosity and surface area , which limits the adsorption performance of the resin. Therefore, a novel porous resin was developed by structural design of the resins through post- modification with HPA and a post-crosslinked method. The novel porous post-modification resin was successfully prepared by the multistep method. Meanwhile, the high surface area and abundant micropores in HCR-AO can improve the adsorption rate by accelerating the diffusion of uranium in the external diffusion stage. The removal capacity of HCR-AO increased 366% for HCR and 120% for PSD-AO at the same initial concentration. HCR-AO takes less time to reach equilibrium than PSD-AO and HCR. Excitingly, the adsorption amount of the material dropped only slightly even after 8 cycles. The short equilibrium time and outstanding removal efficiency makes it a novel candidate for further extraction of U (VI) from seawater .

研究领域: 环境化学 · 核化学 · 材料科学 · 吸附分离 · 海洋资源提取
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