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SENSORS AND ACTUATORS B-CHEMICAL · 2021 · IF 7.46

Fabrication and electrochemical property of La0.8Sr0.2MnO3 and (ZrO2)0.92(Y2O3)0.08 interface for trace alcohols sensor

Chu Cheng,Jie Zou,Yucun Zhou,Zi Wang,Han Jin,Guangzhong Xie,Jiawen Jian

A mixed potential type alcohols gas sensor based on an yttrium stabilized zirconia (YSZ) electrolyte and an La 0.8 Sr 0.2 MnO 3 (LSM) sensing electrode was fabricated. The influences of YSZ-LSM interface on sensing performance were studied by multiple methods including X-ray diffraction (XRD), scanning electron microscope (SEM), energy dispersive spectroscopy (EDS), thermogravimetric analysis and differential scanning calorimetry (TG-DSC) and electrochemical impendence spectroscopy (EIS). The sensor with 1150 °C-sintered interface showed an ultralow detection limit of 50 ppb alcohols (methanol and ethanol) at 500 °C in air. The response voltage was independent of water, CO, CO 2 and NO x . The sensor exhibited a reasonable selectivity towards alcohols under the existence of several kinds of volatile organic compounds. Meanwhile, the sensor showed a good repeatability and a suitable long-term stability. Based on the polarization curves and EIS results, a mixed potential mechanism was proposed. These results demonstrate the promising potential of using the LSM-based sensor for human exhale test.

研究领域: 材料科学 · 电化学
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APPLIED SURFACE SCIENCE · 2018 · IF 4.439

P-type sub-tungsten-oxide based urchin-like nanostructure for superior room temperature alcohol sensor

Yao Yao,Mingli Yin,Junqing Yan,Shengzhong (Frank) Liu

Nanowires assembled sub-WO 3 urchin-like nanostructures have been fabricated via a solvothermal method. The detailed structure and morphology features were characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM). The results reveal that the individual nanowires are grown along the [0   0   1] direction, and assembled together to form an urchin-like nanostructure. Sensing performance of the sub-WO 3 was investigated toward alcohol vapor. At room temperature, the sensor devices based on the WO 3−x exhibit significantly higher sensitivity comparing to that of the stoichiometric WO 3 . The superior sensing performance of this WO 3−x sensor is ascribed to the large specific surface area and abundant oxygen vacancies. The obvious enhancement of the gas sensing property can be very useful for the future design and development of room temperature gas sensors for other volatile organic compounds.

CAS / MDL: 13283-01-7
研究领域: 材料科学 · 传感器技术
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DYES AND PIGMENTS · 2022 · IF 5.122

Controllable in situ generated carbon black hollow silica (C@h-SiO2) photonic crystal inks with highly saturated structural colors

Bing Liu,Jin Fan,Wenzhao Liu,Guannan Zhang,Zhaoyang Wu

The structural color of photonic crystals is usually whitish and has low saturation due to multiple incoherent scattering effects, limiting its application in practical visual observation. Herein, by controlling the calcination time of [email protected] 2 nanoparticles , we obtain hollow SiO 2 with different in situ generated carbon black contents and assemble them into photonic crystal inks (PCIs). PCIs have excellent saturation and high crystallinity due to the in-situ generated carbon black capable of absorbing incoherently scattered light without affecting particle assembly. PCIs are further converted into non-close-packed photonic crystal films with highly saturated structural colors by photopolymerization of resins. This photonic crystal film can be swollen by an ethanol-water mixture, resulting in structural color changes and shifts in reflection peaks. Moreover, the photonic crystal film can dynamically change from a dry opaque state to an ethanol-wetted translucent state. Such solvent-responsive photonic crystal films with highly saturated structural colors are expected to be used in alcohol sensors and color anti-counterfeiting labels.

研究领域: 材料科学 · 纳米技术 · 光学 · 化学
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BIOSENSORS & BIOELECTRONICS · 2024 · IF 10.7

Flexible AIE/PCM composite fiber with biosensing of alcohol, fluorescent anti-counterfeiting and body thermal management functions

Jiahui Lin,Xing Feng,Jintao Huang,Yiwei Liu,Yongshuang Xiao,Yanfeng Li,Yonggang Min,Ben Zhong Tang

Alcohol sensing plays a critical role in medical detection and personal health management. AIE materials with high sensitivity, selectivity and fast response have been widely used in biosensing, but their application in the field of alcohol sensing still needs further research and development. Furthermore, developing flexible phase change materials (PCMs) is significant for the research of human-body thermal management. In this study, a kind of flexible polyacrylonitrile (PAN)/polyvinylpyrrolidone (PVP)/polyethylene glycol (PEG)/Py-CH (pyrene-based AIE molecule)/SiO 2 @h-BN composite fiber textile (PAB) with alcohol sensing performance, writable fluorescence property, and human body thermal management function has been prepared via electrospinning technique. The PAN/PVP fiber matrix successfully integrated AIE fluorescent sensing material and PCM into a multi-functional composite with great shape stability. Owing to the introduction of novel pyrene-based Py-CH with AIE characteristic, this innovative textile exhibited wonderful fluorescent properties, including sensitive alcohol fluorescence sensing, writable fluorescence performance and variable temperature fluorescence. Furthermore, proposed PAB textile delivered a high energy storage density of 87∼90 J/g, excellent thermal reliability, great comprehensive mechanical flexibility and enhanced thermal conductivity for flexible human body thermal management. Hence, this flexible multifunctional AIE/PCM composite sensing textiles can be widely used in alcohol sensing, fluorescence anti-counterfeiting and flexible body thermal management.

CAS / MDL: 1336-21-6
研究领域: 材料科学 · 生物传感 · 热管理 · 纺织工程
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