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APPLIED ENERGY · 2014 · IF 5.261

Photovoltaic and photocatalytic performance study of SOLWAT system for the degradation of Methylene Blue, Acid Red 26 and 4-Chlorophenol

Zhen Wang,Yiping Wang,Marta Vivar,Manuel Fuentes,Li Zhu,Lianwei Qin

The SOLWAT system is a combined system for solar water purification and renewable electricity generation. Its photovoltaic and photocatalytic performance, along with the photovoltaic (PV) electricity production was studied under the degradation of three different pollutants: Methylene Blue, Acid Red 26 and 4-Chlorophenol in present paper. The spectrum loss of the system was analyzed theoretically. Spectral transmittance experiments with different medium were conducted and compared with the results of outdoor experiments. The photovoltaic performance of the SOLWAT system was studied comparatively by measuring the P m and I sc under actual climatic conditions with a reference PV system. To investigate the photocatalytic performance of the SOLWAT system, the degradation of sample pollutants were detected by analyzing the UV absorption and the TOC. In the presence of the additional wastewater layer, PV cells in the SOLWAT system could work under lower temperature. Depending on the spectral absorption of pollutants, if it is within the spectral response of the PV cell, the electricity output is affected by the pollutant degradation (Methylene Blue, Acid Red 26). When the spectral absorption of pollutant is out of the spectral response of the cell, the PV output is not affected by the contaminant degradation (4-Chlorophenol). The output power of SOLWAT system, though decreased due to the light absorption, was sufficient to drive the whole system. The degradation of sample pollutants was detected by analyzing the UV absorption and the TOC to investigate the photocatalytic performance of the SOLWAT system. For the wastewater with different initial concentrations, the decolorization rate ran up above 99% and the mineralization rate was above 80%.

研究领域: 环境科学 · 可再生能源
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JOURNAL OF APPLIED TOXICOLOGY · 2015 ·Vol. 35 ·期 12 ·1473-1480 · IF 2.982

Toxicity induced by Basic Violet 14, Direct Red 28 and Acid Red 26 in zebrafish larvae

Bing Shen,Hong-Cui Liu,Wen-Bin Ou,Grant Eilers,Sheng-Mei Zhou,Fan-Guo Meng,Chun-Qi Li,Yong-Quan Li

Basic Violet 14, Direct Red 28 and Acid Red 26 are classified as carcinogenic dyes in the European textile ecology standard, despite insufficient toxicity data. In this study, the toxicity of these dyes was assessed in a zebrafish model, and the underlying toxic mechanisms were investigated. Basic Violet 14 and Direct Red 28 showed acute toxicity with a LC 50 value at 60.63 and 476.84 µg ml –1 , respectively, whereas the LC 50 of Acid Red 26 was between 2500 and 2800 µg ml –1 . Treatment with Basic Violet 14, Direct Red 28 and Acid Red 26 resulted in common developmental abnormalities including delayed yolk sac absorption and swimming bladder deflation. Hepatotoxicity was observed in zebrafish treated with Basic Violet 14, and cardiovascular toxicity was found in zebrafish treated with Acid Red 26 at concentrations higher than 2500 µg ml –1 . Basic Violet 14 also caused significant up-regulation of GCLC gene expression in a dose-dependent manner whereas Acid Red 26 induced significant up-regulation of NKX2.5 and down-regulation of GATA4 at a high concentration in a dose-dependent manner. These results suggest that Basic Violet 14, Direct Red 28 and Acid Red 26 induce developmental and organ-specific toxicity, and oxidative stress may play a role in the hepatotoxicity of Basic Violet 14, the suppressed GATA4 expression may have a relation to the cardiovascular toxicity of Acid Red 26. Copyright © 2015 John Wiley & Sons, Ltd.

CAS / MDL: 95-76-1
研究领域: 毒理学 · 分子生物学 · 发育生物学 · 环境科学
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