Zheng Wang,Yong Fan,Yimin Zhang,Hong Liu,Peng Liu,Qian Wan
In the context of the accelerated development of all-vanadium liquid flow batteries and vanadium-based alloys, there is a growing requirement for high-purity V 2 O 5 . In this study, vanadium shale leachate was used as raw material and V 2 O 5 products with purity >99.9 % were prepared greenly and efficiently through vanadium precipitation by melamine adsorption, and the adsorption conditions and mechanisms were investigated. XPS, FTIR, DFT, and MD results show that the –NH 2 and N atoms on the melamine bind to VO 2 + through coordination, resulting in high adsorption performance. The Langmuir isothermal adsorption model predicted the maximum adsorption capacity of melamine for vanadium to be 892.86 mg/g. Furthermore, the adsorption thermodynamics indicated that the adsorption reaction was heat-absorbing and spontaneous. The pseudo-second-order kinetic model provided a superior description of the adsorption kinetic data at 363 K, and the adsorption process was found to be mainly controlled by the chemical reaction control kinetic model. The reaction conditions were optimized by response surface methodology, and under the optimized conditions, the vanadium precipitation rate was >99 %, the purity of the prepared V 2 O 5 was >99.9 %, and the vanadium precipitation process did not produce ammonia–nitrogen wastewater. The method provides an efficient, economical, and environmentally friendly way for the preparation of high-purity V 2 O 5 .
危险品化学品经营许可证（带存储）