High mass loading CaV4O9 microflowers with amorphous phase transformation as cathode for aqueous zinc-ion battery
Rechargeable zinc-ion batteries (ZIBs) have shown significant promise as alternative battery technology due to their environmental benignity and cost-effectiveness. However, the current development of ZIB cathode is still hindered by various challenges such as less-than-ideal capacity, poor cyclic performance, and the typical use of low mass loading during battery evaluation. Here we prepared a nanosheet-assembled compact CaV 4 O 9 microflowers/carbon nanotubes (CaVO/CNTs) composite film via a facile spray printing technique. The resultant CaVO/CNTs composite film possessed extremely short ion diffusion pathways, excellent electrical conductivity, and superior structural stability. At a high mass loading of 50 mg cm −2 , the as-fabricated electrode could attain an areal capacity of 10.5 mAh cm −2 . Furthermore, CaVO/CNTs underwent phase transformation during the initial charging process to form amorphous V 2 O 5 ·nH 2 O, which could provide more active sites for Zn 2+ storage. As a result, CaVO/CNTs electrode was able to deliver 410 mAh g −1 at 0.1 A g −1 , high-rate performance (270 mAh g −1 at 10 A g −1 ), and ultra-long cyclic life of 91% retention after 3000 cycles. Since CaVO/CNTs film possessed good flexibility and excellent electrical conductivity, a flexible soft-packaged ZIB was assembled based on this film, and it was able to exhibit consistent electrochemical properties under various bending states.
危险品化学品经营许可证（带存储）