JOURNAL OF APPLIED POLYMER SCIENCE
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2017
·Vol. 134
·期 35
·45235
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IF 1.86
Wei Yuan,Gaoyi Han,Yaoming Xiao,Yunzhen Chang,Ying Zhang,Hua Song
Polypyrrole deposited on titanium mesh (PPy–TiM) was fabricated via a galvanostatic method with titanium mesh as the substrate to electrochemically deposit polypyrrole (PPy) doped with p -toluene sulfonate anions. The influence of the deposition time on the characteristics of the PPy–TiM samples was investigated. Then, semitransparent flexible electrochemical capacitors were assembled with the optimal samples of PPy–TiM as electrodes and H 3 PO 4 –poly(vinyl alcohol) as the gel electrolyte. The testing results show that PPy in the optimal PPy–TiM electrode had a specific capacitance of about 326 F/g, and the capacitance of the assembled cells still remained unchanged or up even after 20,000 cycles. Just as expected, the cells possessed semitransparent and good flexibility, and three cells connected in series could drive an LED device. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2017
研究领域:
材料科学
·
电化学
✓ 已验证
产品关联
DOI
高影响因子
MATERIALS RESEARCH BULLETIN
·
2024
·
IF 5.3
Yuanmei Xu,Wenbing Chen,Xueshi Li
Much attention has been focused on the fabrication of TiO 2 microspheres due to their excellent properties and attractive potential in many fields. Here, undoped 3D hierarchical TiO 2 microspheres (TMS) were synthesized in situ on Ti mesh using a hydrothermal method by varying NaOH concentration, reaction time and temperature. The 3D TMS grown along the surface of the woven wires of the Ti meshes, using the metal Ti meshes as a substrate, which resulted in improved conductivity. Meanwhile, the original Ti mesh with the macroporosity (due to the 15 % open area of the mesh) can act as fast proton mass diffusion. As a result, the flexible TMS-Ti photoelectrodes exhibit an excellent current density of 1.63 mA/cm 2 at a potential of 1.23 V (vs Ag/AgCl). Therefore, the in situ synthesis of TiO 2 microspheres on Ti mesh is highly desirable for flexible devices.
研究领域:
材料科学
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能源科学
✓ 已验证
DOI
高影响因子
CHINESE JOURNAL OF CHEMICAL PHYSICS
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2017
·Vol. 30
·期 1
·112-116
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IF 0.498
Chen Jun-hao,Feng Xia-yu,Chen Wu-feng,Song Yu-qing,Yan Li-feng
Films of polypyrrole/graphene on titanium mesh were prepared by electrochemical reduction of the fresh dried foam films of graphene oxide followed by an electrochemical polymerization of pyrrole. The as-obtained composite had highly surface area, conductivity, and could be used as the electrode for supercapacitors, especially directly used as the active materials in free of binders while the Ti mesh worked as the collector. Plenty of polypyrrole nanoparticles formed on the surface of reduced graphene film, and some fiber-like aggregates could be formed during the polymerization, which worked as the material for pseudo-capacitance. The specific capacitance of the supercapacitor reached 400 F/g and showed high stability with retaining capacitance of 82% after 5000 cycles, indicating that the nanocomposite is a suitable active material for supercapacitors.
研究领域:
材料科学
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电化学
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能源存储
✓ 已验证
DOI
高影响因子
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
·
2017
·
IF 3.582
Kai Li,Min Ma,Lisi Xie,Yadong Yao,Rongmei Kong,Gu Du,Abdullah M. Asiri,Xuping Sun
In this work, we demonstrate the first use of NiCoP nanosheet array on Ti mesh (NiCoP NA/Ti) as an efficient catalyst for hydrolysis of NaBH 4 in alkaline media . This catalyst shows a low activation energy of 52.68 kJ/mol for NaBH 4 hydrolysis meanwhile the hydrogen generation rate can achieve 3016.79 mL/min/g (NiCoP) at 303 K, outperforming most reported Co-based noble-metal-free catalysts and some noble-metal catalysts. Remarkably, the catalyst exhibits high recyclability , durability and controllability for on-demand hydrogen generation in alkaline NaBH 4.
研究领域:
材料科学
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催化化学
✓ 已验证
产品关联
DOI
高影响因子
APPLIED SURFACE SCIENCE
·
2019
·
IF 5.155
Tianlong Yu,Shixiang Lu,Wenguo Xu,Rabah Boukherroub
The development of advanced materials with superwettability has captured much research interest, because of the increasing environmental concerns and technological requirements. In this work, a titanium mesh coated with copper micro/nanostructures was fabricated via chemical immersion and annealing treatment. The resulting mesh surface consists of titanium and copper oxides with special dendritic and island-like micro-nano binary structures and exhibited remarkable superhydrophobic/superoleophilic property. The superhydrophobic/superoleophilic Ti mesh (SSTM) proved to be efficient for the separation of various water-oil mixtures and exhibited an excellent reusability in repeating separation cycles of water-carbon tetrachloride. Moreover, the SSTM sample displayed great icephobic property including ice-over delay and low ice adhesion. The self-cleaning properties of the SSTM sample were demonstrated using simulated chalk powder that can be easily washed off by injecting water droplets. It also exhibited superior stability in air atmosphere or water over months and great durability under a continuous tap-water flow impacting or abrasion test.
研究领域:
材料科学
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环境科学
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表面工程
✓ 已验证
产品关联
DOI
高影响因子
Nano Research
·
2016
·Vol. 10
·期 2
·595-604
·
IF 8.893
Cui Liang,Xu Yuanhong,Niu Li,Yang Wenrong,Liu Jingquan
The issues of hydrogen generation and storage have hindered the widespread use and commercialization of hydrogen fuel cell vehicles. It is thus highly attractive, but the design and development of highly active non-noble-metal catalysts for on-demand hydrogen release from alkaline NaBH 4 solution under mild conditions remains a key challenge. Herein, we describe the use of CoP nanowire array integrated on a Ti mesh (CoP NA/Ti) as a three-dimensional (3D) monolithic catalyst for efficient hydrolytic dehydrogenation of NaBH 4 in basic solutions. The CoP NA/Ti works as an on/off switch for on-demand hydrogen generation at a rate of 6,500 mL/(min·g) and a low activation energy of 41 kJ/mol. It is highly robust for repeated usage after recycling, without sacrificing catalytic performance. Remarkably, this catalyst also performs efficiently for the hydrolysis of NH 3 BH 3 .
研究领域:
材料科学
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催化
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能源存储
·
氢燃料电池
✓ 已验证
产品关联
DOI
高影响因子
Micro & Nano Letters
·
2018
·Vol. 13
·期 10
·1373-1377
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IF 0.841
Hui Zhao,Yuqing Miao
The Ni–W–S nanoparticles (NPs) were synthesised on Ti mesh through the typical hydrothermal method. The obtained Ti/Ni–W–S was characterised on morphology, composition and electrocatalytic property. It showed good electrocatalytic performance towards glucose oxidation in strong alkali electrolyte, exhibiting the potential application in the field of fuel cell. The excellent electrocatalytic activity of Ni–W–S NPs, the favourable electron transfer between electrode and catalysts, as well as the high conductivity of Ti contributed to its final catalytic performance of Ti/Ni–W–S.
研究领域:
材料科学
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电化学
✓ 已验证
产品关联
DOI
高影响因子
Journal of Energy Storage
·
2022
·
IF 8.907
Xiaolin Sun,Kai Zhao,Zhiqiang Liu,Zhonghan Feng,Zihao Wang,Liang Cui,Jingquan Liu
The construction of cost-effective, efficient, and sustainable energy storage systems is extremely important for future fuels globally. Nickel borates display important characteristics in electrochemical catalytic applications, whereas few reports have focused on their energy storage properties in supercapacitors . Herein, Ni 3 (BO 3 ) 2 nanospheres (NSs) are fabricated on titanium (Ti) mesh to afford Ni 3 (BO 3 ) 2 NSs@Ti using a simple and scalable electrodeposition technique, whose electrochemical performance is carefully studied. The Ni 3 (BO 3 ) 2 NSs@Ti obtained at 1.2 V (Ni 3 (BO 3 ) 2 NSs-1.2V) exhibits a higher specific capacitance of 663 F g −1 with a current density of 0.5 A g −1 . Furthermore, by directly employing Ni 3 (BO 3 ) 2 NSs-1.2V as the positive electrode and activated carbon as the negative electrode , an asymmetric supercapacitor (ASC) device can be fabricated and displays the energy density up to 30.6 Wh kg −1 at the power density of 400 W kg −1 . Hence, the facile electrodeposited Ni 3 (BO 3 ) 2 NSs can be a potential platform for energy storage applications .
研究领域:
材料科学
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能源存储
✓ 已验证
产品关联
DOI
高影响因子
APPLIED SURFACE SCIENCE
·
2023
·
IF 6.7
Yanlei Liu,Mengbo Shan,Lange Du,Weihao Sun,Dapeng Wu,Qing Bi,Hongju Wang,Yufang Liu
A scalable strategy with commercial feasibility was developed to in situ generate TiO 2 nanowires/amorphous CuS@TiO 2 nanolayer (TiO 2 /CuS@TiO 2 ) composites on the surface of titanium mesh through a sequent hydrothermal method, successive ionic layer adsorption and reaction (SILAR), and atomic layer deposition (ALD) techniques. The TiO 2 /CuS@TiO 2 composites could respectively harness the incident light with different spectra at the photothermal center (CuS, visible and near-infrared light) and photocatalytic center (TiO 2 , UV and visible light), which leads to the effective utilization of the solar energy. Benefiting from the CuS photothermal-induced local heating effect of CuS, the adjacent micro-zone temperature could be elevated and the activation energy barrier could be reduced by 10.5 kJ mol −1 , which promotes the activation of surface lattice oxygen and dissolved oxygen in the photocatalytic process. Meanwhile, the ALD generated TiO 2 nanolayer could both serve as reactive centers but also protecting armor for the CuS, which prohibited the peeling and oxidation of the thermal centers, leading to a high stability of the photocatalyst, which exhibits no obvious fading after 20-cycle reuse. A flow reactor was conceived and made by 3D print and the Ti-mesh based photocatalyst was integrated, which demonstrates high photocatlytic performances, manifesting its great potential for large-scale water treatment.
研究领域:
环境科学
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材料科学
✓ 已验证
产品关联
DOI
高影响因子
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
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2019
·
IF 3.131
Shiting Luo,Xiaoshan Lin,Limei Xu,Huicheng Guo,Jieyi Lai,Jianglun Wu,Yifei Feng,Lin Ma
In this work, a template-free hydrothermal strategy has been developed to fabricate 3D hierarchical MoS 2 microflowers on macroporous Ti mesh (MoS 2 MF-Ti) as a binder-free electrode for hydrogen evolution reaction (HER). It is found that the Ti mesh is able to provide an ideal platform for self-assembly of the MoS 2 nanosheets into the hierarchical microflowers. The as-prepared MoS 2 MF-Ti electrode is characteristic of meso/macro porous structures, abundant active edges and good conductivity. As a result, the MoS 2 MF-Ti demonstrates greatly enhanced electrocatalytic activity and stability toward HER due to its desirable structural features.
研究领域:
材料科学
·
电化学
✓ 已验证
DOI
高影响因子
CHEMISTRY-A EUROPEAN JOURNAL
·
2016
·Vol. 22
·期 42
·14831-14835
·
IF 5.771
Liang Cui,Xuping Sun,Yuanhong Xu,Wenrong Yang,Jingquan Liu
Graphical Hydrogen generation : The catalytic dehydrogenation of NaBH 4 in alkaline media for on-demand hydrogen generation can be effectively driven by self-supported Co(CO 3 ) 0.5 (OH)⋅0.11 H 2 O nanowire array on Ti mesh (CHNA/Ti), with a high hydrogen generation rate of 4000 mL min −1 g Co −1 and a low activation energy of 39.78 kJ mol −1 . In this work, for the first time, a cobalt carbonate hydroxide (Co(CO 3 ) 0.5 (OH)⋅0.11 H 2 O) nanowire array on Ti mesh (CHNA/Ti) was applied to drive the dehydrogenation of alkaline NaBH 4 solution for on-demand hydrogen production. Compared with other nanostructured Co-based catalyst systems, CHNA/Ti can be activated more quickly and separated easily from fuel solutions. This self-supported cobalt salt nanowire array catalyst works as an efficient and robust 3D catalyst for the hydrolysis reaction of NaBH 4 with a hydrogen generation rate of 4000 mL min −1 g Co −1 and a low apparent activation energy of 39.78 kJ mol −1 and offers an attractive system for on-demand hydrogen generation.
研究领域:
材料科学
·
能源化学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
CHEMISTRY-A EUROPEAN JOURNAL
·
2017
·Vol. 23
·期 29
·6959-6963
·
IF 5.317
Ruixiang Ge,Xiang Ren,Fengli Qu,Danni Liu,Min Ma,Shuai Hao,Gu Du,Abdullah M. Asiri,Liang Chen,Xuping Sun
Graphical Nickel–borate nanosheets array on titanium mesh (Ni−Bi NA/TM) is derived from NiSe 2 nanosheets array on titanium mesh (NiSe 2 NA/TM) by electrochemical transformation. As a three-dimensional electrode, Ni−Bi NA/TM exhibits high catalytic activity toward the oxygen evolution reaction and requires a low overpotential of 430 mV at 10 mA cm −2 in 0.1 m potassium borate (pH 9.2), with outstanding long-term stability and high turnover frequency. Nickel-borate nanosheets array on titanium mesh (Ni−Bi NA/TM) was derived from NiSe 2 nanosheets array on titanium mesh (NiSe 2 NA/TM) by electrochemical transformation. As a three-dimensional electrode, Ni−Bi NA/TM exhibited high catalytic activity toward the oxygen evolution reaction and required a low overpotential of 430 mV at 10 mA cm −2 in 0.1 m potassium borate (pH 9.2), with outstanding long-term stability and high turnover frequency.
研究领域:
材料科学
·
电化学
·
能源转换与储存
✓ 已验证
产品关联
DOI
PubMed
高影响因子
危险品化学品经营许可证（带存储）