JOURNAL OF ORGANIC CHEMISTRY
·
2021
·
IF 4.354
Zhibin Tian,Qihang Gong,Tianzeng Huang,Long Liu,Tieqiao Chen
A practical and sustainable synthesis of arylsulfonate esters has been developed through electro-oxidation. This reaction employed the stable and readily available phenols and sodium arenesulfinates as the starting materials and took place under mild reaction conditions without additional oxidants. A wide range of arylsulfonate esters including those bearing functional groups were produced in good to excellent yields. This reaction could also be conducted at a gram scale without a decrease of reaction efficiency. Those results well demonstrated the potential synthetic value of this reaction in organic synthesis.
研究领域:
有机化学
·
绿色化学
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DOI
PubMed
高影响因子
Asia-Pacific Journal of Chemical Engineering
·
2012
·Vol. 7
·期 6
·940-947
·
IF 0.758
Jianxian Zeng,Qincheng He,Hu Zhou,Xiahui Sun,Jiaojiao Zhang
Complexation–ultrafiltration process was investigated for cerium(III) recovery from aqueous solutions by using poly (acrylic acid) sodium salt (PAASS) as a complexing agent. The adsorption of cerium(III) on PAASS was preliminarily studied at different pH values. Next, effects of pH, polymer metal ratio (PMR), calcium(II) and competitive complexing agents on permeate flux ( J ) and cerium rejection coefficient ( R ) were investigated in the total recirculation mode. Finally, the integrations of four experiments including concentration, decomplexation, regeneration of PAASS and reuse of regenerated PAASS were carried out. Obtained results show that the adsorption can be described well using the Langmuir equation. If pH is reduced below 4, J decreases rapidly. PMR has negligible effect on J . R increases with increasing pH or PMR. Calcium(II) and ethylenediaminetetraacetic acid disodium salt have the effects on R , but these effects can decrease by increasing pH. Tartrate sodium does not influence R . In the process of concentration, J declines slowly, and R is about 1. It takes 40 min to reach the decomplexation equilibrium at pH 3. The decomplexation percentage of cerium(III)–PAASS complex is about 70%. In the regeneration of PAASS, cerium(III) can be removed effectively, and the purification of regenerated PAASS is acceptably satisfactory. The binding capacity of regenerated PAASS is close to that of fresh PAASS, and the recovery percentage of binding capacity is higher than 90%. © 2012 Curtin University of Technology and John Wiley & Sons, Ltd.
研究领域:
化学工程
·
环境科学
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DOI
高影响因子
CARBON
·
2019
·
IF 7.466
Piaopiao Wei,Jian Shen,Kangbing Wu,Nianjun Yang
Graphene electrochemistry is dependent on the quality of produced graphene. Ultrasonic exfoliation of graphite in a solvent with aid of sodium salts is believed to be a convenient method to prepare high-quality graphene layers , although the effect of sodium salts on the yields of exfoliated graphene and electrochemistry of graphene have not been clearly clarified. Herein, different sodium salts (e.g., sodium citrate, sodium phosphate, and sodium pyrophosphate) with different anions are added during ultrasonic exfoliation of graphite in N -methyl-2-pyrrolidone (NMP). Sodium pyrophosphate improves the most efficiently the graphene yield and decreases the number of graphene layers, leading to the highest defect content. On these defect-rich graphene layers, the redox response of K 3 [Fe(CN) 6 ] exhibits the fastest electron-transfer rate constant. Their active areas are also the largest, as revealed using rotating ring disk electrode and cyclic voltammetry . Moreover, the oxidation signals of biomolecules (e.g., dopamine, uric acid, xanthine, and hypoxanthine), phenolic pollutants (e.g., 4-chlorophenol and 4-nitrophenol), and toxic colorants (e.g., ponceau 4R and rhodamine B) are the mostly enhanced. This work proposes a novel way to synthesize defect-rich exfoliated 2D materials and further to construct universal interfaces for different electrochemical applications.
研究领域:
材料科学
·
电化学
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产品关联
DOI
高影响因子
FLUID PHASE EQUILIBRIA
·
2014
·
IF 2.241
Rongrong Li,Guobo Huang,Huanan Hu,Chenghong Li,Wenping Jia
In this work, solid–liquid equilibria (SLE) data for ternary sodium 1-naphthalenesulfonate + sodium 2-naphthalenesulfonate + water system was measured at (283.15, 303.15 and 323.15) K respectively. The diagrams for solid liquid phase of the ternary system were well-established by the measured solubility data. The solid phases formed in the studied system were determined by the method of Schreinemaker’s wet residue. Moreover, the density of equilibrium liquid phase was gained in the process. At each temperature, there are two pure solids forming. They are sodium 1-naphthalenesulfonate and sodium 2-naphthalenesulfonate in the ternary system. The solubility data for the ternary system were calculated and regressed by NRTL model, giving acceptable results for the investigated systems.
研究领域:
化学热力学
·
物理化学
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DOI
高影响因子
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
·
2019
·
IF 3.375
Kaixuan Yan,Xiaofeng Hang,Junsheng Liu,Jianquan Luo,Yinhua Wan
Hypophosphorous acid (H3PO2) is an important chemical product with wide applications in pharmaceuticals and electroless plating. In this study, bipolar membrane electrodialysis (BMED) was used to produce H3PO2 from sodium hypophosphite salt (NaH2PO2) to replace the traditional preparation methods. The BMED process was optimized in terms of current density, NaH2PO2 salt concentration, and initial NaOH concentration of the base solution. The results indicated that low Na+ leakage occurred at lower salt concentrations. Under the optimum conditions, such a BMED system obtained a high concentration of H3PO2, a low Na+ content, and a low energy consumption, equaling to 1.03 mol/L, 670 ppm, and 1.18 kW h/kg, respectively. To minimize the amount of phosphorous acid (H3PO3) generated from H3PO2 oxidation during the BMED process, a nitrogen aeration operation was applied in both the acid and salt chambers, decreasing the HPO32– content to 251 ppm, which was 44.1% lower than that without a dissolved oxygen content control strategy. The newly produced H3PO3 during the BMED process was reduced by 96.5%. The obtained results indicated that the BMED process has great potential for application in the production of high-quality H3PO2 from NaH2PO2 in industry.
研究领域:
化学工程
·
环境科学
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产品关联
DOI
高影响因子
JOURNAL OF CHEMICAL AND ENGINEERING DATA
·
2015
·
IF 2.037
Rongrong Li,Jian Wan,Yingjie Zhang,Danxia Liang,Bin Zhang,Chenghong Li
The equilibrium solubility of sodium 1-naphthalenesulfonate in binary NaCl + water, Na2SO4 + water, and C2H5OH + water solvent mixtures was measured by a steady-state method at elevated temperatures from (278.15 to 323.15) K. The results of these data were correlated by a modified Apelblat equation. The dissolution enthalpy (ΔHd) and entropy (ΔSd) of sodium 1-naphthalenesulfonate in solutions of different mole fraction were obtained.
研究领域:
物理化学
·
热力学
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产品关联
DOI
高影响因子
ORGANIC PROCESS RESEARCH & DEVELOPMENT
·
2023
·
IF 3.4
Shichun Weng,Wei Feng,Wenqian Wu,Zichao Guo,Liping Chen,Wanghua Chen
Nitrophenols and corresponding sodium nitrophenolates are the main side products in the production of mononitrobenzene (MNB). These side products are hazardous due to their thermal instability nature. In this article, the thermal decomposition behaviors of nitrophenols and sodium nitrophenolates were first characterized by differential scanning calorimeter and accelerating rate calorimetry techniques. Then, the influence of phenol and sodium phenolate on the thermal decomposition of MNB was studied to clarify the effect of phenolic hydroxyl groups on the thermal stability of nitrophenols. It was found that compared to nitrophenols, the exothermic peaks of sodium nitrophenolates were more intense and presented strongly autocatalytic features. Sodium phenolate could significantly decrease the decomposition temperature of MNB. Aniline was detected as the unique product in the decomposition processes of pure MNB and MNB/sodium phenolate mixtures, and the nitrosobenzene was verified as the intermediate product. It was experimentally proven that sodium phenolate could catalyze the decomposition of nitrosobenzene (the decomposition intermediate of MNB). The violent decomposition of sodium nitrophenols was caused by the intermolecular catalysis effect of phenoxy groups.
研究领域:
化学工程
·
安全科学
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产品关联
DOI
高影响因子
JOURNAL OF CHEMICAL AND ENGINEERING DATA
·
2024
·
IF 2
Hongxiang Xu,Wentao Li,Junfeng Wang,Jiushuai Deng,Shangqing Chen
After the NaClO solution was used to purify acetylene gas, the solution contained significant amounts of NaCl, Na2SO4, and Na2HPO4. The phase equilibrium data is the most important basic information for recovering sodium salts. In this study, the solubilities and dry-salt phase diagram for the system (Na+//Cl–-SO42–-HPO42–-H2O) were systemically studied. The dry-salt phase diagram contained one invariable point, three univariate solubility curves, and three single salt crystallization regions corresponding to NaCl, Na2SO4, and Na2HPO4·12H2O at 298.15 K and 0.1 MPa. Based on the ELEC-NRTL and Pitzer model embedded in the Aspen Plus, the phase equilibrium data for the ternary subsystem (Na+//Cl–-SO42–-H2O, Na+//Cl–-HPO42–-H2O, and Na+//SO42–-HPO42–-H2O) at 298.15 K and 0.1 MPa taken from the literature were first predicted to verify the applicability of parameters from the default database and literature. Subsequently, the models were optimized by literature solubility data, and then, the obtained parameters can well predict the phase equilibrium data for the ternary subsystem at 298.15 K and 0.1 MPa. All of these will provide basis data for the separation of sodium salt from the Na+//Cl–-SO42–-HPO42–-H2O system.
研究领域:
化学工程
·
环境科学
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产品关联
DOI
高影响因子
JOURNAL OF MATERIALS RESEARCH
·
2019
·Vol. 34
·期 4
·510-518
·
IF 1.982
Yanjun Zhao,Weiyu Yao,Yu Wang,Quan Wang,Feipeng Lou,Weihong Guo
Graphene (G) has attracted great interest because of its excellent chemical and electrical properties. However, the aggregation of graphene restricts its application. Herein, linoleic acid sodium salt (LASS), a low-cost and environmentally friendly material, was used to improve the dispersion of graphene through covalent interaction. Then, the mixture (G@LASS) was integrated with acrylic resin matrix via hydrogen bond between the carboxyl and ester groups. The excellent interfacial compatibility between G@LASS and acrylic matrix, as well as good dispersibility of G@LASS, was demonstrated by Fourier-transform infrared spectroscopy, X-ray photoelectron spectroscopy, Raman, and scanning electron microscopy tests. Compared with acrylic matrix, the surface hydrophobicity of G@LASS@Acrylic increased considerably because of its compact structure. G@LASS@Acrylic composites meet the requirement of antistatic materials when the content of G was only about 0.5 wt%. The results showed that conductive pathways were established successfully through this method.
研究领域:
材料科学
·
化学工程
✓ 已验证
产品关联
DOI
高影响因子
TRIBOLOGY LETTERS
·
2019
·Vol. 67
·期 2
·1-14
·
IF 2.235
Yang Ye,Zhang Chenhui,Dai Yuanjing,Luo Jianbin
Effective water-based lubricants for titanium alloys have been investigated. The results reveal that castor oil sulfated sodium salt (CSS) solution can decrease the friction coefficient and adhesive wear compared with water, polyalkylene glycol (PAG) aqueous solution, or castor oil. The surface morphology of the tested discs and balls were measured, and the mechanism investigated. The rubbing surface was analyzed by using time-of-flight secondary-ion mass spectrometry (ToF–SIMS), indicating that a layer of physically adsorbed film remained on the surface, the main ingredient of which was CSS molecules. The mass and morphology of the adsorbed film were explored by quartz crystal microbalance measurements with dissipation monitoring and atom force microscopy, respectively. An electrical voltage, which could change the electrostatic force of the lubricants with the metal surface, was then applied to the frictional pair to explore the mechanism driving the adsorption. The physically adsorbed film played an important role in lubrication. The results of this study indicate that CSS could represent a good water-based lubricant base stock for the design of cutting fluids for titanium alloys.
研究领域:
材料科学
·
表面工程
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产品关联
DOI
高影响因子
Journal of Chemistry
·
2019
·
IF 1.727
Hongbin Guo,Mengqiao Chen,Mengran Li,Mingye Hu,Baohua Chen,Chengyan Zhou
Mangiferin (MG) is an active component in natural medicines, and various studies have been reported on pharmacological effects, but the low solubility and bioavailability of MG limit its wide application. The aim of the present study was to investigate the pharmacokinetic profiles of mangiferin (MG) and mangiferin monosodium salt (MG-Na) in rat plasma by UPLC-MS/MS, which were then compared between the two groups. An appropriate high sensitivity and selectivity ultraperformance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS) method was applied to the comparison of plasma pharmacokinetics in MG and MG-Na using carbamazepine as internal standard (IS). These results showed that there were statistically significant differences in the pharmacokinetic parameters between MG and MG-Na after a single oral administration at 100 mg/kg. When compared with pharmacokinetic parameters of MG, the AUC(0-t), AUC(0–∞), Cmax,K10, and Ka of MG-Na were increased by 5.6-, 5.7-, 20.8-, 8-, and 83.6-fold, while the Tmax and CL/F were decreased by 4- and 5.7-fold (), respectively. t1/2 value showed an increasing trend, but was statistically significant between the two groups. Moreover, the AUC value in the MG-Na group was significantly increased and the relative bioavailability was calculated to be 570% when compared with that of the MG group. These results suggested that the salification reaction of MG can effectively enhance gastrointestinal absorption and relative bioavailability by improving solubility and membrane permeability.
研究领域:
药理学
·
分析化学
✓ 已验证
DOI
高影响因子
JOURNAL OF FOOD SCIENCE
·
2024
·Vol. 89
·期 12
·9060-9072
·
IF 3.2
Haibo Shi,Yongjie Li,Jiabao Zheng,Xianqi Yao,Wei Wang,Igor Tomasevic,Weizheng Sun
The protein structure, gel changes, and chewing properties of low-sodium myofibrillar protein (MP) prepared by compound chloride salts (KCl/MgCl 2 , KCl/CaCl 2 , and KCl/MgCl 2 /CaCl 2 ) and different substitution degrees (10%, 25%, and 40%) at same ionic strength (0.6 M) were investigated. The results revealed that the low-sodium MP gels containing CaCl 2 manifested more liquid loss and less moisture content accompanied by obvious morphological shrinkage, while KCl/MgCl 2 contributed to the gel juiciness. At high substitution degree of 40%, KCl/CaCl 2 substitution rendered the gel with dense structure and highest strength, but worse water retention capacity. Using other compound chloride salts influenced the chewing efficiency, and CaCl 2 substitution made the gel relatively hard to chew. The inhomogeneous structure accompanied by cluster blocks in KCl/CaCl 2 -substituted MP gel accelerated the overall fracture rate. During heating process, more proteins in CaCl 2 -substituted MP did not participate in gel formation, intervening the final gel properties. The chloride salt mixtures containing MgCl 2 , rather than CaCl 2 , avoided or alleviated the liquid loss and shrinkage of low-sodium MP gel within the substitution degree of 10%–40%, and substitution degree not exceeding 25% was more reasonable for the controlled qualities.
研究领域:
食品科学
·
蛋白质化学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
危险品化学品经营许可证（带存储）