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APPLIED PHYSICS LETTERS · 2016 ·Vol. 108 ·期 18 · IF 3.142

Inverted polymer solar cells with enhanced fill factor by inserting the potassium stearate interfacial modification layer

Li Jiangsheng,Jiu Tonggang,Li Bairu,Kuang Chaoyang,Chen Qiushan,Ma Sushuang,Shu Jie,Fang Junfeng

A thin potassium stearate (KSt) film combined with an optimized ZnO film was introduced to improve the fill factor (FF) of highly efficient inverted polymer solar cells (PSCs). Atomic force microscopy and contact angle measurements were used to show that the introduction of KSt did not change the morphology of interlayer. On the contrary, it is beneficial for the spread of the active layer on the interlayer. The origin of enhanced FF was systematically studied by the ideal current-voltage model for a single heterojunction solar cell and electrochemical impedance spectroscopy. On the basis of the data analysis, the reduced charge recombination loss was responsible for this improved FF. At last, when KSt was replaced by sodium stearate (NaSt), the similar experiment phenomenon was observed. This indicates that inserting a metallic stearate modified layer is a promising strategy to enhance inverted PSCs performance.

研究领域: 材料科学 · 能源科学 · 光伏技术
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