Song Zhou,Xi Liu,Jian Xu,Hui Zhang,Xiaosong Liu,Pengcheng Li,Xiaodong Wen,Yong Yang,Yongwang Li
As an alternative to noble metal hydrogenation catalysts, pure molybdenum carbide displays unsatisfactory catalytic activity for arene hydrogenation. Precious metals such as palladium, platinum, and gold are widely used as additives to enhance the catalytic activities of molybdenum carbide, which severely limits its potential applications in industry. In this paper, iron-promoted molybdenum carbide was prepared and characterized by various techniques, including in situ XRD, synchrotron-based XPS and TEM. while the influence of Fe addition on catalytic performance for toluene hydrogenation was also studied. The experimental data disclose that a small amount of Fe doping strongly enhances catalytic stability in toluene hydrogenation, but the catalytic performance drops rapidly with higher loading amounts of Fe.Keywords:molybdenum carbide;Fe-promoter;toluene hydrogenation;synchrotron-based XPS;in situ XRD
Menglan Wang,Yudong Li,Qing-An Wu,Shuping Luo,Yuehui Li
Indole scaffold synthesis relies primarily on oxidative C–H amination of N-protected alkenylanilines for C–N intramolecular cyclization reactions. Herein, for the first time, without N-protection, various readily prepared 2-alkenylanilines were transformed into the desired indole products in good yields by using K2S2O8 as oxidant in the presence of catalytic amounts of FeF2. The K2S2O8/FeF2 system offers a direct and benign synthetic route to 3-arylindoles and it is applicable to a wide range of substituted indoles including drug intermediates.
危险品化学品经营许可证（带存储）