Preparation of Fe-based magnetic-core-supported Co and Ni catalyst: application in viscosity reduction of heavy oil hydrocracking
BACKGROUND Heavy oil has the characteristics of high viscosity and low American Petroleum Institute gravity, which makes it difficult to transport and produce. The key to efficiently utilizing heavy oil is reducing viscosity and improving quality. Hydroconversion has the advantages of viscosity reduction and decreased coke production, but it is difficult to separate nonmagnetic catalysts from the reaction system, which affects the industrial application. RESULTS A spherical Fe 3 O 4 (74.71 emu g −1 ) and a chain Fe Fe 2 O 3 (110 emu g −1 ) were prepared as magnetic cores, and coated with SiO 2 and Al 2 O 3 layers, respectively. The metal-supported catalyst modified with Co and Ni show irregular and honeycomb-shaped surfaces, and the magnetic saturation strength decreases to 24.91 and 14.63 emu g −1 , but still possessing superparamagnetic properties, enabling the catalysts to be separated from the reaction mixture. Fe-Fe 2 O 3 @SiO 2 @Al 2 O 3 @CoNi catalyst has the best viscosity reduction effect for Canadian oil sands asphalt residue at about 410 °C and 10 MPa hydrogen pressure. The viscosity of the liquid product decreased significantly from 56 600 to 135 mPa s at 50 °C, with a viscosity reduction of 99.8%. CONCLUSION Magnetic catalyst prepared from chain-like Fe-Fe 2 O 3 has an excellent honeycomb structure, which can provide increased active surfaces and exhibit improved viscosity reduction performance. This work provides a strategy for the recovery of heavy oil hydrogenation catalysts and is expected to play a key role in the practical application of heavy oil hydrogenation catalytic viscosity reduction. © 2023 Society of Chemical Industry.
危险品化学品经营许可证（带存储）