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JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS · 2022 ·Vol. 33 ·期 22 ·17814-17827 · IF 2.779

Effects of Pb–B–Si–O glass on the microstructures and electrical properties of silver electrode for LTCC application

Liu Zhuofeng,Liang Wenxue,Zhang Weijun,Wang Fenglin,Xun Yan,Chen Tongting,Li Wei,Chen Xingyu,Mao Haijun

The co-firing compatibility between green tape and the Ag electrode is a crucial characteristic in low-temperature co-fired ceramic (LTCC) technology and plays a vital role in improving the performance and application status of LTCC device modules. In this work, we studied the effects of lead content on the glass viscosity, the microstructure, and co-firing compatibility of silver electrode film. It was found that the softening point and viscosity of the glass were decreased, and the wettability between the glass and silver was improved with the increase of the lead content, which promoted the co-firing densification and interfacial bonding between the silver electrode film and the ceramic layer. The film presented the best electrical properties co-firing at 875 °C for 15 min, with the resistivity of 1.21 mΩ/sq. And the film was densified. The sintering interface was clear and well bonded. The results showed that an appropriate lead content in glass could effectively improve the interfacial bonding and the electrical properties during co-fired process, providing a new control methodology for realizing co-fired matching of the silver electrode film with low-temperature co-fired ceramics.

研究领域: 材料科学 · 电子工程
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Functional Materials Letters · 2024 · IF 1.2

Preparation of F/Mn-doped CsPb(Br/Cl)3 quantum-dot glass and their luminescence properties

Zhuqing Sun,Yongxia Li,Haowen Bai,Shenghang Jin,Haibo Zhang,Guanying Cao

All inorganic lead halide cesium perovskite quantum dots (QDs) have attracted much attention due to their excellent luminescence properties, but further development is restricted by their stability and the existence of toxic element lead. In this paper, F/Mn-doped CsPb ( Br / Cl ) 3 QDs glass was prepared by melt quenching and heat treatment, with reduced Pb content effectively. The result shows that the spectrum of the QD glass is adjustable between 450 nm and 515.4 nm by changing the feeding ratio of Mn-Pb ion and heat treatment temperature. Moreover, the indraught of Mn 2 + effectively improves the PLQY of CsPb ( Br / Cl ) 3 QDs glass and serves as a red-emitting. The prepared composites not only maintain good fluorescence characteristics, but also greatly improve the stability of QDs. And successfully coupled with blue LED chips to synthesize WLED, Under 20 mA current, the color coordinate is (0.3446, 0.3389).

研究领域: 材料科学 · 纳米技术 · 光电子学 · 固体物理 · 无机化学
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