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CHINESE CHEMICAL LETTERS · 2023 · IF 9.1

Recovery of cathode copper and ternary precursors from CuS slag derived by waste lithium-ion batteries: Process analysis and evaluation

Yun Wei,Lei Zhou,Wenbin Hu,Liming Yang,Guang Yang,Chaoqiang Wang,Hui Shi,Fei Han,Yufa Feng,Xuan Ding,Penghui Shao,Xubiao Luo

The efficient and environmentally friendly recycling technology of waste residue that including abundant heavy metal produced during the recovery of lithium batteries has become a research hotspot. Herein, a novelty process of acid leaching-selective electrodeposition-deep impurity removal-regeneration was proposed to recovery of the CuS slag, which has been efficient transferred to high purity cathode copper and commercially available ternary precursors. Copper cathode with a purity of 99.67% was prepared under electrochemical reaction conditions at −0.55 V for 2 h. A novel impurity remover-Mn powder, which was used to remove the residual impurities and as a feedstock for the ternary precursor. Finally, NCM523 was regenerated by co-precipitation. The process is superior to the traditional process in economy, energy consumption, CO 2 emissions, product purity and process duration. This study provides a new approach for solid waste recovery and precious metal enrichment.

CAS / MDL: 7439-96-5
研究领域: 环境科学 · 材料科学 · 冶金工程
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