Suppression of performance of activated carbon filter due to residual aluminum accumulation
Extending the lifetime of granular activated carbon (GAC) filters with no significant loss in their effectiveness is a considerable challenge for drinking water supply utilities. However, the effects of residual Al from coagulants on GAC performance are rarely considered. Herein, in-service GAC samples obtained from full-scale water treatment plants were investigated to evaluate the amount of accumulated Al. Although the Al concentration in water was two to three times lower than the Ca concentration, Al exhibited considerable accumulation (second to Ca accumulation) in in-service GAC samples (0.68–8.63 mg g −1 ). Surface characterization results indicated that Al accumulation could have been caused by the co-precipitation of Al with Ca and Si to form Ca 4 Al 2 Si 3 O 10 ·H 2 O and Ca 4 Al 6 O 12 SO 4 , self-precipitation or complexion with −OH/−COOH on the GAC or biofilm surfaces. Correlation analysis of the accumulated Al and GAC properties implied that Al accumulation considerably reduced the surface area of GAC by ∼30%. Lab simulation experiments indicated that the removal of dissolved organic matter was reduced by 6–10% when additional Al was loaded. In addition, results showed that the residual Al (up to 200 μg L −1 ) considerably affected the extracellular polymeric substance component and microorganism community structure. In summary, strict control of residual Al is beneficial for maintaining the efficacies of GAC and biologically activated carbon.
危险品化学品经营许可证（带存储）