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Micromachines · 2018 ·Vol. 9 ·期 10 ·501 · IF 2.222

Shear Mode Bulk Acoustic Resonator Based on Inclined c-Axis AlN Film for Monitoring of Human Hemostatic Parameters

Shuren Song,Da Chen,Hongfei Wang,Chaohui Li,Wei Wang,Wangli Yu,Yanyan Wang,Qiuquan Guo

Measurement of hemostatic parameters is essential for patients receiving long-term oral anticoagulant agents. In this paper, we present a shear mode bulk acoustic resonator based on an inclinedc-axis aluminum nitride (AlN) film for monitoring the human hemostatic parameters. During the blood coagulation process, the resonant frequency of the device decreases along with a step-ladder profile due to the viscosity change during the formation of fibers in blood, revealing the sequential coagulation stages. Two hemostatic parameters with clinical significance, prothrombin time (PT) along with its derived measure of international normalized ratio (INR), are determined from time-frequency curves of the device. Furthermore, the resonator is compared with a commercial coagulometer by monitoring the hemostatic parameters for one month in a patient taking the oral anticoagulant. The results are consistent. In addition, thanks to the excellent potential for integration, miniaturization and the availability of direct digital signals, the proposed device has promising application for point of care coagulation monitoring.Keywords:bulk acoustic wave;AlN film;hemostatic parameters;viscosity sensor

CAS / MDL: 91-17-8
研究领域: 生物医学工程 · 临床检验学
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MATERIALS & DESIGN · 2021 · IF 7.991

Flexible graphene/silver nanoparticles/aluminum film paper for high-performance electromagnetic interference shielding

Xiang Li,Yifei Qu,Xiu Wang,Huiyang Bian,Weibing Wu,Hongqi Dai

Rubber and plastic are widely acted as substrates in flexible electromagnetic shielding (EMS) materials. However, these materials have several drawbacks in practical applications, such as potential environmental concerns and difficulties in degrading. In this work, a biodegradability paper-based material composed of electromagnetic wave loss layer (graphene/ silver nanoparticles (AgNPs) coating) and reflective layer (aluminum film layer) was successfully fabricated. The electromagnetic wave loss layer constructed three-dimensional (3D) electric conductive network to facilitate the timely transfer of electrons and heat energy obtained from electromagnetic waves. Meanwhile, the reflective layer received electrons and heat from the electric conductive network and make a small quantity of transmission wave back to the wave loss layer. The resulting material exhibited an ultrahigh electromagnetic interference shielding effectiveness (EMI SE) of 92.29 dB within 8–13 GHz, electrical conductivity of 4431 S/m, mechanical properties with a tensile strength of 32 MPa and elongation at break of 6.65%. Compared to the traditional EMS materials, the composite material integrated with excellent EMI SE, heat transfer performance, and weatherability, which has potential applications in microelectronics, high integrated circuits, and flexible electronic fields.

研究领域: 材料科学 · 电子工程
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MATERIALS LETTERS · 2017 · IF 2.572

Combination of chemical etching and electrophoretic deposition for the fabrication of multi-scale superhydrophobic Al films

Zhibo Wei,Deyi Jiang,Jie Chen,Xiaogang Guo

In this study, we reported a new method to fabricate superhydrophobic Al films by combination of HCl/H 2 O 2 etching and electrophoretic deposition process. Through this two-step method, multi-scale hierarchical structures were successfully introduced on the surface. After hydrophobization, the resultant surface showed an excellent superhydrophobicity with a water contact angle of 169.6° and a sliding angle of ca. 1°. Furthermore, the surface exhibited excellent mechanical durability and could withstand abrasion tests under 8   kPa for 60   cm without losing superhydrophobicity. It also maintained superhydrophobicity when exposed to air or water for a long-term period. This work provides a cost efficient method to prepare mechanically robust and stable superhydrophobic Al alloy surface.

CAS / MDL: 7783-85-9 7429-90-5
研究领域: 材料科学 · 表面工程
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JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS · 2020 ·Vol. 31 ·期 3 ·2686-2690 · IF 2.22

Alumina film deposited by spin-coating method for silicon wafer surface passivation

Cao Liqi,Yang Ning,Li Shizheng,Ye Xiaojun,Yuan Xiao,Li Hongbo,Tong Hua

In the present work, alumina gel was developed for passivating silicon wafers. The alumina gel was prepared by sol–gel method with aluminum sec-butoxide as precursor. After coating, rapid thermal process (RTP) was conducted to activate the passivation effect. X-ray photoelectron spectroscopy and C–V curve were executed to evaluate film properties. The peak at 74.35 eV confirmed the formation of Al 2 O 3 . Meanwhile, a small peak at low binding energy decreased with the growth of annealing temperature, which was ascribed to the escape of hydrogen, leading to the decline of effective lifetime after 700 °C. The highest fixed charge (Q f ) of − 1.16e12 cm −2 and superior interface defect density at mid gap (D it ) of 1.98e12 cm −2 eV −1 were obtained at the annealing temperature of 700 °C, contributing to the highest effective minority carrier lifetime of 292 µs. The present work will be helpful to provide a more cost-effective technique for Al 2 O 3 passivation.

CAS / MDL: 2269-22-9
研究领域: 材料科学 · 半导体物理
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JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS · 2020 ·Vol. 31 ·期 16 ·13503-13510 · IF 2.22

Ultra-low-voltage electrophoretic assembly of extremely water-repellent functional nano-Al films with long lifespan

Guo Xiaogang,Wang Jing,Liang Taotao,Yuan Binfang,Sun Qi

It is still a bottleneck to design anti-wetting homogeneous metal films or coatings with great stability via by a high-efficiency and low-cost technique with applications in fields of battery, sensors, and electronics, etc. This paper proposed an environment-friendly ultra-low-voltage electrophoretic deposition (EPD) with facile modification post-processing method to fabricate a novel extremely water-repellent functional nano-Al films with evenly loose net-like structures and high purity. The optimized stable suspension consists of water–ethanol with trace nitric acid and polyethyleneimine. Product with an ultra-high contact angle of ~ 171° and extreme low sliding angle of < 1° showed extremely anti-wetting properties, and outstanding water-repellent stability or long lifespan (> 3 years) with great potential applications. These results provide a novel approach with low-cost and less energy consumption for preparing other functional ant-wetting metal coatings with wide potential applications.

CAS / MDL: 101947-16-4 7429-90-5
研究领域: 材料科学 · 表面工程 · 功能涂层
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JOURNAL OF COLLOID AND INTERFACE SCIENCE · 2022 · IF 9.965

Plasma and magnetron sputtering constructed dual-functional polysulfides barrier separator for high-performance lithium-sulfur batteries

Yaochen Song,Xiongbang Wei,Ziqi Zhao,Yilin Yao,Linnan Bi,Yuhong Qiu,Xin Long,Zhi Chen,Sizhe Wang,Jiaxuan Liao

In order to fundamentally suppress the shuttle effect, N 2 Plasma & Al 2 O 3 magnetron sputtered separators (Al 2 O 3 @ N -PP) are proposed for lithium-sulfur batteries (LSBs). Such a dual-functional polysulfides (LiPSs) barrier separator greatly inhibits the shuttle effect from the perspective of physical and chemical interaction. Physically, the inherently electronegative amorphous Al 2 O 3 first achieves the repulsion of LiPSs to the sulfur cathode through the electrostatic repulsive effect, effectively preventing a large amount of soluble LiPSs from accumulating at the separator. At the same time, the Al 2 O 3 film seals the shuttle channel of LiPSs to a certain extent. Chemically, N 2 plasma-doped N heteroatoms form a lithium bond with Li + in LiPSs to achieve the first step chemical adsorption and anchoring of LiPSs. When the LiPSs reaches the amorphous Al 2 O 3 film, more stable chemical bonds are formed between Al 3+ and S 2− , Li + and O 2– to achieve more effective adsorption and anchoring of LiPSs. At 1C with a high sulfur loading up to 3–5 mg cm −2 the LSB contributes a specific charge capacity of 717.4 mAh g −1 , with high retention rate up to 75.49 % after 450 cycles. The U-shaped electrolytic cell experiment and ultraviolet–visible spectrum experiment confirmed the LiPSs barrier function of the functional separator.

研究领域: 电化学 · 能源材料 · 纳米材料 · 表面工程 · 储能技术
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REVIEW OF SCIENTIFIC INSTRUMENTS · 2015 ·Vol. 86 ·期 7 · IF 1.614

Fluidized bed coupled rotary reactor for nanoparticles coating via atomic layer deposition

Duan Chen-Long,Liu Xiao,Shan Bin,Chen Rong

A fluidized bed coupled rotary reactor has been designed for coating on nanoparticles (NPs) via atomic layer deposition. It consists of five major parts: reaction chamber, dosing and fluidizing section, pumping section, rotary manipulator components, as well as a double-layer cartridge for the storage of particles. In the deposition procedure, continuous fluidization of particles enlarges and homogenizes the void fraction in the particle bed, while rotation enhances the gas-solid interactions to stabilize fluidization. The particle cartridge presented here enables both the fluidization and rotation acting on the particle bed, demonstrated by the analysis of pressure drop. Moreover, enlarged interstitials and intense gas–solid contact under sufficient fluidizing velocity and proper rotation speed facilitate the precursor delivery throughout the particle bed and consequently provide a fast coating process. The cartridge can ensure precursors flowing through the particle bed exclusively to achieve high utilization without static exposure operation. By optimizing superficial gas velocities and rotation speeds, minimum pulse time for complete coating has been shortened in experiment, and in situ mass spectrometry showed the precursor usage can reach 90%. Inductively coupled plasma-optical emission spectroscopy results suggested a saturated growth of nanoscale Al 2 O 3 films on spherical SiO 2 NPs. Finally, the uniformity and composition of the shells were characterized by high angle annular dark field-transmission electron microscopy and energy dispersive X-ray spectroscopy.

CAS / MDL: 7631-86-9
研究领域: 化学工程 · 材料科学 · 纳米技术 · 表面化学
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