Metal-organic framework derived spinel tricobalt tetroxide with trifle iridium sites for near-pH-neutral seawater electrolysis
Metal-organic frameworks (MOFs) derived spinel tricobalt tetroxide (Co 3 O 4 ) electrocatalysts incorporated with trifle Iridium (Ir) sites are in-situ grown on nickel foam (NF) substrate (Ir-Co 3 O 4 /NF) as effective anode for OER especially in near-pH-neutral seawater with high ability to suppress chlorine evolution reaction. Density functional theory (DFT) calculations indicate that the trifle Ir sites can be safeguarded in spinel Co 3 O 4 via structural-confinement and charge-redistribution so that the Ir and Co sites with their bridged electrophilic O ligands can serve as the active sites for boosting OER performance. As expected, a relatively low OER overpotential of 370 mV @ 10 mA cm −2 and it is achieved with at least 7 days durability under the current density of 100 mA cm −2 in near-pH-neutral simulated seawater with high selectivity toward OER. In same condition, a fabricated electrolyzer using it presents excellent electrocatalytic performance with a cell voltage of 2.11 V @ 100 mA cm −2 , strongly suggesting that the present electrolyzer has great promising for practical seawater electrolysis.
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