Enhancing performance of tin-based perovskite solar cells by polyvinyl pyrrolidone doping strategy
The power conversion efficiency (PCE) of tin-based perovskite solar cells (TPSCs) was significantly improved when polyvinyl pyrrolidone (PVP) was doped into the formamidinium tin iodide (FASnI 3 ) layer with an optimized doping mass. After doping, the FASnI 3 grain size, film smoothness and average carrier lifetime were largely enhanced, which demonstrate the crystallization quality improvement to FASnI 3 . The champion PCE of the enhanced TPSC was improved to 7.83%, which is relatively 27% larger than that of the control, 6.15%. After continuous storage for 15 days, the PCE of the enhanced TPSC remained 74.4% of its original value. Using the finite difference time domain (FDTD) simulation method, we demonstrated that the light absorption ratio of the FASnI 3 :PVP layer was larger than that of the FASnI 3 , and the photo-generated carrier density of the enhanced TPSC was approximately 2% ∼ 3% larger than that of the control. The ultimate efficiency of the enhanced TPSC was calculated to be 26.23%. It is potential to dope PVP into FASnI 3 to further enhance the device performance of TPSCs.
危险品化学品经营许可证（带存储）