High-Voltage and Stable Manganese Hexacyanoferrate/Zinc Batteries Using Gel Electrolytes
Because of the high safety and environmental friendliness, aqueous zinc-ion batteries have gained a lot of attention in recent years. Prussian blue and its analogues are regarded as a promising cathode material of zinc-ion batteries. Manganese hexacyanoferrate is appropriate among them due to its high operating voltage, large capacity, and cheap price. However, the poor cycling stability of manganese hexacyanoferrate, mainly caused by transition metal dissolution, side reaction, and phase transition, greatly restricts its practical application. In this work, gelatin is used to limit the content of free water in the electrolyte, thus reducing the dissolution effect of transition metal manganese. The introduction of gelatin improves the durability of the Zn anode as well. The optimized MnHCF/gel-0.3/Zn battery displays a high reversible capacity (120 mAh·g–1 at 0.1 A·g–1), an excellent rate performance (42.7 mAh·g–1 at 2 A·g–1), and a good capacity retention (65% at 0.5 A·g–1 after 1000 cycles).
危险品化学品经营许可证（带存储）