Microstructure and Catalytic Activity of MnSbOx Catalysts for Selective Catalytic Reduction of NO with NH3
Manganese-antimony composite oxide catalysts were prepared for use in low-temperature selective catalytic reduction of flue gas, by adopting the strategy of passivation to regulate the valence state of the active component and control catalytic activity. Activity evaluation results found that MnSb 0.36 O y delivered 80 % NO conversion in the presence of SO 2 at 200 °C, and nearly 90 % conversion at 250 °C. Doping with Sb changed the surface micromorphology, resulting in a perforated porousness layered foam with a porous structure of tens of nanometers, which was conducive to molecular mass transfer of the reaction gas. Doping with Sb regulated the valence state of the active MnO x component, which diminished catalytic oxidation of SO 2 , thus promoting catalyst stability and limiting the toxic effect of SO 2 .
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