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JOURNAL OF APPLIED POLYMER SCIENCE · 2019 ·Vol. 137 ·期 24 ·48813 · IF 2.188

Hydrogen-bonding assembly of heteropolyacid and poly(vinyl alcohol) for strong, flexible, and transparent UV-protective films

Ziang Zhang,Kui Chen,Qun Tang,Heping Li,Zhiming Zou

Although many preparation approaches have been developed, it remains a huge challenge to achieve ultraviolet (UV)-protection films that combine high transparency, excellent UV-shielding, and mechanical properties. Herein, we demonstrate a facile and eco-friendly process for fabricating strong, flexible, and transparent UV-protective poly(vinyl alcohol) (PVA) films by exploiting silicomolybdic acid (SiMoA) as UV absorber and reinforcing phase. Fourier-transform infrared analysis confirms the formation of strong hydrogen-bonding interactions between PVA and SiMoA. The glass-transition temperature, mechanical properties, and UV-shielding stability of the UV-protective PVA composite films obviously increase with increasing the content of SiMoA. By incorporation of only 2 wt % SiMoA, the UV-protective PVA composite film can block more than 90% of UV light in the entire UV regions and retain high visible light transparency (up to 95%). Simultaneously, the UV-protective PVA composite film presents excellent mechanical properties with a tensile strength of 65.2 MPa and an elongation at break of 172.6%, which are 72.0 and 69.5% higher than that of pristine PVA films. This work provides a simple but effective approach for creating strong, flexible, and transparent UV-blocking polymeric materials via hydrogen-bonding assembly, which are expected to have wide application prospects in UV-protection field. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137 , 48813.

研究领域: 材料科学 · 高分子化学
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ADVANCED FUNCTIONAL MATERIALS · 2023 ·Vol. 33 ·期 51 ·2305411 · IF 19

Integrated High Barrier and Efficient Moisture-Wicking Multilayer Textile for Medical and Health Protection

Na Meng,Yufei Zhang,Yanyan Lin,Cengceng Zhao,Zhaoling Li,Xianfeng Wang,Jianyong Yu,Bin Ding

Developing textiles with rapid moisture-wicking capability is a potential and effective solution to the poor comfort of medical and health-protective clothing. However, designing protective clothing that combines safety and comfort remains a crucial and formidable task. Herein, a moisture-wicking protective fibrous membrane (MWPFM) with a dual-gradient structure manufactured by electrospinning and electrostatic spraying techniques is proposed. Interestingly, the protective layer with a small pore structure and an extremely hydrophobic effect can block water, blood, and ethanol. Additionally, the textile is designed in a multilayer configuration with a wetting gradient and pore structure gradient, ensuring comfort. The MWPFM exhibits excellent protective properties (ethanol contact angle of 115°, hydrostatic pressure of 14.8 kPa) and comfort (breathability of 46.8 mm s −1 , water vapor transmission rate of 5.9 kg m −2 d −1 ). In addition, compared with the commercially available high-density polyethylene protective membrane, MWPFM displays a distinct comfort advantage. This work provides a fresh avenue to improve the thermal-moisture comfort of medical and health-protective clothing.

研究领域: 纺织材料学 · 生物医学工程 · 防护材料研究
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