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JOURNAL OF APPLIED POLYMER SCIENCE · 2011 ·Vol. 122 ·期 3 ·2090-2098 · IF 1.24

Ultraviolet resistant/antiwrinkle finishing of cotton fabrics by sol-gel method

Chenghui Zheng,Guoqiang Chen,Zhenming QI

Nano titanium dioxide (TiO 2 ) sols were prepared by sol-gel method with tetrabutyl orthotitanate (TBOT) as precursors, citric acid (CA) as inhibitors. Ultraviolet resistant capacity of finished cotton fabrics are greatly improved with good wrinkle-resistance, whiteness and tensile strength as well. The optimum molar ratio for preparing nano-TiO 2 sols in this study is n[C 2 H 5 OH] : n[H 2 O] : n[CA] : n[HCl] : n[TOBT] = 20 : 6 : 1.2 : 0.025 : 1, at ambient temperature. Particle size distribution analysis of the sol reveals that the curve is right tailed with an average diameter of 72.8 nm. Factors affecting the performance of finished cotton fabrics by TiO 2 sols, such as concentration of sodium hypophosphite (SHP), triethanolamine (TEA) in finishing bath, curing temperatures and time lengths were investigated by orthogonal experiments. The optimum finishing results can be obtained with 3% SHP, 3% TEA, curing at 165°C for 3 min. Aggregated nano-TiO 2 particles on surfaces of finished cotton fibers both washed and unwashed were investigated by high resolution cold field emission scanning electron microscope and energy dispersive X-ray spectrometer. Esterification crosslinking between CA and cotton fibers were also demonstrated through infrared spectra. After a five-time's wash, ultraviolet protection factor of finished cotton fabrics with nano-TiO 2 sols is up to 117.42 and dry crease recovery angles increase by 30.2° with slightly improved whiteness, while the breaking strength decreases by 18.8%. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011

研究领域: 纺织科学 · 材料科学
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Materials · 2022 ·Vol. 16 ·期 1 ·286 · IF 3.748

Vinylated Modification of Biophytic Acid and Flame-Retardant/Crease-Proofing Finishing of Cotton Fabrics via In Situ Copolymerization

Bingying Cheng,Qingqing Zhou,Jiayi Chen,Xu Zhang,Chenglei Zhu,Minghao Wu

The vinyl phytic acid (GPA) was prepared using biophytic acid (PA) and glycidyl methacrylate (GMA), in which double bonds were introduced into the phytic acid molecule to increase the active groups in the phytic acid molecule. Furthermore, itaconic acid (IA) containing two unsaturated double bonds and GPA was polymerized in situ and crosslinked on the surface of cotton fabrics, and flame retardant and crease-proofed fabrics were obtained. The effects of GPA, IA, and the initiator on the flame-retardant and crease-proofing properties of the fabrics were analyzed by a single-factor and double-dip double-nip experiment. A flame-retardant and wrinkle-resistant fabric was obtained when the limiting oxygen index (LOI) and wrinkle recovery angle (WRA) were 28% and 270°, respectively. During combustion, the thermal properties of the fabrics changed; typically, the extrapolated initial temperature (Te) decreased, and moisture release increased. After burning, the fabrics had good shape retention, and the carbon residue content increased to 48%, which effectively inhibited or slowed down the combustion and heat release of the textiles. However, the whiteness, mechanical properties, and washability of the products need to be further improved.Keywords:flame-retardant and crease-proofing finishing;phytic acid;cotton textiles

研究领域: 纺织科学 · 材料化学
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