INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
·
2024
·
IF 7.7
Chunzu Cheng,Zhongkai Xu,Qingbo Zhao,Min Gao,Ting Li,Guozhen Li,Kedong Chi,Jigang Xu,Bowen Cheng
Cellulose is a kind of green and renewable materials, but its flammability limits its wide application. In order to enhance the flame retardancy of cellulose materials, herein, melamine cyanurate, decabromodiphenyl ethane, 1,2-Bis(2-oxo-5,5-dimethyl-1,3,2-dioxyphosphacyclohexyl-2-imino)ethane(BODIE) and montmorillonite were used as four typical flame retardants. These flame retardants were used alone or in combination to prepare several flame retardant lyocell fibres by physical blending method. Furthermore, the flame retardancy mechanism of phosphorus, nitrogen, halogen and inorganic flame retardant was studied through TG-IR and Raman test, and the synergistic flame retardant between four flame retardants were studied for the first time. The results showed that the nitrogen and halogen-containing flame retardants played the gas-phase flame retardant action by inert gas dilution and chemical quenching of active radicals, respectively. The inorganic flame retardant exerted condensed-phase flame retardant mechanism. The phosphorus flame retardant played both gas and condensed-phase flame retardant effect by chemical quenching of active radicals and cellulose carbonization. Furthermore, the synergism index of phosphorus‑nitrogen and phosphorus-halogen in cellulose materials were 2.1 and 1.7, respectively. There was no obvious synergistic effect between inorganic flame retardant with other flame retardants. In addition, the use of any flame retardant alone tailored the fibre's Limiting Oxygen Index (LOI) lower than 28 %. In contrast, the fibres achieved a LOI of 31 % and a tensile strength of 3.0 cN/dtex when the content of phosphorous flame retardant, nitrogen flame retardant and halogen flame retardant were 45–75 %, 12–55 %, 0–25 %, respectively. This study prepared a method for preparing flame retardant cellulose materials with extremely low-cost and large-scale application potential, and provided a theoretical basis that the selection of flame retardants helped to improve the flame retardant performance of cellulose materials.
研究领域:
材料科学
·
化学工程
✓ 已验证
产品关联
DOI
PubMed
高影响因子
Materials
·
2019
·Vol. 12
·期 24
·4035
·
IF 2.972
Junsheng Wang,Lei Xue,Bi Zhao,Guide Lin,Xing Jin,Dan Liu,Haibo Zhu,Jinjun Yang,Ke Shang
The intumescent flame retardant ethylene–propylene–diene rubber (EPDM) was prepared using intumescent flame retardant (IFR), including ammonium polyphosphate (APP) /pentaerythrotol (PER) and expandable graphite (EG), as the flame retardant agent. The effects of IFR and EG on the flame retardancy, fire behavior, and thermal stability of the EPDM were investigated. The results show that IFR and EG have excellent synergistic flame retardant effects. When the mass ratio of IFR to EG is 3:1 and the total addition content is 40 phr, the limiting oxygen index (LOI) value of the EPDM material (EPDM/IFR/EG) can reach 30.4%, and it can pass a V-0 rating in the vertical combustion (UL-94) test. Meanwhile, during the cone calorimetry test, the heat release rate and total heat release of EPDM/IFR/EG are 69.0% and 33.3% lower than that of the pure EPDM, respectively, and the smoke release of the material also decreases significantly, suggesting that the sample shows good fire safety. In addition, the flame retardant mechanism of IFR and EG is systematically investigated by thermogravimetric analysis/infrared spectrometry (TG-IR), Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM), and the results indicate that IFR and EG have only physical interaction. Moreover, the reason why IFR exhibits a poor flame retardant effect in EPDM materials is explained.Keywords:ethylene–propylene–diene rubber;flame retardancy;fire behavior;synergistic flame retardant effect;flame retardant mechanism
研究领域:
材料科学
·
化学工程
✓ 已验证
DOI
PubMed
高影响因子
JOURNAL OF FIRE SCIENCES
·
2017
·
IF 1.051
Qianqiong Zhao,Congyan Chen,Ruilan Fan,Yong Yuan,Yalin Xing,Xiao Ma
A halogen-free flame retardant containing nitrogen and phosphorus, 2-[anilino-(6-oxobenzo[c][2,1]benzoxaphosphinin-6-yl)methyl]phenol (PDOP), has been synthesized by reaction of benzo[c][2,1]benzoxaphosphinine-6-oxide (DOPO) with 2-(N-phenyliminomethyl)phenol. Halogen-free flame-retardant rigid polyurethane foams (RPUF-PDOP) were prepared using PDOP as a flame retardant. The flammability was investigated using limiting oxygen index, a vertical burning test (UL-94), and a cone calorimeter. When PDOP (10 wt%) as flame retardant was added to RPUF (RPUF-PDOP10%), the limiting oxygen index value was increased from 18% to 27%, and a UL-94 V-0 rating was achieved; meanwhile, the peak heat release rate, total heat release, and the average mass-loss rates of RPUF-PDOP10% were reduced from 246 to 207 kW m−2, from 26.9 to 21.0 MJ/m2, and from 0.043 to 0.033 g/s, respectively. Especially, the initial decomposition temperature of RPUF-PDOP10% was decreased from 228°C to 209°C. The final residual char from decomposition of RPUF-PDOP10% was significantly increased up to 35.6%. The addition of PDOP did not markedly decrease the mechanical properties of the resulting flame-retardant RPUFs.
研究领域:
材料科学
·
化学工程
✓ 已验证
DOI
高影响因子
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
·
2025
·
IF 8.5
Wenju Zhu,Wei Peng,Dongxiang Li,Shuolong Wang,Shuang Xu,Kai Ma,Jiarui Liu,Bowen Cheng
The concept of homologous flame retardant of cottonseed meal to cotton fiber is reported. According to the chemical bond characteristics of the amide bond, ester bond, and glycosidic bond in crude protein, crude fiber, and crude fat cottonseed meal, we developed a new system of H 2 O 2 -H 3 PO 4 degradation of dissolved cottonseed meal to prepare flame retardant. The study focuses on preparing water-soluble flame retardant (H 2 O 2 -H 3 PO 4 degradation Cottonseed meal, HPCm) by one-pot degradation of cottonseed meal and achieving durable flame retardancy for cotton fiber. The controllable degradation and dissolution conditions were optimized by orthogonal experiment, achieving a degradation rate of cottonseed meal that reached 88.4 %. The LOI of flame retardant cotton fiber after washing 50 LCS was still maintained at 36.2 %, and the damage length was 55 mm when the concentration of flame retardant HPCm was 60 g/L. The results of X-ray photoelectron spectroscopy, scanning electron microscopy and cone calorimetry showed that HPCm exhibited a synergistic flame retardant mechanism dominated by condensed phase flame retardant and supplemented by gas phase flame retardant. This method successfully produced a durable flame retardant for cotton fiber.
研究领域:
材料科学
·
纺织工程
·
阻燃化学
·
农业化学
·
高分子化学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
POLYMERS FOR ADVANCED TECHNOLOGIES
·
2019
·Vol. 30
·期 7
·1684-1695
·
IF 2.162
Jingshang Zhou,Miaojun Xu,Xiaohan Zhang,Yang Leng,Yintong He,Bin Li
The unsaturated polyester resins (UPR) were usually applied in electronic equipment, but the intrinsic flammability severely retrained their application. A mono-component flame retardant poly (piperazine methylphosphonic acid neopentylglycol ester) (PPMPNG) made in our lab was selected and applied to improve their flame retardant performance. The UPR thermosets achieved UL-94 V-0 grade during vertical burning tests and the limiting oxygen index was as high as 32.1% when 15 wt% PPMPNG was incorporated. PPMPNG promoted the decomposition and carbonization of UPR materials in advance during heating process, and the residual mass was effectively enhanced at high temperature. The flame retardant mechanism of UPR/PPMPNG thermosets was investigated by pyrolysis-gas chromatography/mass spectrometry tests, and the measurement of the morphologies and chemical components of the char residue. The phosphine oxygen radical was generated and then quenched the active free radicals in gas phase. Moreover, the av-EHC of FR-UPR was declined from 15.8 MJ kg −1 of pure UPR to 8 9 MJ kg −1 corresponding a reduction of 43.6%, which also verified the flame retardant effect in gas phase. The compact, integrated, and graphitized char layer was produced on materials surface and then exerted excellent barrier effect in condensed phase. Thus, the UPR/PPMPNG composites were conferred superior flame retardant properties.
研究领域:
材料科学
·
高分子化学
✓ 已验证
产品关联
DOI
高影响因子
Polymers
·
2023
·Vol. 15
·期 5
·1183
·
IF 5
Yanpeng Wu,Tonghui Yang,Yongchang Cheng,Tao Huang,Bin Yu,Qilin Wu,Meifang Zhu,Hao Yu
Preparing flame-retardant polyamide 66 (PA66) fibers through melt spinning remains one of the biggest challenges nowadays. In this work, dipentaerythritol (Di−PE), an eco-friendly flame retardant, was blended into PA66 to prepare PA66/Di−PE composites and fibers. It was confirmed that Di−PE could significantly improve the flame-retardant properties of PA66 by blocking the terminal carboxyl groups, which was conducive to the formation of a continuous and compact char layer and the reduced production of combustible gas. The combustion results of the composites showed that the limiting oxygen index (LOI) increased from 23.5% to 29.4%, and underwriter laboratories 94 (UL-94) passed the V-0 grade. The peak of heat release rate (PHRR), total heat release (THR), and total smoke production (TSP) decreased by 47.3%, 47.8%, and 44.8%, respectively, for the PA66/6 wt% Di−PE composite compared to those recorded for pure PA66. More importantly, the PA66/Di−PE composites possessed excellent spinnability. The prepared fibers still had good mechanical properties (tensile strength: 5.7 ± 0.2 cN/dtex), while maintaining good flame-retardant properties (LOI: 28.6%). This study provides an outstanding industrial production strategy for fabricating flame-retardant PA66 plastics and fibers.Keywords:PA66;Di−PE;flame retardance;melt spinning;flame retardant mechanism
研究领域:
材料科学
·
高分子化学
✓ 已验证
DOI
PubMed
高影响因子
INTERNATIONAL POLYMER PROCESSING
·
2021
·Vol. 36
·期 2
·172-184
·
IF 0.824
Y. Zhang,J. Liu,S. Li
A polyphosphonate (PDPA) flame retardant that contains phenyl phosphonic dichloride and 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide groups, has been synthesized. The flame retardant was introduced into epoxy resins (EP) and cured by 4,4’-diamino diphenylmethane. The vertical burning, limited-oxygen index and cone calorimeter tests reveal that the PDPA can enhance the flame-retardant properties of the EP significantly. With only a 4 wt% PDPA loading, the EP composites achieved a limited-oxygen index value of 33.4% and a V-0 rating in the vertical burning test, and the peak heat release rate and total heat release were decreased by 40.9% and 24.6%, respectively. The thermal properties and gas pyrolysis products of the EP composites were evaluated by thermogravimetric analysis and thermogravimetric analysis-Fourier transform infrared spectroscopy, and the morphology and structure of residual char were characterized by scanning electron microscopy, Flourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. To explain the combined effects of the condensed and gas phases, modes of the flame-retardant action are proposed.
研究领域:
材料科学
·
化学工程
✓ 已验证
DOI
高影响因子
JOURNAL OF POLYMER RESEARCH
·
2021
·Vol. 28
·期 5
·1-14
·
IF 3.097
Hu Rong,He Kaibin,Zheng Xianghong,Zeng Birong,Chen Guorong,Xu Yiting,Yuan Conghui,Luo Weiang,Dai Lizong
Octa-N-phenylaminopropyl-POSS (Octa-NAPA-POSS), DOPO and paraformaldehyde were used to synthesize Octa-DOPO-POSS through the Kabachnik-Fields reaction. It was added into epoxy resin with different ratio to prepare a series of modified epoxy resin composites. The results proved that the addition of flame retardant Octa-DOPO-POSS significantly improved the thermal property, flame retardant performance and moisture resistance of epoxy resin without weakening the mechanical properties. When the addition amount of Octa-DOPO-POSS was 5 wt%, the LOI value of the cured EP/Octa-DOPO-POSS composite increased to 33.9%. Its UL-94 level reached V-0 rating, and the THR and PHRR were significantly reduced. Meanwhile, the flexural modulus and breaking elongation were improved. Moreover, as the adding amount increased the residual char yield of EP/Octa-DOPO-POSS composites also increased, while the maximum thermal weight loss rate gradually decreased. The real-time FTIR and SEM analysis of the char residue after high temperature pyrolysis proved that Octa-DOPO-POSS could promote the char formation and produce a denser char layer. Overall, the combination of POSS and DOPO at a molecular level rather than physical mixing has a positive and significant effect on the flame retardancy of epoxy resin.
研究领域:
材料科学
·
化学工程
✓ 已验证
产品关联
DOI
高影响因子
POLYMERS FOR ADVANCED TECHNOLOGIES
·
2019
·Vol. 31
·期 5
·932-940
·
IF 2.162
Jie Wang,Yu Guo,ShunPing Zhao,Rong-Yi Huang,Xue-Jun Kong
Intumescent flame retardant (IFR) has received the considerable attention ascribed to the inherent advantages including non-halogen, low toxicity, low smoke release and environmentally friendly. In this work, a novel charring agent poly (piperazine phenylaminophosphamide) named as PPTA was successfully synthesized and characterized by Fourier transform infrared spectra (FTIR) and X-ray photoelectron spectroscopy (XPS). Then, a series of flame-retardant EP samples were prepared by blending with ammonium polyphosphate (APP) and PPTA. Combustion tests include oxygen Index (LOI), vertical Burning Test (UL-94) and cone calorimeter testing，these test results showed that PPTA greatly enhances the flame retardancy of EP/APP. According to detailed results, EP containing 10 wt% APP had a LOI value of 30.2%，but had no enhancement on UL-94 rating. However, after both 7.5 wt% APP and 2.5 wt% PPTA were added, EP-7 passed UL-94 V-0 rating with a LOI value of 33.0%. Moreover, the peak heat release rate (PHRR) and peak of smoke product rate (PSPR) of EP-7 were greatly decreased. Meanwhile, the flame-retardant mechanism of EP-7 was investigated by scanning electron microscopy (SEM), thermogravimetric analysis/infrared spectrometry (TG-IR) and X-ray photoelectron spectroscopy (XPS). The corresponding results presented PPTA significantly increased the density of char layer, resulting in the good flame retardancy.
研究领域:
材料科学
·
化学工程
✓ 已验证
产品关联
DOI
高影响因子
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
·
2020
·
IF 5.162
Caiyan Wan,Shidong Liu,Yv Chen,Fengxiu Zhang
The N P flame retardant ammonium salt of hydroxyethyl hexahydrotristriazine˗triphosphoric acid (AHTTPA) was prepared by a one–pot synthesis method under formaldehyde-free and solvent-free conditions. The AHTTPA was finished on the biomolecule of cotton by using the dip-roll-bake method. Nuclear magnetic resonance (NMR 1 H, 13 C, and 31 P) demonstrated that AHTTPA was successfully synthesized. The flame retardancy of AHTTPA-treated cotton was studied by limiting oxygen index (LOI), vertical flaming test (VFT), scanning electron microscopy (SEM), and cone calorimetry (CC). The results from these tests indicate that AHTTPA-treated cotton exhibited favorable flame retardancy and durability (the LOI value of 40%-treated cotton after 50 laundering cycles (LCs) was 29.8%), the flame was immediately extinguished after removal from the treated cotton, no smoldering or continued burning, the burned part formed a complete carbon frame and generally maintained its original morphology, the peak heat release rate (PHRR) and total heat release (THR) of AHTTPA-treated cotton fabric were significantly lower than pure cotton. Thermogravimetric analysis ( TGA ) results showed that AHTTPA improved the thermal stability of cotton. The breaking strength and softness of AHTTPA-treated cotton was also retained.
研究领域:
材料科学
·
纺织工程
✓ 已验证
DOI
PubMed
高影响因子
HIGH PERFORMANCE POLYMERS
·
2017
·
IF 1.179
Shan Huang,Xiao Hou,Jiaojiao Li,Xiujuan Tian,Qing Yu,Zhongwei Wang
A phosphorous/nitrogen-containing diphenylphosphine oxide (DPO) derivative (DPO-SS) was designed and synthesized via a two-step reaction of 4,4′-diaminodiphenylsulfone, 2-hydroxy-benzaldehyde, and DPO. The structure of DPO-SS was confirmed by Fourier transform infrared spectroscopy (FTIR), 1H and 31P nuclear magnetic resonance (NMR) spectroscopy, and mass spectrometry (MS). DPO-SS was used as a flame retardant and curing agent for copolymerizing with diglycidyl ether of bisphenol-A. Thermal and flame-retardant properties of the obtained flame-retardant epoxy resin (F-EP) were investigated by thermogravimetric analysis, dynamic thermomechanical analysis, limited oxygen index (LOI) measurement, vertical burning test (UL-94), and cone calorimeter test. Results indicated that all F-EP samples exhibited excellent thermal stability and flame-retardant property. Especially for F-EP with P content of 0.7 wt% (denoted as EP/P-0.7), it achieved high LOI values (32.4%) and UL-94 V-0 rating. Compared with pure EP, all F-EP samples showed lower heat release rate, total heat release, total smoke produce, and little Tg fluctuation. In order to study the flame-retardant mechanism, the char residues were investigated by FTIR, scanning electron microscopy, and energy-dispersive spectrometer analysis. The results manifested that DPO-SS acted as flame retardant in both gas phase and condensed phase. Water absorption properties of pure EP and F-EP were also compared through immersion experiments. Results showed that EP/P-0.7 sample had apparently lower water absorptivity than pure EP.
研究领域:
材料科学
·
化学工程
✓ 已验证
产品关联
DOI
高影响因子
POLYMER DEGRADATION AND STABILITY
·
2020
·
IF 4.032
Hao Wang,Shan Li,Zongmin Zhu,Xianze Yin,Luoxin Wang,Yunxuan Weng,Xuyi Wang
A novel flame retardant POBDBI was generated by the reaction of p-dibenzaldehyde, 5-amino-2-benzimidazolinone and 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO), and employed to epoxy resin. The structure of POBDBI was measured by FT-IR and NMR tests. Then flame-retardant EP was fabricated by using POBDBI as a flame-retardant. The thermal stability, flame-retardant performance and fire behavior were investigated by a serious of comprehensive instruments. Combustion tests show the flame-retardant performance of composite materials has been significantly improved. For example, the EP/POBDBI-1.0 with the phosphorus content of 1.0% accorded a V-0 rating and its limiting oxygen index (LOI) value increased to 36.5%. Besides, total smoke production (TSP), peak heat release rate (PHRR) and total heat release (THR) of EP/POBDBI-1.0 dropped significantly, and the corresponding values were decreased by 48.4%, 48.9% and 8.7%, respectively. At the same time, the composition, morphology of chars and gaseous products of POBDBI were studied by X-ray photoelectron spectroscopy (XPS), FT-IR, scanning electron microscope (SEM) and Py-GC/MS. These results presented that POBDBI could not only exerted free radical capture effect, but also enhanced the density of char residue.
研究领域:
材料科学
·
化学工程
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）