CERAMICS INTERNATIONAL
·
2022
·
IF 5.532
Zichen Zheng,Kewei Liu,Kaichun Xu,Chao Zhang
Various metal oxides with unique microstructures have been hopeful in fabricating gas sensors applications . This paper reports the room-temperature sensing properties of hierarchical Sb 2 WO 6 (antimony tungstate) microspheres for nonanal, which is a dominant aromatic aldehyde compound in cooked rice. The hierarchical Sb 2 WO 6 microspheres were obtained by pH control (from pH 1 to 5) through a one-step hydrothermal reaction . The experiment indicated that the optimal response of the Sb 2 WO 6 (pH = 4) gas sensor to 30 ppm nonanal reached 62 at room temperature, which was about 8 times that of Sb 2 WO 6 (pH = 1). The improved sensing performance resulted from the finer microstructure and larger specific surface area of Sb 2 WO 6 with a pH value of 4, providing abundant adsorption sites for nonanal molecules. Meanwhile, the practicability of cooked rice stored for various periods was verified through gas detection, and the results indicated that the sensor might recognize the deterioration of cooked rice and ready-to-eat rice. Therefore, the as-prepared sensor can be used in electronic nose systems to detect cooked rice and ready-to-eat rice deterioration and improve rice cooking methods.
研究领域:
材料科学
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传感器技术
✓ 已验证
DOI
高影响因子
EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY
·
2022
·Vol. 124
·期 9
·2100254
·
IF 3.196
Kainan Xing,Minghe Cao,Qinkai Zhu,Haojie Yin,Meizhen Lu,Jianbing Ji
Vegetable oils and their derivatives are of great interest because of their abundance and renewability. This paper prepares nonanal (N) and methyl 9-oxonanoate (M) from methyl epoxystearate (ME) with WO 3 ∙0.33H 2 O, WO 3 ∙H 2 O, and WO 3 ∙2H 2 O as catalysts and H 2 O 2 as the oxidant without the use of organic solvent. The reaction temperature, catalyst amount, H 2 O 2 amount, and reaction time effects on ME conversion and N/M yield are investigated. The results show that WO 3 ∙H 2 O has the best catalytic performance. The optimal reaction conditions are: reaction temperature 60 °C, reaction time 40 min, ME/H 2 O 2 /WO 3 ∙H 2 O molar ratio 1/1.2/0.4, under which the ME conversion and N/M yield reach 95% and 70%, respectively. WO 3 ∙ n H 2 O reacts with H 2 O 2 to form soluble tungsten anions, resulting in severe tungsten loss. Al-MCM-41 materials with different silicon to aluminum molar ratios are added to the reaction system as adsorbents to recover the catalyst by effective adsorption of tungsten anions. The adsorption performance improves as the Si/Al ratio decreases, however, the ME conversion and N/M yield decrease. Thus, 50 is the most suitable Si/Al ratio. The ME conversion and N/M yield can still reach 90% and 60% after four times of use. Practical applications : The nonanal has a natural fragrance and can be used in the cosmetic industry as well as in the preparation of bio-based surfactants. The methyl 9-oxonanoate can be converted into polymer monomers by hydrogenation or amination. The results show that WO 3 ∙ n H 2 O has good catalytic activity, and a satisfying yield of aldehyde products is obtained under mild reaction conditions.
研究领域:
化学工程
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可再生资源化学
✓ 已验证
产品关联
DOI
高影响因子
FOOD CHEMISTRY
·
2023
·
IF 8.8
Mingguang Yu,Qinggang Xie,Han Sun,Ying Wang,Yuan Tang,Baosong Wang,Huanlu Song,Lijin Wang,Shilong Jiang,Kaifeng Li,Yongjiu Zhang,Chengdong Zheng
Odor is an important indicator of human milk (HM) quality, with a proven function. Here, the effect of inter-individual nutrient differences on key odor-active compounds (OACs) and odor attributes of HM samples was investigated using flavor analysis techniques and correlation network analysis. A total of ninety-four OACs were identified from 30 HMs, of which 24 key OACs could represent the basic odor characteristics of HMs. Fat content was closely related to the amounts of OACs, with aldehydes being the most abundant species and having the highest correlation with fat content. Of them, nonanal and octanal were the most important OACs in HM, having both high flavor dilution factor (2 ∼ 64, 4 ∼ 128) and odor activity values (<1 ∼ 37, 2 ∼ 36) in most samples. Additionally, different pattern of synergism between key OACs contribute to each odor attribute of HM. These findings will provide insights for subsequent in-depth studies of HM flavor.
研究领域:
食品科学
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营养学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
Advanced Science
·
2024
·
IF 14.3
Zichen Zheng,Kewei Liu,Yiwen Zhou,Kaichun Xu,Yifan Luo,Jiabao Ding,Carla Bittencourt,Marc Debliquy,Chao Zhang
La-decorated Bi 2 O 2 CO 3 (BCO-La) microspheres are synthesized using a facile wet chemical strategy for sensing low-concentration nonanal (C 9 H 18 O) at room temperature. These BCO-La gas sensors are applied to evaluate agricultural product quality, specifically for cooked rice. The sensitivity of the BCO-6La sensor significantly surpassed that of the pure BCO sensor, achieving a response value of 174.6 when detecting 30 ppm nonanal gas. Notably, the BCO-6La sensor demonstrated a faster response time (36 s) when exposed to 18 ppm of nonanal. Additionally, the selectivity toward nonanal gas detection is higher (approximately 4–24 times) compared to interfering gases (1-octanol, geranyl acetone, linalool, hexanal, 2-pentyfuran, and 1-octen-3-ol) during cooked rice quality detection. The gas sensing mechanism and the factors contributing to the enhanced sensing performance of the BCO-La microspheres are demonstrated through in situ FT-IR spectra and DFT analysis while the realistic detection scenario is carried out. In a broader context, the reported sensors here represent a novel platform for the detection and monitoring of gases released by agricultural products during storage.
研究领域:
材料科学
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传感器技术
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农业科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
LWT-FOOD SCIENCE AND TECHNOLOGY
·
2019
·
IF 3.714
Meng Fu,Xu Shen,Hui Peng,Qiang Zhou,Jing Yun,Yue Sun,Chi-Tang Ho,Huimei Cai,Ruyan Hou
Roasted sunflower seeds contain high levels of unsaturated fatty acids , which are susceptible to oxidative rancidity when they are stored under inappropriate conditions. This lipid oxidation affects the quality of roasted sunflower seeds . Rancidity components (mainly including 11 aldehydes, 1 alcohol, 2 ketones, 1 acid and 1 furan) were identified in roasted sunflower seeds using HS-GC-MS-O (headspace-gas chromatography-mass spectrometry-olfactometry). Sunflower seeds harvested within the last year and those stored for one or two years were used to produce roasted sunflower seeds. The roasted sunflower seeds were stored at room temperature for 160 days and analyzed by HS-GC-MS-O. In roasted sunflower seeds, 16 rancidity compounds showed similar increasing trends with age of raw material, while the levels of the pyrazine compounds did not change during storage. Nonanal , hexanoic acid , 2,4-nonadienal, and heptanal were determined to be responsible for the off-flavor of the rancid products, and could be used to discriminate between final products made fresh and stored raw materials.
研究领域:
食品科学
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植物学
✓ 已验证
DOI
高影响因子
EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY
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2018
·Vol. 120
·期 7
·1700415
·
IF 2.2
Meizhen Lu,Libo Peng,Qinglong Xie,Yong Nie,Xuejun Liu,Xianghong Lu,Jianbing Ji
At present, the utilization of grease has attracted more and more attention. This article presents a simple method that efficiently cleaves methyl oleate-derived methyl 9,10-epoxystearate ( a ) to give high yields of methyl 9-oxononanoate ( d ) with nonanal ( c ) as co-product. A WO 3 /MCM-41 catalyst is prepared via direct mixed-gel synthesis. The catalyst is tested in the oxidative cleavage of a to produce d which can be used as a polymer precursor or an important feedstock. The effects of WO 3 loading, temperature, time, H 2 O 2 / a molar ratio, catalyst/ a weight ratio, and t -BuOH/ a weight ratio on the a conversion and d yield are examined using single-factor experiments. The optimal reaction conditions are determined by orthogonal experiments. The optimal WO 3 loading, temperature, time, H 2 O 2 / a molar ratio, catalyst/ a weight ratio, and t -BuOH/ a weight ratio are 35%, 80 °C, 20 min, 1.3, 0.04, and 0.5, respectively. Under these conditions, the a conversion and d yield reach 99.4 and 78.4%, respectively. In addition, the catalyst shows no significant decrease in activity after being reused three times. Moreover, the reaction mechanism is studied based on the product distribution over time. Practical Applications : Few studies on methyl 9,10-epoxystearate used as the raw material to give methyl 9-oxononanoate and nonanal are found. Because the ethylene oxide bond is more unstable than the carbon–carbon double bond, the oxidative cleavage of methyl 9,10-epoxystearate is easier than cleavage of methyl oleate that allows the oxidative cleavage to be done under milder conditions. Methyl 9-oxononanoate can be converted to a monomer of high-value polymers and is also an important feedstock in the production of chemicals. The co-product nonanal is a natural spice which can be used in the fragrance industry. The results show that the reaction time is short and methyl 9-oxononanoate yield is high under mild reaction conditions. The method in this study can also be widely used in other oxidative cleavage reactions of epoxides. Methyl 9,10-epoxystearate is used as the raw material to produce methyl 9-oxononanoate with nonanal as co-product using WO 3 /MCM-41 as catalyst and H 2 O 2 as oxidant.
研究领域:
化学工程
·
催化材料
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）