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Food Science & Nutrition · 2020 ·Vol. 8 ·期 7 ·3234-3242 · IF 1.797

Copigmentation effect of three phenolic acids on color and thermal stability of Chinese bayberry anthocyanins

Yanyun Zhu,Hongji Chen,Leyan Lou,Yixin Chen,Xingqian Ye,Jianchu Chen

The copigmentation effects of three phenolic acids (ferulic acid, sinapic acid, and syringic acid) on the color and thermal stability of Chinese bayberry anthocyanins were investigated. The three copigments of ferulic acid, sinapic acid, and syringic acid were found to have significant effects on the color enhancement of bayberry anthocyanins ( p < .05). The maximum absorption wavelength of the anthocyanin aqueous solution exhibited a bathochromic shift, L * decreased, and a * increased with the increase in the molar ratio of copigments. The thermal stability of bayberry anthocyanins was significantly improved after copigmentation. No new anthocyanin derivatives appeared after copigmentation. The thermodynamic parameters (Δ G , Δ H , Δ S ) of the three processes were all negative, indicating the three copigmentations were generally spontaneous and exothermic. The equilibrium constant ( K ) of the sinapic acid group was the greatest among the three phenolic acids, indicating that sinapic acid was more effective in stabilizing the anthocyanins.

研究领域: 食品科学 · 植物化学
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RSC Advances · 2022 ·Vol. 12 ·期 17 ·10386-10394 · IF 4.036

Insights into coloration enhancement of mercerized cotton fabric on reactive dye digital inkjet printing

Hongzhi Zhao,Kun Zhang,Kuanjun Fang,Furui Shi,Ying Pan,Fuyun Sun,Dezhen Wang,Ruyi Xie,Weichao Chen

Mercerization can improve the utilization rate of dyes in the dyeing process, and reduce the discharge of washing wastewater. However, the effect and mechanism of mercerization is not clear on digital inkjet printing of cotton fabric. In this work, two kinds of cotton fabrics (original and mercerized) were used for reactive dye digital inkjet printing, and the color improvement mechanism of caustic soda mercerization was investigated. It was found that the crystallinity of cotton fibre was adjusted from 73.9% to 58.5% by caustic mercerization, and the breaking strength did not decrease compared with original cotton fibre. Thus, the accessible reactive hydroxyl groups and the wettability were enhanced for treated cotton fibres, which promoted the inks' wick into the fibres. Interestingly, the penetration of ink droplets between the yarns and fibres after caustic mercerization was decreased, thus the dyes mainly gathered on the surface of cotton fabric. The cotton fibres' cross section structure changed from flat oval to round, which increased the contact area between reactive dyes and fibres. At a certain amount of ink, the optimal K/S value of 23.47 was achieved for treated cotton fabrics, which was higher than that of untreated cotton fabrics (17.15). Meanwhile, the printed fabrics displayed good washing fastness, rubbing fastness and glossiness. This work has important theoretical guiding significance for producing high quality mercerized cotton fabric digital printing products and reducing printing wastewater discharge.

CAS / MDL: 107-21-1 127-68-4
研究领域: 纺织科学 · 染整工程
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Journal of Materials Chemistry C · 2015 ·Vol. 4 ·期 7 ·1386-1391 · IF 4.696

Photosensitive polystyrene/silver bromide hybrid colloidal crystals as recoverable colorimetric naked eye probes for bromine gas sensing

Bing Yu,Feng Zhai,Hailin Cong,Di Yang

Photosensitive polystyrene (PS)/silver bromide (AgBr) hybrid colloidal crystals were prepared using a co-deposition method. After treatment with UV light, the infiltrated AgBr decomposed to silver nanoparticles (Ag-NPs), and PS/Ag-NP hybrid colloidal crystals with enhanced structural colours were obtained. The enhanced structural colors are due to the absorption of incoherent scattering light and increase in color saturation by the embedded Ag-NPs. The band gaps of the PS colloidal crystals, and PS/AgBr and PS/Ag-NP hybrid colloidal crystals were measured using a UV-vis reflection spectrometer and calculated using Bragg law. The obtained PS/Ag-NP hybrid colloidal crystals could be used as recoverable colorimetric naked eye probes for bromine (Br) gas sensing with a detection limit of 15 mmol L−1 at a sensing time of 50 s. The sensor had a very reliable performance after repeated bromine sensing, and could be mass produced facilely with very low cost.

CAS / MDL: 31098-21-2
研究领域: 材料科学 · 化学传感器 · 纳米技术
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FOOD CHEMISTRY · 2025 · IF 9.8

From discoloration to color enhancement: A novel approach to high-concentration tannic acid detection based on VCo-N-C bimetallic Nanozyme

Cailin Qiao,Xinrou Wang,Huibo Luo,Yi Ma,Ping Yang,Danqun Huo,Suyi Zhang,Changjun Hou

The direct and rapid detection of high-concentration tannic acid (TA) was crucial for food quality monitoring. In this study, a TA detection system was developed based on a binary metal V and Co-enclosed carbon substrate (VCo-N-C) nanozyme with laccase-like activity, which innovatively shifted the conventional detection approach from the 3,3′,5,5′-tetramethylbenzidine (TMB) discoloration principle to the 4-aminoantipyrine(4-AP) color enhancement principle. In the presence of VCo-N-C, 4-AP specifically bound to the oxidation products of TA, resulting in a brown-red compound. The sensing platform reduced the reaction time to 10 min and extended the detection range to 0.1–3000 mg/L (R 2  > 0.99). Ultimately, the VCo-N-C&4-AP system was successfully applied to detect TA content in high-concentration actual samples such as brandy, white liquor, and tea beverages without the need of pretreatment. This study provided a new and powerful strategy for food quality control and monitoring.

研究领域: 生物化学 · 食品安全
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CHEMICAL ENGINEERING JOURNAL · 2023 · IF 15.1

Pt-Ru bimetallic nanoclusters with super peroxidase-like activity for ultra-sensitive lateral flow immunoassay

Xiaoting Li,Cheng Qian,Yonghui Tian,Naizhi Yao,Yixiang Duan,Zhijun Huang

In this work, Pt-Ru bimetallic nanoclusters (Pt-Ru NCs) were prepared by a simple one-pot hydrothermal method. The as-prepared Pt-Ru NCs has extremely high peroxidase-like activity, showing a specific activity of 115.36 U/mg far superior to Pt NCs and many reported single-atom nanozymes. This can be attributed to the various microstructures effective for catalysis and unique electron transfer characteristics leading to active hydroxyl radicals ( OH) activation as revealed by density functional theory. By using the Pt-Ru NCs as a substitute for natural horseradish peroxidaseand when cross-linking with antibody as a catalytic label, the colorimetric enhanced lateral flow immunoassay (LFIA) for D-dimer detection was established. As a result, with only 20 s of additional coloration, the visual sensitivity can be improved by about 100 times to 1 ng/mL, while maintaining good specificity and anti-interference. In general, the excellent performance indicates that the Pt-Ru NCs have great potential in colorimetric detection, which is worthy of further promotion.

CAS / MDL: 54827-17-7
研究领域: 生物化学 · 医学诊断 · 纳米材料
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CARBOHYDRATE POLYMERS · 2024 · IF 10.7

Customized development of 3D printed anthocyanin-phycocyanin polychromatic oral film via chondroitin sulfate homeostasis: A platform based on starch and κ-carrageenan

Yiwen Bao,Mingshuang Wang,Xu Si,Dongnan Li,Hailong Gui,Qiao Jiang,Jiaxin Li,Shufang Yang,Yiyun Yang,Zhongxia Li,Bin Li

The development of oral film with diverse colors and customized nutrition is in line with the innovation of emerging food . In this study, polychromatic system was formed by regulating the ratio of phycocyanin (PC) to blueberry anthocyanin (BA). Further, chondroitin sulfate (CS) was utilized to achieve color-enhanced and homeostatic effects on PC-BA, and κ-carrageenan (KC) - starch complex was exploited as printing ink to construct oral film system. The color-enhanced effect of CS is mainly related to the complexation of sulfate groups, and the film-forming substrates are combined mainly through hydrogen bonding . In addition, the proportion of KC modulated the gel structure of printing ink, and affected 3D printability and physical properties of oral film. OF II (1.5 % KC content) had a uniform and dense network structure, with the most stable color and the highest BA retention (70.33 %) after 8 d of light exposure. Importantly, OF II had an excellent slow-release effect, and BA release rate was as high as 92.52 %. The optimized components can form polychromatic oral film with controllable color and structure, and provide new insights for the creation of sensory personalized and nutritionally customized food.

CAS / MDL: 11114-20-8
研究领域: 食品科学 · 材料科学 · 生物技术
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FOOD AND BIOPRODUCTS PROCESSING · 2024 · IF 3.5

Synergistic effects of plasma-activated water (PAW) and electrochemical treatment on the color of tuna slices

Zhigang Ke,Yuqing Yi,Yuhang Liu,Shulai Liu,Xuxia Zhou,Yuting Ding

Recent advances in the field of meat processing have promoted the exploration of innovative methods to enhance the visual appeal of meat products. This research introduces a new approach that involves the combination of plasma-activated water (PAW) and electrochemical processes to improve the redness of tuna meat. The study revealed that subjecting PAW to electrochemical treatment at −0.85 V for 5 min significantly enhanced its color-enhancing properties. This enhancement is linked to the conversion of nitrites and nitrates into nitric oxide (NO) during the electrochemical process, which then interact with myoglobin to form nitrosomyoglobin (NOMb), resulting in the desired pink coloration. While a slight rise in residual nitrite and lipid oxidation was noted after treatment, these levels remained within acceptable limits according to prevailing safety standards , ensuring consumer safety. This study sets the stage for the potential utilization of a combined approach involving PAW and electrochemical methods in meat processing, offering the prospect of developing more appealing and commercially viable meat products.

CAS / MDL: 373-57-9 110-54-3
研究领域: 食品科学 · 肉类加工 · 电化学 · 等离子体技术
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