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JOURNAL OF THE EUROPEAN CERAMIC SOCIETY · 2025 · IF 6.2

Low-temperature sintering of high-Q MgGa2O4 ceramics via (Li0.5Bi0.5)2+ substitution and assisting sintering atmosphere

Chenglong Wang,Luchao Ren,Zixin Zhang,Hui Peng,Cuncheng Li,Panpan Lyu,Qingyang Du,Mingwei Zhang

A dual-modification strategy combining (Li 0.5 Bi 0.5 ) 2+ substitution and BaCu(B 2 O 5 )/LiF atmosphere-assisted sintering was developed to reduce the sintering temperature of MgGa 2 O 4 ceramic. The strategy achieved a 360 °C reduction in sintering temperature (from 1610 to 1250 °C) while maintaining a high performance. The optimal sample (Li 0.5 Bi 0.5 ) x Mg 1- x Ga 2 O 4 ( x  = 0.02) exhibited ε r = 9.41, Q × f = 127,159 GHz, and τ f = -39.6 ppm/°C. XRD and Rietveld refinement confirmed that the spinel structure was preserved upon doping, alongside a lattice expansion. Consistent with the enhanced Q × f , a Raman spectroscopy analysis revealed a narrowing of the T 2 g mode, indicating an improved structural ordering. Furthermore, τ f was improved to −39.6 ppm/°C, directly related to the induced lattice distortion and expansion. The enhanced performance was attributed to the synergistic effects of composite ion doping and atmosphere-assisted sintering. The former modified the intrinsic structure and polarization characteristics, while the latter facilitated the densification at lower temperatures.

研究领域: 材料科学 · 陶瓷工程
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Photonics Research · 2024 ·Vol. 12 ·期 7 ·1542-1547 · IF 6.6

Enhanced terahertz vibrational absorption spectroscopy using an integrated high-Q resonator

Zhibo Hou,Zhibo Hou,Liao Chen,Liao Chen,Rongwu Liu,Rongwu Liu,Chi Zhang,Chi Zhang,Xiaojun Wu,Xiaojun Wu,Xinliang Zhang,Xinliang Zhang,Xinliang Zhang

The terahertz (THz) absorption spectrum is a powerful method to identify substances. The improvement focuses on sensitivity and recovery ability. Here, we demonstrate enhanced THz vibrational absorption spectroscopy based on an on-chip THz whispering gallery mode resonator (THz-WGMR). A THz-WGMR with high Q can store energy and enhance the interaction between the THz waves and the target substances to capture the unique absorption fingerprint information. Therefore, it possesses significant sensitivity to identify trace amounts of substances. As a proof of concept, lactose powder and glucose powder are applied to demonstrate the effectiveness of our approach in recovering fingerprint absorption spectroscopy. Compared with a straight waveguide, the high sensitivity of the THz-WGMR is illustrated. The change of the transmissivity caused by the lactose reaches 7.8 dB around 532 GHz for the THz-WGMR, while only 1.4 dB for the straight waveguide, demonstrating the state-of-the-art sensing performance in fingerprint absorption recovery. We believe the proposed integrated THz-WGMR will promote the THz identification of tiny fingerprint substances.

CAS / MDL: 50-99-7
研究领域: 物理学 · 光学 · 材料科学
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ACS Applied Materials & Interfaces · 2021 · IF 9.229

High-Quality-Factor AlON Transparent Ceramics for 5 GHz Wi-Fi Aesthetically Decorative Antennas

Chao Du,Di Zhou,Shu-Zhao Hao,He-Tuo Chen,Jian Zhang,Shi-Kuan Sun,Tao Zhou,Ming-Zhao Dang,Shao-Fei Wang,Hai-Wen Liu,Long Li,Zhuo Xu

Transparent material has been widely used in product design and has seen a large increase in its use. In this paper, a kind of aesthetically decorative 5 GHz Wi-Fi dielectric resonator antenna (DRA) of aluminum oxynitride (AlON) transparent ceramic has been designed. High-quality-factor AlON transparent dielectric ceramics were fabricated by presintering at 1780 °C and further cold isostatic pressing (CIP) under a 200 MPa argon atmosphere. For a 9.0 mm thick specimen, the in-line light transmittance reached 83%. Optimum dielectric constant (εr = 9.32), quality factor (Qf = 47 960) and temperature coefficient (TCF = −51.7 ppm/°C) was achieved in the AlON transparent ceramic by cold isostatic pressing. As a result, the proposed aesthetically decorative DRA can achieve an impedance bandwidth of 32% (4.48–6.19 GHz), a high radiation efficiency of 85%, and a low cross-polarization discrimination (XPD) of −30 dB. To achieve a broad bandwidth, the proposed antenna was excited in its dominant TE111x mode and higher-order TE113x mode. The proposed antenna is thus an excellent candidate for an indoor decoration Wi-Fi antenna.

研究领域: 材料科学 · 无线通信 · 陶瓷工程
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ACS Omega · 2024 · IF 3.7

Concave Version Printing of High-Performance Polymer THz Filters

Jiang Wei,Yan Miao,Wenqian Zhang,Youxin Chen,Guotao Sun,Kaiyu Wu,Qingkang Wang

The development of high Q and tunable narrowband filters that can efficiently manipulate THz beams is critical for various THz applications, such as imaging and sensing. However, for filters made of metals and dielectrics, issues such as high losses, limited tunability, and lengthy process flows exist. Here, a scalable concave version reprinting technique to mass produce high-performance microstructured polymer filters is presented. The technique is extremely simple, eliminating the demand for the use of any large equipment including injection molding and thermal press printing machines, and is reliable; in the reprinted structures, there are no defects including gaps and air bubbles. The produced narrowband filters exhibit a high Q factor of 57 with wide tunability over the THz band from ∼80 to 160 μm in wavelength. The presented technique can be adopted to realize other devices as well using polymer materials with simplicity and high precision.

研究领域: 光学工程 · 材料科学 · 微纳米制造
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CERAMICS INTERNATIONAL · 2018 ·Vol. 44 ·期 17 ·21000-21003 · IF 3.057

MgTiO3/TiO2/MgTiO3: An ultrahigh-Q and temperature-stable microwave dielectric ceramic through cofired trilayer architecture

Jie Zhang,Zhenxing Yue,Yu Luo,Longtu Li

A cofired trilayer ceramic architecture showing as MgTiO 3 /TiO 2 /MgTiO 3 was designed to realize temperature-stable and ultrahigh- Q microwave dielectrics in the typical MgTiO 3 -TiO 2 system. The effects of TiO 2 content on the microwave dielectric properties of cofired trilayer ceramics were studied. Through the design of cofired trilayer architecture, the chemical reactions between MgTiO 3 and TiO 2 were limited within a narrow region of MgTiO 3 /TiO 2 interfaces (~ 15 µm in width), which could be beneficial for optimizing the microwave dielectric properties. Excellent characteristics of ε r ~ 18.38, Q×f value ~ 169,900 GHz and τ f ~ − 1 ppm/°C were gained for the MgTiO 3 /TiO 2 /MgTiO 3 ceramic architectures stacked with 1.63 vol% TiO 2 . The current work could serve as new strategies to develop high-performance dielectric resonators and multilayers for 5G wireless communication applications.

研究领域: 材料科学 · 无机非金属材料 · 电子陶瓷 · 微波介质材料 · 功能陶瓷
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TALANTA · 2023 · IF 6.1

Integrated label-free erbium-doped fiber laser biosensing system for detection of single cell Staphylococcus aureus

Jiandong Liu,Bin Liu,Juan Liu,Xing-Dao He,Jinhui Yuan,Zabih Ghassemlooy,Hamdi Torun,Yong-Qing Fu,Xuewu Dai,Wai Pang Ng,Richard Binns,Qiang Wu

A critical challenge to realize ultra-high sensitivity with optical fiber interferometers for label free biosensing is to achieve high quality factors (Q-factor) in liquid. In this work a high Q-factor of 10 5 , which significantly improves the detection resolution is described based on a structure of single mode -core-only -single mode fiber (SCS) with its multimode (or Mach-Zehnder) interference effect as a filter that is integrated into an erbium-doped fiber laser (EDFL) system for excitation. In the case study, the section of core-only fiber is functionalized with porcine immunoglobulin G (IgG) antibodies, which could selectively bind to bacterial pathogen of Staphylococcus aureus ( S. aureus ). The developed microfiber-based biosensing platform called SCS-based EDFL biosensors can effectively detect concentrations of S. aureus from 10 to 10 5  CFU/mL, with a responsivity of 0.426 nm wavelength shift in the measured spectrum for  S. aureus  concentration of 10 CFU/mL. The limit of detection (LoD) is estimated as 7.3 CFU/mL based on the measurement of S. aureus with minimum concentration of 10 CFU/mL. In addition, when a lower concentration of 1 CFU/mL is applied to the biosensor, a wavelength shift of 0.12 nm is observed in 10% of samples (1/10), indicating actual LoD of 1 CFU/mL for the proposed biosensor. Attributed to its good sensitivity, stability, reproducibility and specificity, the proposed EDFL based biosensing platform has great potentials for diagnostics.

研究领域: 光学 · 生物传感 · 光子学 · 微生物学
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