Hydrothermal synthesis and growth of stable strontium apatite for radioactive salt waste immobilization
Safe management of chloride-rich radioactive salt waste produced during molten-salt dry reprocessing of spent nuclear fuel is essential for the sustainable deployment of advanced nuclear energy systems. Although 90 SrCl 2 represents only a minor mass fraction, its high specific activity and decay heat dominate short-term thermal management. In this work, a low temperature hydrothermal synthesis of Sr 5 (PO 4 ) 3 Cl effectively immobilized Sr and about 10 % of Cl, while the remaining Cl was released as NaCl. Over a 10-h hydrothermal process, the step-like growth of crystalline and partially disordered domains promotes enhanced crystallinity and increased particle size of the Sr 5 (PO 4 ) 3 Cl solidified form, thereby improving its chemical durability. The well-crystallized product exhibits a mass loss of less than 1.8 wt .% at 1000 °C, and normalized leach rate of Sr 2+ is 3.5 × 10 −6 gm −2 d −1 after 28 d in deionized water at 90 °C. Reliable thermal and chemical stability confirm that low-temperature hydrothermal processing is an energy-efficient strategy for conditioning 90 SrCl 2 chloride wastes prior to geological disposal.
危险品化学品经营许可证（带存储）